skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Rate and mechanism of the photoreduction of birnessite (MnO 2 ) nanosheets

Authors:
; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1235165
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Proceedings of the National Academy of Sciences of the United States of America
Additional Journal Information:
Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 112 Journal Issue: 15; Journal ID: ISSN 0027-8424
Publisher:
Proceedings of the National Academy of Sciences
Country of Publication:
United States
Language:
English

Citation Formats

Marafatto, Francesco Femi, Strader, Matthew L., Gonzalez-Holguera, Julia, Schwartzberg, Adam, Gilbert, Benjamin, and Peña, Jasquelin. Rate and mechanism of the photoreduction of birnessite (MnO 2 ) nanosheets. United States: N. p., 2015. Web. doi:10.1073/pnas.1421018112.
Marafatto, Francesco Femi, Strader, Matthew L., Gonzalez-Holguera, Julia, Schwartzberg, Adam, Gilbert, Benjamin, & Peña, Jasquelin. Rate and mechanism of the photoreduction of birnessite (MnO 2 ) nanosheets. United States. doi:10.1073/pnas.1421018112.
Marafatto, Francesco Femi, Strader, Matthew L., Gonzalez-Holguera, Julia, Schwartzberg, Adam, Gilbert, Benjamin, and Peña, Jasquelin. Mon . "Rate and mechanism of the photoreduction of birnessite (MnO 2 ) nanosheets". United States. doi:10.1073/pnas.1421018112.
@article{osti_1235165,
title = {Rate and mechanism of the photoreduction of birnessite (MnO 2 ) nanosheets},
author = {Marafatto, Francesco Femi and Strader, Matthew L. and Gonzalez-Holguera, Julia and Schwartzberg, Adam and Gilbert, Benjamin and Peña, Jasquelin},
abstractNote = {},
doi = {10.1073/pnas.1421018112},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 15,
volume = 112,
place = {United States},
year = {2015},
month = {3}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1073/pnas.1421018112

Citation Metrics:
Cited by: 22 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Abundant Porewater Mn(III) Is a Major Component of the Sedimentary Redox System
journal, August 2013


Terephthalic acid: A dosimeter for the detection of hydroxyl radicals in vitro
journal, December 1994


Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis
journal, February 2013

  • Robinson, David M.; Go, Yong Bok; Mui, Michelle
  • Journal of the American Chemical Society, Vol. 135, Issue 9
  • DOI: 10.1021/ja310286h

Photocurrent Generation from Semiconducting Manganese Oxide Nanosheets in Response to Visible Light
journal, May 2005

  • Sakai, Nobuyuki; Ebina, Yasuo; Takada, Kazunori
  • The Journal of Physical Chemistry B, Vol. 109, Issue 19
  • DOI: 10.1021/jp0500485

Water in the interlayer region of birnessite: Importance in cation exchange and structural stability
journal, April 2006


Structure of Synthetic K-rich Birnessite Obtained by High-Temperature Decomposition of KMnO 4 . I. Two-Layer Polytype from 800 °C Experiment
journal, December 2003

  • Gaillot, Anne-Claire; Flot, David; Drits, Victor A.
  • Chemistry of Materials, Vol. 15, Issue 24
  • DOI: 10.1021/cm021733g

Diel cycles in microbial manganese oxidation and manganese redox speciation in coastal waters of the Bahama Islands
journal, March 1990


Optical properties of the clearest natural waters (200–800 nm)
journal, January 1981


Why did Nature choose manganese to make oxygen?
journal, October 2007

  • Armstrong, Fraser A.
  • Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 363, Issue 1494
  • DOI: 10.1098/rstb.2007.2223

Mechanisms of pH-Dependent Activity for Water Oxidation to Molecular Oxygen by MnO 2 Electrocatalysts
journal, January 2012

  • Takashima, Toshihiro; Hashimoto, Kazuhito; Nakamura, Ryuhei
  • Journal of the American Chemical Society, Vol. 134, Issue 3
  • DOI: 10.1021/ja206511w

Energetic basis of catalytic activity of layered nanophase calcium manganese oxides for water oxidation
journal, May 2013

  • Birkner, N.; Nayeri, S.; Pashaei, B.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 22
  • DOI: 10.1073/pnas.1306623110

Mn(II) oxidation by an ascomycete fungus is linked to superoxide production during asexual reproduction
journal, July 2012

  • Hansel, C. M.; Zeiner, C. A.; Santelli, C. M.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 31
  • DOI: 10.1073/pnas.1203885109

Ultrafast electron and energy transfer in dye-sensitized iron oxide and oxyhydroxide nanoparticles
journal, January 2013

  • Gilbert, Benjamin; Katz, Jordan E.; Huse, Nils
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 40
  • DOI: 10.1039/c3cp53368a

Ultrafast optical probes of polaron dynamics in La0.7Ca0.3MnO3 thin films
journal, February 2009

  • Wu, K. H.; Hsu, T. Y.; Shih, H. C.
  • Journal of Applied Physics, Vol. 105, Issue 4
  • DOI: 10.1063/1.3078082

Enhanced Dissolution of Manganese Oxide in Ice Compared to Aqueous Phase under Illuminated and Dark Conditions
journal, December 2012

  • Kim, Kitae; Yoon, Ho-Il; Choi, Wonyong
  • Environmental Science & Technology, Vol. 46, Issue 24
  • DOI: 10.1021/es302003z

Molecular models of birnessite and related hydrated layered minerals
journal, August 2012

  • Cygan, R. T.; Post, J. E.; Heaney, P. J.
  • American Mineralogist, Vol. 97, Issue 8-9
  • DOI: 10.2138/am.2012.3957

