Dynamic nuclear polarization solid-state NMR in heterogeneous catalysis research

Kobayashi, Takeshi; Perras, Frédéric A.; Slowing, Igor I.; Sadow, Aaron D.; Pruski, Marek

doi:10.1021/acscatal.5b02039

Title: Dynamic nuclear polarization solid-state NMR in heterogeneous catalysis research

Journal Article · 19 October 2015 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.5b02039 · OSTI ID:1227432

Kobayashi, Takeshi ^[1]; Perras, Frédéric A. ^[1]; Slowing, Igor I. ^[2]; Sadow, Aaron D. ^[2]; Pruski, Marek ^[2]

Ames Lab., Ames, IA (United States)
Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

In this study, a revolution in solid-state nuclear magnetic resonance (SSNMR) spectroscopy is taking place, attributable to the rapid development of high-field dynamic nuclear polarization (DNP), a technique yielding sensitivity improvements of 2–3 orders of magnitude. This higher sensitivity in SSNMR has already impacted materials research, and the implications of new methods on catalytic sciences are expected to be profound.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1227432

Report Number(s):: IS-J-8825

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (65)

Beyond the Silica Surface by Direct Silicon-29 Dynamic Nuclear Polarization Lafon, Olivier; Rosay, Melanie; Aussenac, Fabien Angewandte Chemie International Edition, Vol. 50, Issue 36 https://doi.org/10.1002/anie.201101841	journal	July 2011
Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks Rossini, Aaron J.; Zagdoun, Alexandre; Lelli, Moreno Angewandte Chemie International Edition, Vol. 51, Issue 1 https://doi.org/10.1002/anie.201106030	journal	November 2011
Rapid Natural-Abundance 2D ¹³ C- ¹³ C Correlation Spectroscopy Using Dynamic Nuclear Polarization Enhanced Solid-State NMR and Matrix-Free Sample Preparation Takahashi, Hiroki; Lee, Daniel; Dubois, Lionel Angewandte Chemie International Edition, Vol. 51, Issue 47 https://doi.org/10.1002/anie.201206102	journal	October 2012
Highly Efficient, Water-Soluble Polarizing Agents for Dynamic Nuclear Polarization at High Frequency Sauvée, Claire; Rosay, Melanie; Casano, Gilles Angewandte Chemie International Edition, Vol. 52, Issue 41 https://doi.org/10.1002/anie.201304657	journal	August 2013
Quantitative Structural Constraints for Organic Powders at Natural Isotopic Abundance Using Dynamic Nuclear Polarization Solid-State NMR Spectroscopy Mollica, Giulia; Dekhil, Myriam; Ziarelli, Fabio Angewandte Chemie International Edition, Vol. 54, Issue 20 https://doi.org/10.1002/anie.201501172	journal	March 2015
Efficient Dynamic Nuclear Polarization at 800 MHz/527 GHz with Trityl-Nitroxide Biradicals Mathies, Guinevere; Caporini, Marc A.; Michaelis, Vladimir K. Angewandte Chemie International Edition, Vol. 54, Issue 40 https://doi.org/10.1002/anie.201504292	journal	August 2015
Highly Dispersed SiO _x /Al ₂ O ₃ Catalysts Illuminate the Reactivity of Isolated Silanol Sites Mouat, Aidan R.; George, Cassandra; Kobayashi, Takeshi Angewandte Chemie International Edition, Vol. 54, Issue 45 https://doi.org/10.1002/anie.201505452	journal	September 2015
Selective Host-Guest Interaction between Metal Ions and Metal-Organic Frameworks Using Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy Guo, Zhiyong; Kobayashi, Takeshi; Wang, Lin-Lin Chemistry - A European Journal, Vol. 20, Issue 49 https://doi.org/10.1002/chem.201403884	journal	October 2014
A Spectrometer for Dynamic Nuclear Polarization and Electron Paramagnetic Resonance at High Frequencies Becerra, L. R.; Gerfen, G. J.; Bellew, B. F. Journal of Magnetic Resonance, Series A, Vol. 117, Issue 1 https://doi.org/10.1006/jmra.1995.9975	journal	November 1995
