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Title: Multi-scale entropic depletion phenomena in polymer liquids

Authors:
ORCiD logo [1];  [2]
  1. Department of Materials Science, University of Illinois, Urbana, Illinois 61801, USA
  2. Department of Materials Science, University of Illinois, Urbana, Illinois 61801, USA, Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA, Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1228622
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
The Journal of Chemical Physics
Additional Journal Information:
Journal Name: The Journal of Chemical Physics Journal Volume: 142 Journal Issue: 21; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Banerjee, Debapriya, and Schweizer, Kenneth S. Multi-scale entropic depletion phenomena in polymer liquids. United States: N. p., 2015. Web. doi:10.1063/1.4921747.
Banerjee, Debapriya, & Schweizer, Kenneth S. Multi-scale entropic depletion phenomena in polymer liquids. United States. https://doi.org/10.1063/1.4921747
Banerjee, Debapriya, and Schweizer, Kenneth S. Tue . "Multi-scale entropic depletion phenomena in polymer liquids". United States. https://doi.org/10.1063/1.4921747.
@article{osti_1228622,
title = {Multi-scale entropic depletion phenomena in polymer liquids},
author = {Banerjee, Debapriya and Schweizer, Kenneth S.},
abstractNote = {},
doi = {10.1063/1.4921747},
journal = {The Journal of Chemical Physics},
number = 21,
volume = 142,
place = {United States},
year = {Tue Jun 02 00:00:00 EDT 2015},
month = {Tue Jun 02 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1063/1.4921747

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Cited by: 6 works
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Works referenced in this record:

Molecular theories of polymer nanocomposites
journal, April 2010

  • Hall, Lisa M.; Jayaraman, Arthi; Schweizer, Kenneth S.
  • Current Opinion in Solid State and Materials Science, Vol. 14, Issue 2
  • DOI: 10.1016/j.cossms.2009.08.004

Derivation of an integral equation for pair correlation functions in molecular fluids
journal, September 1973

  • Chandler, David
  • The Journal of Chemical Physics, Vol. 59, Issue 5
  • DOI: 10.1063/1.1680393

Current and Future Nanotech Applications in the Oil Industry
journal, June 2012


Local structure of semiflexible polymer melts
journal, July 1990

  • Honnell, Kevin G.; Curro, John G.; Schweizer, Kenneth S.
  • Macromolecules, Vol. 23, Issue 14
  • DOI: 10.1021/ma00216a018

Anisotropic self-assembly of spherical polymer-grafted nanoparticles
journal, March 2009

  • Akcora, Pinar; Liu, Hongjun; Kumar, Sanat K.
  • Nature Materials, Vol. 8, Issue 4
  • DOI: 10.1038/nmat2404

Entropy driven phase transitions in colloid–polymer suspensions: Tests of depletion theories
journal, February 2002

  • Ramakrishnan, S.; Fuchs, M.; Schweizer, K. S.
  • The Journal of Chemical Physics, Vol. 116, Issue 5
  • DOI: 10.1063/1.1426413

The Role of Filler Networking in Dynamic Properties of Filled Rubber
journal, May 1999

  • Wang, Meng-Jiao
  • Rubber Chemistry and Technology, Vol. 72, Issue 2
  • DOI: 10.5254/1.3538812

Structure and effective interactions in polymer nanocomposite melts: An integral equation theory study
journal, April 2006

  • Zhao, Lei; Li, Yi-Gui; Zhong, Chongli
  • The Journal of Chemical Physics, Vol. 124, Issue 14
  • DOI: 10.1063/1.2187489

Monte Carlo Simulations of Polymer Melts Filled with Solid Nanoparticles
journal, March 2001


Role of Repulsive Forces in Determining the Equilibrium Structure of Simple Liquids
journal, June 1971

  • Weeks, John D.; Chandler, David; Andersen, Hans C.
  • The Journal of Chemical Physics, Vol. 54, Issue 12
  • DOI: 10.1063/1.1674820

Long Wavelength Concentration Fluctuations and Cage Scale Ordering of Nanoparticles in Concentrated Polymer Solutions
journal, December 2010

  • Kim, So Youn; Hall, Lisa M.; Schweizer, Kenneth S.
  • Macromolecules, Vol. 43, Issue 23
  • DOI: 10.1021/ma1021677

Effect of polymer adsorption and depletion on the interaction between two parallel surfaces
journal, July 1982


Integrating PRISM theory and Monte Carlo simulation to study polymer-functionalised particles and polymer nanocomposites
journal, July 2012


Theory of the Miscibility of Fullerenes in Random Copolymer Melts
journal, October 2013

  • Banerjee, Debapriya; Dadmun, Mark; Sumpter, Bobby
  • Macromolecules, Vol. 46, Issue 21
  • DOI: 10.1021/ma4017604

Structure, scattering patterns and phase behavior of polymer nanocomposites with nonspherical fillers
journal, January 2010

  • Hall, Lisa M.; Schweizer, Kenneth S.
  • Soft Matter, Vol. 6, Issue 5
  • DOI: 10.1039/b919160g

Many body effects on the phase separation and structure of dense polymer-particle melts
journal, June 2008