Manganese-oxidizing photosynthesis before the rise of cyanobacteria
journal, June 2013

  • Johnson, J. E.; Webb, S. M.; Thomas, K.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 28
  • DOI: 10.1073/pnas.1305530110

Electron Small Polarons and Their Mobility in Iron (Oxyhydr)oxide Nanoparticles
journal, September 2012


What Are the Oxidation States of Manganese Required To Catalyze Photosynthetic Water Oxidation?
journal, July 2012

  • Kolling, Derrick R. J.; Cox, Nicholas; Ananyev, Gennady M.
  • Biophysical Journal, Vol. 103, Issue 2
  • DOI: 10.1016/j.bpj.2012.05.031

Photodissolution of iron oxides. IV. A comparative study on the photodissolution of hematite, magnetite, and maghemite in EDTA media
journal, September 1992

  • Litter, Marta I.; Blesa, Miguel A.
  • Canadian Journal of Chemistry, Vol. 70, Issue 9
  • DOI: 10.1139/v92-316

Photoreductive Dissolution of Iron(III) (Hydr)oxides in the Absence and Presence of Organic Ligands: Experimental Studies and Kinetic Modeling
journal, March 2009

  • Borer, Paul; Sulzberger, Barbara; Hug, Stephan J.
  • Environmental Science & Technology, Vol. 43, Issue 6
  • DOI: 10.1021/es801352k

On the role of Mn(IV) vacancies in the photoreductive dissolution of hexagonal birnessite
journal, July 2009

  • Kwon, Kideok D.; Refson, Keith; Sposito, Garrison
  • Geochimica et Cosmochimica Acta, Vol. 73, Issue 14
  • DOI: 10.1016/j.gca.2009.04.031

Characterization of the manganese oxide produced by pseudomonas putida strain MnB1
journal, July 2003


Visible-light-induced photodissolution of α-Fe2O3 powder in the presence of chloride anions
journal, January 1985

  • Grätzel, Michael; Kiwi, John; Morrison, Colin L.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 81, Issue 8
  • DOI: 10.1039/f19858101883

Charge carrier trapping, recombination and transfer in hematite (α-Fe2O3) water splitting photoanodes
journal, January 2013

  • Barroso, Monica; Pendlebury, Stephanie R.; Cowan, Alexander J.
  • Chemical Science, Vol. 4, Issue 7
  • DOI: 10.1039/c3sc50496d

Photocatalytic Water Oxidation Using Manganese Compounds Immobilized in Nafion Polymer Membranes
journal, January 2011

  • Young, Karin J.; Gao, Yunlong; Brudvig, Gary W.
  • Australian Journal of Chemistry, Vol. 64, Issue 9
  • DOI: 10.1071/CH11178

Layered manganese oxides for water-oxidation: alkaline earth cations influence catalytic activity in a photosystem II-like fashion
journal, January 2012

  • Wiechen, Mathias; Zaharieva, Ivelina; Dau, Holger
  • Chemical Science, Vol. 3, Issue 7
  • DOI: 10.1039/c2sc20226c

Phosphonate- and Carboxylate-Based Chelating Agents that Solubilize (Hydr)oxide-Bound Mn III
journal, June 2008

  • Wang, Yun; Stone, Alan T.
  • Environmental Science & Technology, Vol. 42, Issue 12
  • DOI: 10.1021/es7032668

Mechanism of Photocatalytic Water Splitting in TiO 2 . Reaction of Water with Photoholes, Importance of Charge Carrier Dynamics, and Evidence for Four-Hole Chemistry
journal, October 2008

  • Tang, Junwang; Durrant, James R.; Klug, David R.
  • Journal of the American Chemical Society, Vol. 130, Issue 42
  • DOI: 10.1021/ja8034637

Photoassisted dissolution of a colloidal manganese oxide in the presence of fulvic acid
journal, July 1988

  • Waite, T. David.; Wrigley, Ian C.; Szymczak, Ron.
  • Environmental Science & Technology, Vol. 22, Issue 7
  • DOI: 10.1021/es00172a006

Water-oxidation catalysis by manganese in a geochemical-like cycle
journal, May 2011

  • Hocking, Rosalie K.; Brimblecombe, Robin; Chang, Lan-Yun
  • Nature Chemistry, Vol. 3, Issue 6
  • DOI: 10.1038/nchem.1049

Short-range and long-range order of phyllomanganate nanoparticles determined using high-energy X-ray scattering
journal, January 2013

  • Manceau, Alain; Marcus, Matthew A.; Grangeon, S.
  • Journal of Applied Crystallography, Vol. 46, Issue 1
  • DOI: 10.1107/S0021889812047917

Photoreduction of manganese oxides in seawater
journal, April 1994


Substructure and superstructure of four-layer Ca-exchanged birnessite
journal, February 1998

  • Drits, Victor A.; Lanson, Bruno; Gorshkov, Anatoli I.
  • American Mineralogist, Vol. 83, Issue 1-2
  • DOI: 10.2138/am-1998-1-210

Bacteriogenic Manganese Oxides
journal, January 2010

  • Spiro, Thomas G.; Bargar, John R.; Sposito, Garrison
  • Accounts of Chemical Research, Vol. 43, Issue 1
  • DOI: 10.1021/ar800232a

Birnessite-type manganese oxides nanosheets with hole acceptor assisted photoelectrochemical activity in response to visible light
journal, January 2012

  • Hsu, Yu-Kuei; Chen, Ying-Chu; Lin, Yan-Gu
  • J. Mater. Chem., Vol. 22, Issue 6
  • DOI: 10.1039/c1jm14355g