Identifying low-coverage surface species on supported noble metal nanoparticle catalysts by DNP-NMR

Johnson, Robert L.; Perras, Frédéric A.; Kobayashi, Takeshi; Schwartz, Thomas J.; Dumesic, James A.; Shanks, Brent H.; Pruski, Marek

doi:10.1039/C5CC06788J

Title: Identifying low-coverage surface species on supported noble metal nanoparticle catalysts by DNP-NMR

Journal Article · Fri Nov 20 04:00:00 UTC 2015 · ChemComm

DOI: https://doi.org/10.1039/C5CC06788J · OSTI ID:1227446

Johnson, Robert L. ^[1]; Perras, Frédéric A. ^[2]; Kobayashi, Takeshi ^[2]; Schwartz, Thomas J. ^[3]; Dumesic, James A. ^[3]; Shanks, Brent H. ^[1]; Pruski, Marek ^[4]

Iowa State Univ., Ames, IA (United States)
Ames Lab., Ames, IA (United States)
Univ. of Wisconsin, Madison, WI (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

DNP-NMR spectroscopy has been applied to enhance the signal for organic molecules adsorbed on γ-Al₂O₃-supported Pd nanoparticles. In addition, by offering >2500-fold time savings, the technique enabled the observation of ¹³C-¹³C cross-peaks for low coverage species, which were assigned to products from oxidative degradation of methionine adsorbed on the nanoparticle surface.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1227446

Report Number(s):: IS-J--8841

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 12 Vol. 5; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Understanding Surface and Interfacial Chemistry in Functional Nanomaterials via Solid-State NMR Marchetti, Alessandro; Chen, Juner; Pang, Zhenfeng Advanced Materials, Vol. 29, Issue 14 https://doi.org/10.1002/adma.201605895	journal	March 2017
Direct ¹⁷ O dynamic nuclear polarization of single-site heterogeneous catalysts Perras, Frédéric A.; Boteju, Kasuni C.; Slowing, Igor I. Chemical Communications, Vol. 54, Issue 28 https://doi.org/10.1039/c8cc00293b	journal	January 2018
Room temperature CO oxidation catalysed by supported Pt nanoparticles revealed by solid-state NMR and DNP spectroscopy Klimavicius, Vytautas; Neumann, Sarah; Kunz, Sebastian Catalysis Science & Technology, Vol. 9, Issue 14 https://doi.org/10.1039/c9cy00684b	journal	January 2019

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