Sensitivity Enhancement in Solid State 15N NMR by Indirect Detection with High-Speed Magic Angle Spinning Ishii, Yoshitaka; Tycko, Robert Journal of Magnetic Resonance, Vol. 142, Issue 1 https://doi.org/10.1006/jmre.1999.1976	journal	January 2000
Solid State NMR of Porous Materials Koller, Hubert; Weiß, Mark Topics in Current Chemistry https://doi.org/10.1007/128_2011_123	book	January 2011
Probing Quadrupolar Nuclei by Solid-State NMR Spectroscopy: Recent Advances Fernandez, Christian; Pruski, Marek Solid State NMR: Topics in Current Chemistry https://doi.org/10.1007/128_2011_141	book	January 2011
Magic-angle spinning and polarization transfer in proton-enhanced NMR Stejskal, E. O.; Schaefer, Jacob; Waugh, J. S. Journal of Magnetic Resonance (1969), Vol. 28, Issue 1 https://doi.org/10.1016/0022-2364(77)90260-8	journal	October 1977
Applications of dynamic nuclear polarization in 13C NMR in solids Wind, R. A.; Duijvestijn, M. J.; van der Lugt, C. Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 17 https://doi.org/10.1016/0079-6565(85)80005-4	journal	January 1985
Cryogenic sample exchange NMR probe for magic angle spinning dynamic nuclear polarization Barnes, Alexander B.; Mak-Jurkauskas, Melody L.; Matsuki, Yoh Journal of Magnetic Resonance, Vol. 198, Issue 2 https://doi.org/10.1016/j.jmr.2009.03.003	journal	June 2009
Is solid-state NMR enhanced by dynamic nuclear polarization? Lee, Daniel; Hediger, Sabine; De Paëpe, Gaël Solid State Nuclear Magnetic Resonance, Vol. 66-67 https://doi.org/10.1016/j.ssnmr.2015.01.003	journal	April 2015
Dynamic Nuclear Polarization Surface Enhanced NMR Spectroscopy Rossini, Aaron J.; Zagdoun, Alexandre; Lelli, Moreno Accounts of Chemical Research, Vol. 46, Issue 9 https://doi.org/10.1021/ar300322x	journal	March 2013
NMR at Low and Ultralow Temperatures Tycko, Robert Accounts of Chemical Research, Vol. 46, Issue 9 https://doi.org/10.1021/ar300358z	journal	March 2013
High-Frequency Dynamic Nuclear Polarization in MAS Spectra of Membrane and Soluble Proteins Rosay, Melanie; Lansing, Jonathan C.; Haddad, Kristin C. Journal of the American Chemical Society, Vol. 125, Issue 45 https://doi.org/10.1021/ja036898k	journal	November 2003
Dynamic Nuclear Polarization with Biradicals Hu, Kan-Nian; Yu, Hsiao-hua; Swager, Timothy M. Journal of the American Chemical Society, Vol. 126, Issue 35 https://doi.org/10.1021/ja039749a	journal	September 2004
TOTAPOL: A Biradical Polarizing Agent for Dynamic Nuclear Polarization Experiments in Aqueous Media Song, Changsik; Hu, Kan-Nian; Joo, Chan-Gyu Journal of the American Chemical Society, Vol. 128, Issue 35 https://doi.org/10.1021/ja061284b	journal	September 2006
Dynamic Nuclear Polarization of Amyloidogenic Peptide Nanocrystals: GNNQQNY, a Core Segment of the Yeast Prion Protein Sup35p van der Wel, Patrick C. A.; Hu, Kan-Nian; Lewandowski, Józef Journal of the American Chemical Society, Vol. 128, Issue 33 https://doi.org/10.1021/ja0626685	journal	August 2006
Chemical Shift Correlation NMR Spectroscopy with Indirect Detection in Fast Rotating Solids: Studies of Organically Functionalized Mesoporous Silicas Wiench, Jerzy W.; Bronnimann, Charles E.; Lin, Victor S. -Y Journal of the American Chemical Society, Vol. 129, Issue 40, p. 12076-12077 https://doi.org/10.1021/ja074746+	journal	September 2007
Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization Lesage, Anne; Lelli, Moreno; Gajan, David Journal of the American Chemical Society, Vol. 132, Issue 44 https://doi.org/10.1021/ja104771z	journal	November 2010
