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Title: Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries

Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleophilic-substitution-mediated polymerization or radical polymerization of monomers bearing six 1-vinylimidazolium cations. PIN-based solid-like electrolytes show good ionic conductivities (up to 5.32 × 10 -3 S cm -1 at 22 °C), wide electrochemical stability windows (up to 5.6 V), and good interfacial compatibility with the electrodes.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1] ;  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Advanced Materials (Online)
Additional Journal Information:
Journal Name: Advanced Materials (Online); Journal Volume: 27; Journal Issue: 48; Journal ID: ISSN 1521-4095
Publisher:
Wiley
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE
OSTI Identifier:
1234996

Zhang, Pengfei, Li, Mingtao, Jiang, Xueguang, Fang, Youxing, Veith, Gabriel M., Sun, Xiao-Guang, and Dai, Sheng. Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries. United States: N. p., Web. doi:10.1002/adma.201502855.
Zhang, Pengfei, Li, Mingtao, Jiang, Xueguang, Fang, Youxing, Veith, Gabriel M., Sun, Xiao-Guang, & Dai, Sheng. Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries. United States. doi:10.1002/adma.201502855.
Zhang, Pengfei, Li, Mingtao, Jiang, Xueguang, Fang, Youxing, Veith, Gabriel M., Sun, Xiao-Guang, and Dai, Sheng. 2015. "Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries". United States. doi:10.1002/adma.201502855. https://www.osti.gov/servlets/purl/1234996.
@article{osti_1234996,
title = {Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries},
author = {Zhang, Pengfei and Li, Mingtao and Jiang, Xueguang and Fang, Youxing and Veith, Gabriel M. and Sun, Xiao-Guang and Dai, Sheng},
abstractNote = {Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleophilic-substitution-mediated polymerization or radical polymerization of monomers bearing six 1-vinylimidazolium cations. PIN-based solid-like electrolytes show good ionic conductivities (up to 5.32 × 10-3 S cm-1 at 22 °C), wide electrochemical stability windows (up to 5.6 V), and good interfacial compatibility with the electrodes.},
doi = {10.1002/adma.201502855},
journal = {Advanced Materials (Online)},
number = 48,
volume = 27,
place = {United States},
year = {2015},
month = {11}
}