  • Hall, Lisa M.; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 128, Issue 23
  • DOI: 10.1063/1.2938379

Effective interactions between solid particles mediated by free polymer in solution
journal, August 2013

  • Shvets, A. A.; Semenov, A. N.
  • The Journal of Chemical Physics, Vol. 139, Issue 5
  • DOI: 10.1063/1.4816469

Integral equation theory for the adsorption of chain fluids in slitlike pores
journal, September 1991

  • Yethiraj, Arun; Hall, Carol K.
  • The Journal of Chemical Physics, Vol. 95, Issue 5
  • DOI: 10.1063/1.461797

Rheology and Microstructure of Polymer Nanocomposite Melts: Variation of Polymer Segment−Surface Interaction
journal, June 2010

  • Anderson, Benjamin J.; Zukoski, Charles F.
  • Langmuir, Vol. 26, Issue 11
  • DOI: 10.1021/la9044573

Rheology and Microstructure of an Unentangled Polymer Nanocomposite Melt
journal, December 2008

  • Anderson, Benjamin J.; Zukoski, Charles F.
  • Macromolecules, Vol. 41, Issue 23
  • DOI: 10.1021/ma801415e

Interaction between particles suspended in solutions of macromolecules
journal, December 1958


Origin of particle clustering in a simulated polymer nanocomposite and its impact on rheology
journal, July 2003

  • Starr, Francis W.; Douglas, Jack F.; Glotzer, Sharon C.
  • The Journal of Chemical Physics, Vol. 119, Issue 3
  • DOI: 10.1063/1.1580099

Nanoparticle Stability in Polymer Melts As Determined by Particle Second Virial Measurement
journal, July 2007

  • Anderson, Benjamin J.; Zukoski, Charles F.
  • Macromolecules, Vol. 40, Issue 14
  • DOI: 10.1021/ma0624346

Structure, surface excess and effective interactions in polymer nanocomposite melts and concentrated solutions
journal, October 2004

  • Hooper, J. B.; Schweizer, K. S.; Desai, T. G.
  • The Journal of Chemical Physics, Vol. 121, Issue 14
  • DOI: 10.1063/1.1790831

Liquid-State Theory of Semidilute and Concentrated Polymer Solutions
journal, April 1998

  • Chatterjee, Avik P.; Schweizer, Kenneth S.
  • Macromolecules, Vol. 31, Issue 7
  • DOI: 10.1021/ma971460o

Glass transition behavior of alumina/polymethylmethacrylate nanocomposites
journal, July 2002


Microscopic theory of polymer-mediated interactions between spherical particles
journal, December 1998

  • Chatterjee, Avik P.; Schweizer, Kenneth S.
  • The Journal of Chemical Physics, Vol. 109, Issue 23
  • DOI: 10.1063/1.477729

Integral equation theory of polymer melts: intramolecular structure, local order, and the correlation hole
journal, October 1988

  • Schweizer, Kenneth S.; Curro, John G.
  • Macromolecules, Vol. 21, Issue 10
  • DOI: 10.1021/ma00188a027

Chain Dimensions in Filled Polymers:  An Intriguing Problem
journal, October 2002


Concentration Fluctuations, Local Order, and the Collective Structure of Polymer Nanocomposites
journal, November 2009

  • Hall, Lisa M.; Anderson, Benjamin J.; Zukoski, Charles F.
  • Macromolecules, Vol. 42, Issue 21
  • DOI: 10.1021/ma901523w

Aggregation of colloidal particles induced by polymer chains: The RISM integral equation theory
journal, December 1997

  • Khalatur, P. G.; Zherenkova, L. V.; Khokhlov, A. R.
  • Physica A: Statistical Mechanics and its Applications, Vol. 247, Issue 1-4
  • DOI: 10.1016/S0378-4371(97)00406-8

Surface Tension of High‐Polymer Solutions
journal, July 1954

  • Oosawa, Fumio; Asakura, Sho
  • The Journal of Chemical Physics, Vol. 22, Issue 7
  • DOI: 10.1063/1.1740346

Amorphous Solidification in Polymer-Platelet Nanocomposites
journal, December 2002


Effects of polymer solutions on colloid stability
journal, June 1979

  • Joanny, J. F.; Leibler, L.; De Gennes, P. G.
  • Journal of Polymer Science: Polymer Physics Edition, Vol. 17, Issue 6
  • DOI: 10.1002/pol.1979.180170615

Depletion-induced phase separation in colloid–polymer mixtures
journal, March 2003


RISM theory of polymer liquids: Analytical results for continuum models of melts and alloys
journal, December 1990


General Strategies for Nanoparticle Dispersion
journal, March 2006


Effect of Nonadsorbed Polymer on the Stability of Weakly Flocculated Suspensions
journal, January 1996


Interaction between colloids in solutions containing dissolved polymer
journal, June 1992

  • Yethiraj, Arun; Hall, Carol K.; Dickman, Ronald
  • Journal of Colloid and Interface Science, Vol. 151, Issue 1
  • DOI: 10.1016/0021-9797(92)90241-D