Fast Characterization of Functionalized Silica Materials by Silicon-29 Surface-Enhanced NMR Spectroscopy Using Dynamic Nuclear Polarization Lelli, Moreno; Gajan, David; Lesage, Anne Journal of the American Chemical Society, Vol. 133, Issue 7 https://doi.org/10.1021/ja110791d	journal	February 2011
A Slowly Relaxing Rigid Biradical for Efficient Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy: Expeditious Characterization of Functional Group Manipulation in Hybrid Materials Zagdoun, Alexandre; Casano, Gilles; Ouari, Olivier Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja210177v	journal	January 2012
¹⁷ O NMR Gives Unprecedented Insights into the Structure of Supported Catalysts and Their Interaction with the Silica Carrier Merle, Nicolas; Trébosc, Julien; Baudouin, Anne Journal of the American Chemical Society, Vol. 134, Issue 22 https://doi.org/10.1021/ja301085m	journal	May 2012
Enhanced Solid-State NMR Correlation Spectroscopy of Quadrupolar Nuclei Using Dynamic Nuclear Polarization Lee, Daniel; Takahashi, Hiroki; Thankamony, Aany S. L. Journal of the American Chemical Society, Vol. 134, Issue 45 https://doi.org/10.1021/ja307755t	journal	October 2012
Dynamic Nuclear Polarization NMR Spectroscopy of Microcrystalline Solids Rossini, Aaron J.; Zagdoun, Alexandre; Hegner, Franziska Journal of the American Chemical Society, Vol. 134, Issue 40 https://doi.org/10.1021/ja308135r	journal	September 2012
High-Field ¹³ C Dynamic Nuclear Polarization with a Radical Mixture Michaelis, Vladimir K.; Smith, Albert A.; Corzilius, Björn Journal of the American Chemical Society, Vol. 135, Issue 8 https://doi.org/10.1021/ja312265x	journal	February 2013
Dynamic Nuclear Polarization Enhanced Natural Abundance ¹⁷ O Spectroscopy Blanc, Frédéric; Sperrin, Luke; Jefferson, David A. Journal of the American Chemical Society, Vol. 135, Issue 8 https://doi.org/10.1021/ja4004377	journal	February 2013
Large Molecular Weight Nitroxide Biradicals Providing Efficient Dynamic Nuclear Polarization at Temperatures up to 200 K Zagdoun, Alexandre; Casano, Gilles; Ouari, Olivier Journal of the American Chemical Society, Vol. 135, Issue 34 https://doi.org/10.1021/ja405813t	journal	August 2013
Dynamic Nuclear Polarization Enhanced NMR Spectroscopy for Pharmaceutical Formulations Rossini, Aaron J.; Widdifield, Cory M.; Zagdoun, Alexandre Journal of the American Chemical Society, Vol. 136, Issue 6 https://doi.org/10.1021/ja4092038	journal	January 2014
Dynamic Nuclear Polarization NMR Enables the Analysis of Sn-Beta Zeolite Prepared with Natural Abundance ¹¹⁹ Sn Precursors Gunther, William R.; Michaelis, Vladimir K.; Caporini, Marc A. Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja502113d	journal	April 2014
Dynamic Nuclear Polarization of ¹ H, ¹³ C, and ⁵⁹ Co in a Tris(ethylenediamine)cobalt(III) Crystalline Lattice Doped with Cr(III) Corzilius, Björn; Michaelis, Vladimir K.; Penzel, Susanne A. Journal of the American Chemical Society, Vol. 136, Issue 33 https://doi.org/10.1021/ja5044374	journal	August 2014
Untangling the Condensation Network of Organosiloxanes on Nanoparticles using 2D ²⁹ Si– ²⁹ Si Solid-State NMR Enhanced by Dynamic Nuclear Polarization Lee, Daniel; Monin, Guillaume; Duong, Nghia Tuan Journal of the American Chemical Society, Vol. 136, Issue 39 https://doi.org/10.1021/ja506688m	journal	September 2014
Influences of Dilute Organic Adsorbates on the Hydration of Low-Surface-Area Silicates Sangodkar, Rahul P.; Smith, Benjamin J.; Gajan, David Journal of the American Chemical Society, Vol. 137, Issue 25 https://doi.org/10.1021/jacs.5b00622	journal	June 2015
