VUV action spectroscopy of protonated leucine-enkephalin peptide in the 6-14 eV range

Ranković, M. Lj.; Canon, F.; Nahon, L.; Giuliani, A.; Milosavljević, A. R.

doi:10.1063/1.4939080

Title: VUV action spectroscopy of protonated leucine-enkephalin peptide in the 6-14 eV range

Journal Article · Tue Dec 29 04:00:00 UTC 2015 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.4939080 · OSTI ID:1234511

Ranković, M. Lj. ^[1]; Canon, F. ^[2]; Nahon, L. ^[3]; Giuliani, A. ^[4];

^[5]

Univ. of Belgrade, Belgrade (Serbia); Radiation Laboratory, University of Notre Dame
UMR1324 Centre des Sciences du Gout et de l'Alimentation, Dijon (France)
SOLEIL, Gif sur Yvette Cedex (France)
SOLEIL, Gif sur Yvette Cedex (France); INRA, Nantes (France)
Univ. of Belgrade, Belgrade (Serbia); Univ. of Notre Dame, Notre Dame, IN (United States)

We have studied the VUV photodissociation of gas-phase protonated leucine-enkephalin peptide ion in the 5.7 to 14 eV photon energy range by coupling a linear quadrupole ion trap with a synchrotron radiation source. We report VUV activation tandem mass spectra at 6.7, 8.4 and 12.8 eV photon energies and photodissociation yields for a number of selected fragments. The obtained results provide insights into both near VUV radiation damage and electronic properties of a model peptide. We could distinguish several absorption bands and assign them to particular electronic transitions, according to previous theoretical studies. Furthermore, the photodissociation yields appear to be very different for the various observed fragmentation channels, depending both on the type of fragments and their position along the peptide backbone. The present results are discussed in light of recent gas-phase spectroscopic data on peptides.

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Research Organization:: Univ. of Notre Dame, Notre Dame, IN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FC02-04ER15533

OSTI ID:: 1234511

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 24 Vol. 143; ISSN JCPSA6; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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