One liquid, two glasses
journal, November 2002

  • Sciortino, Francesco
  • Nature Materials, Vol. 1, Issue 3
  • DOI: 10.1038/nmat752

Nanoscale effects leading to non-Einstein-like decrease in viscosity
journal, October 2003

  • Mackay, Michael E.; Dao, Tien T.; Tuteja, Anish
  • Nature Materials, Vol. 2, Issue 11
  • DOI: 10.1038/nmat999

Polymer–particle mixtures: Depletion and packing effects
journal, May 2004

  • Doxastakis, M.; Chen, Y-L.; Guzmán, O.
  • The Journal of Chemical Physics, Vol. 120, Issue 19
  • DOI: 10.1063/1.1704634

Structure and thermodynamics of colloid-polymer mixtures: A macromolecular approach
journal, September 2000


Small mesoscopic particles in dilute and semidilute solutions of nonadsorbing polymers
journal, January 2000

  • Eisenriegler, E.
  • The Journal of Chemical Physics, Vol. 113, Issue 12
  • DOI: 10.1063/1.1289239

Real Space Structure and Scattering Patterns of Model Polymer Nanocomposites
journal, September 2007

  • Hooper, Justin B.; Schweizer, Kenneth S.
  • Macromolecules, Vol. 40, Issue 19
  • DOI: 10.1021/ma071147e

Molecular Dynamics Simulation of a Polymer Melt with a Nanoscopic Particle
journal, May 2002

  • Starr, Francis W.; Schrøder, Thomas B.; Glotzer, Sharon C.
  • Macromolecules, Vol. 35, Issue 11
  • DOI: 10.1021/ma010626p

Matrix-induced nanoparticle interactions in a polymer melt: A molecular dynamics simulation study
journal, November 2003

  • Bedrov, Dmitry; Smith, Grant D.; Smith, James S.
  • The Journal of Chemical Physics, Vol. 119, Issue 19
  • DOI: 10.1063/1.1615965

Contact Aggregation, Bridging, and Steric Stabilization in Dense Polymer−Particle Mixtures
journal, October 2005

  • Hooper, Justin B.; Schweizer, Kenneth S.
  • Macromolecules, Vol. 38, Issue 21
  • DOI: 10.1021/ma051318k

Polymer Melts at Solid Surfaces
book, January 2002


Polymer Nanocomposites
journal, April 2007


Analytic solutions of the PRISM equations for Gaussian polymers
journal, April 1997

  • Fuchs, Matthias
  • Zeitschrift für Physik B Condensed Matter, Vol. 103, Issue 3
  • DOI: 10.1007/s002570050406

Density fluctuation correlation length in polymer fluids
journal, October 2003

  • Koshy, R.; Desai, T.; Keblinski, P.
  • The Journal of Chemical Physics, Vol. 119, Issue 14
  • DOI: 10.1063/1.1606673

Polymer‐induced forces between colloidal particles. A Monte Carlo simulation
journal, March 1994

  • Dickman, Ronald; Yethiraj, Arun
  • The Journal of Chemical Physics, Vol. 100, Issue 6
  • DOI: 10.1063/1.466251

Nanocomposites with Polymer Grafted Nanoparticles
journal, April 2013

  • Kumar, Sanat K.; Jouault, Nicolas; Benicewicz, Brian
  • Macromolecules, Vol. 46, Issue 9
  • DOI: 10.1021/ma4001385

Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials
journal, June 2000


Rheology and Microstructure of Entangled Polymer Nanocomposite Melts
journal, November 2009

  • Anderson, Benjamin J.; Zukoski, Charles F.
  • Macromolecules, Vol. 42, Issue 21
  • DOI: 10.1021/ma9011158

Depletion stabilization and depletion flocculation
journal, June 1980


Interactions between colloidal particles in polymer solutions: A density functional theory study
journal, September 2004

  • Patel, N.; Egorov, S. A.
  • The Journal of Chemical Physics, Vol. 121, Issue 10
  • DOI: 10.1063/1.1778671

On the Mechanism of Hydrodynamic Reinforcement in Elastic Composites
journal, November 2002


Many-body depletion interactions among protein spheres in a semidilute polymer solution
journal, February 1997

  • Odijk, Theo
  • The Journal of Chemical Physics, Vol. 106, Issue 8
  • DOI: 10.1063/1.473069

Theory of Phase Separation in Polymer Nanocomposites
journal, July 2006

  • Hooper, Justin B.; Schweizer, Kenneth S.
  • Macromolecules, Vol. 39, Issue 15
  • DOI: 10.1021/ma060577m

A molecular dynamics simulation study of nanoparticle interactions in a model polymer-nanoparticle composite
journal, August 2003


Chain Conformations and Bound-Layer Correlations in Polymer Nanocomposites
journal, March 2007


Statistical theory of the adsorption of interacting chain molecules. 1. Partition function, segment density distribution, and adsorption isotherms
journal, June 1979

  • Scheutjens, J. M. H. M.; Fleer, G. J.
  • The Journal of Physical Chemistry, Vol. 83, Issue 12
  • DOI: 10.1021/j100475a012