Natural Abundance ¹⁷ O DNP Two-Dimensional and Surface-Enhanced NMR Spectroscopy Perras, Frédéric A.; Kobayashi, Takeshi; Pruski, Marek Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b03905	journal	June 2015
Atomic Description of the Interface between Silica and Alumina in Aluminosilicates through Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy and First-Principles Calculations Valla, Maxence; Rossini, Aaron J.; Caillot, Maxime Journal of the American Chemical Society, Vol. 137, Issue 33 https://doi.org/10.1021/jacs.5b06134	journal	August 2015
Mesoporous Silica Nanoparticles Loaded with Surfactant: Low Temperature Magic Angle Spinning ¹³ C and ²⁹ Si NMR Enhanced by Dynamic Nuclear Polarization Lafon, Olivier; Thankamony, Aany S. Lilly; Kobayashi, Takeshi The Journal of Physical Chemistry C, Vol. 117, Issue 3 https://doi.org/10.1021/jp310109s	journal	January 2013
Dynamic Nuclear Polarization of ¹⁷ O: Direct Polarization Michaelis, Vladimir K.; Corzilius, Björn; Smith, Albert A. The Journal of Physical Chemistry B, Vol. 117, Issue 48 https://doi.org/10.1021/jp408440z	journal	November 2013
Primostrato Solid-State NMR Enhanced by Dynamic Nuclear Polarization: Pentacoordinated Al ³⁺ Ions Are Only Located at the Surface of Hydrated γ-Alumina Lee, Daniel; Duong, Nghia Tuan; Lafon, Olivier The Journal of Physical Chemistry C, Vol. 118, Issue 43 https://doi.org/10.1021/jp508009x	journal	October 2014
Dynamic Nuclear Polarization of Oxygen-17 Michaelis, Vladimir K.; Markhasin, Evgeny; Daviso, Eugenio The Journal of Physical Chemistry Letters, Vol. 3, Issue 15 https://doi.org/10.1021/jz300742w	journal	July 2012
Dynamic Nuclear Polarization NMR of Low-γ Nuclei: Structural Insights into Hydrated Yttrium-Doped BaZrO ₃ Blanc, Frédéric; Sperrin, Luke; Lee, Daniel The Journal of Physical Chemistry Letters, Vol. 5, Issue 14 https://doi.org/10.1021/jz5007669	journal	June 2014
Mechanism of DNP-enhanced polarization transfer across the interface of polycarbonate/polystyrene heterogeneous blends Afeworki, Mobae; Schaefer, Jacob Macromolecules, Vol. 25, Issue 16 https://doi.org/10.1021/ma00042a007	journal	August 1992
Unraveling the Core–Shell Structure of Ligand-Capped Sn/SnO _x Nanoparticles by Surface-Enhanced Nuclear Magnetic Resonance, Mössbauer, and X-ray Absorption Spectroscopies Protesescu, Loredana; Rossini, Aaron J.; Kriegner, Dominik ACS Nano, Vol. 8, Issue 3 https://doi.org/10.1021/nn406344n	journal	February 2014
Non-aqueous solvents for DNP surface enhanced NMR spectroscopy Zagdoun, Alexandre; Rossini, Aaron J.; Gajan, David Chem. Commun., Vol. 48, Issue 5 https://doi.org/10.1039/C1CC15242D	journal	January 2012
Probing ²⁷ Al– ¹³ C proximities in metal–organic frameworks using dynamic nuclear polarization enhanced NMR spectroscopy Pourpoint, Frédérique; Thankamony, Aany Sofia Lilly; Volkringer, Christophe Chem. Commun., Vol. 50, Issue 8 https://doi.org/10.1039/C3CC47208F	journal	January 2014
Silica-surface reorganization during organotin grafting evidenced by ¹¹⁹ Sn DNP SENS: a tandem reaction of gem-silanols and strained siloxane bridges Conley, Matthew P.; Rossini, Aaron J.; Comas-Vives, Aleix Phys. Chem. Chem. Phys., Vol. 16, Issue 33 https://doi.org/10.1039/C4CP01973C	journal	January 2014
Solid state ¹⁷ O NMR—an introduction to the background principles and applications to inorganic materials Ashbrook, Sharon E.; Smith, Mark E. Chem. Soc. Rev., Vol. 35, Issue 8 https://doi.org/10.1039/b514051j	journal	January 2006
High field dynamic nuclear polarization—the renaissance Griffin, R. G.; Prisner, T. F. Physical Chemistry Chemical Physics, Vol. 12, Issue 22 https://doi.org/10.1039/c0cp90019b	journal	January 2010
Matrix-free dynamic nuclear polarization enables solid-state NMR 13C–13C correlation spectroscopy of proteins at natural isotopic abundance Takahashi, Hiroki; Hediger, Sabine; De Paëpe, Gaël Chemical Communications, Vol. 49, Issue 82 https://doi.org/10.1039/c3cc45195j	journal	January 2013
Analysis of sensitivity enhancement by dynamic nuclear polarization in solid-state NMR: a case study of functionalized mesoporous materials Kobayashi, Takeshi; Lafon, Olivier; Lilly Thankamony, Aany S. Physical Chemistry Chemical Physics, Vol. 15, Issue 15 https://doi.org/10.1039/c3cp00039g	journal	January 2013
Dynamic nuclear polarisation enhanced ¹⁴ N overtone MAS NMR spectroscopy Rossini, Aaron J.; Emsley, Lyndon; O'Dell, Luke A. Phys. Chem. Chem. Phys., Vol. 16, Issue 25 https://doi.org/10.1039/c4cp00590b	journal	January 2014
Pushing NMR sensitivity limits using dynamic nuclear polarization with closed-loop cryogenic helium sample spinning Bouleau, E.; Saint-Bonnet, P.; Mentink-Vigier, F. Chemical Science, Vol. 6, Issue 12 https://doi.org/10.1039/c5sc02819a	journal	January 2015
Mechanism of dynamic nuclear polarization in high magnetic fields Farrar, C. T.; Hall, D. A.; Gerfen, G. J. The Journal of Chemical Physics, Vol. 114, Issue 11 https://doi.org/10.1063/1.1346640	journal	March 2001
Proton‐Enhanced Nuclear Induction Spectroscopy. A Method for High Resolution NMR of Dilute Spins in Solids Pines, A.; Gibby, M. G.; Waugh, J. S. The Journal of Chemical Physics, Vol. 56, Issue 4 https://doi.org/10.1063/1.1677439	journal	February 1972
Dynamic nuclear polarization at high magnetic fields Maly, Thorsten; Debelouchina, Galia T.; Bajaj, Vikram S. The Journal of Chemical Physics, Vol. 128, Issue 5 https://doi.org/10.1063/1.2833582	journal	February 2008
Overhauser effects in insulating solids Can, T. V.; Caporini, M. A.; Mentink-Vigier, F. The Journal of Chemical Physics, Vol. 141, Issue 6 https://doi.org/10.1063/1.4891866	journal	August 2014
Polarization of Nuclear Spins in Metals Carver, T. R.; Slichter, C. P. Physical Review, Vol. 92, Issue 1 https://doi.org/10.1103/PhysRev.92.212.2	journal	October 1953
Polarization of Nuclei in Metals Overhauser, Albert W. Physical Review, Vol. 92, Issue 2 https://doi.org/10.1103/PhysRev.92.411	journal	October 1953
Dynamic nuclear polarization with an inhomogeneously broadened ESR line. I. Theory Wollan, David S. Physical Review B, Vol. 13, Issue 9 https://doi.org/10.1103/PhysRevB.13.3671	journal	May 1976
New Effect in Dynamic Polarization Hwang, Chester F.; Hill, D. A. Physical Review Letters, Vol. 18, Issue 4 https://doi.org/10.1103/PhysRevLett.18.110	journal	January 1967
Operational characteristics of a 14-W 140-GHz gyrotron for dynamic nuclear polarization Joye, C. D.; Griffin, R. G.; Hornstein, M. K. IEEE Transactions on Plasma Science, Vol. 34, Issue 3 https://doi.org/10.1109/TPS.2006.875776	journal	June 2006
Polarization-Enhanced NMR Spectroscopy of Biomolecules in Frozen Solution Hall, Dennis A.; Maus, Douglas C.; Gerfen, Gary J. Science, Vol. 276, Issue 5314 https://doi.org/10.1126/science.276.5314.930	journal	May 1997

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75 CONDENSED MATTER PHYSICS
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Title: Dynamic nuclear polarization solid-state NMR in heterogeneous catalysis research

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