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Title: Recent advances of lanthanum-based perovskite oxides for catalysis

Journal Article · · ACS Catalysis
 [1];  [1];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent development of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1222575
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 5 Vol. 5; ISSN 2155-5435
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (137)

Patterning Porous Oxides within Microchannel Networks journal March 2001
Tuning Nanoparticle Catalysis for the Oxygen Reduction Reaction journal June 2013
Synthesis of Perovskite-Based Porous La 0.75 Sr 0.25 MnO 3 Nanotubes as a Highly Efficient Electrocatalyst for Rechargeable Lithium-Oxygen Batteries journal February 2013
A Bifunctional Perovskite Catalyst for Oxygen Reduction and Evolution journal March 2014
In Situ Observation of Surface Species on Iridium Oxide Nanoparticles during the Oxygen Evolution Reaction journal May 2014
Hydrogénations et déshydrogénations par catalyse journal July 1911
Catalytic Oxidation of Carbon Monoxide over Transition Metal Oxides journal December 2010
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces journal March 2011
Kinetics of Methanol Oxidation over Mesoporous Perovskite Catalysts journal February 2012
Effect of Textural Structure on the Catalytic Performance of LaCoO 3 for CO Oxidation journal April 2014
Porous Carbon Supports: Recent Advances with Various Morphologies and Compositions journal August 2015
Electrocatalytic Oxygen Reduction Reaction on Perovskite Oxides: Series versus Direct Pathway journal May 2014
Surface Profile Control of FeNiPt/Pt Core/Shell Nanowires for Oxygen Reduction Reaction journal March 2015
Synthesis of LaMnO3+δby Firing Gels Using Citric Acid journal February 1997
Characterization of perovskite-type oxide catalysts RECoO3 by TPR journal March 1986
Nano-sized La0.8Sr0.2MnO3 as oxygen reduction catalyst in nonaqueous Li/O2 batteries journal September 2011
Structure-dependent electrocatalytic activity of La1-x Sr x MnO3 for oxygen reduction reaction journal March 2015
The surface chemistry of some perovskite oxides journal June 1981
Catalytic properties of La1 $minus; xA$prime;xFeO3(A$prime; = Sr,Ce) and La1 $minus; xCexCoO3 journal June 1985
Catalytic properties of La1$minus;xA$prime;xMnO3 (A$prime; = Sr, Ce, Hf) journal March 1986
Oxydes mixtes ou en solution solide sous forme très divisée obtenus par décomposition thermique de précurseurs amorphes journal January 1973
Effect of electrode materials on the properties of high-temperature solid electrolyte fuel cells journal August 1981
Influence of the method of preparation on the porous structure of perovskite oxides journal December 1986
Supported perovskites journal December 1990
Solid state surface studies of the electrocatalysis of oxygen evolution on perovskites journal July 1983
Surface characterization of LaCoO3 synthesized using citric acid journal January 2002
Mechanochemical synthesis of LaCrO3 by grinding constituent oxides journal January 2002
Mechanism and kinetics of oxygen reduction on porous La1−Sr CoO3− electrodes journal August 1998
Synthesis and properties of La1−xSrxFeO3 journal November 1999
Mechanochemical synthesis of LaMnO3 from La2O3 and Mn2O3 powders journal February 2000
Role of bulk and surface structures of La1−xSrxNiO3 perovskite-type oxides in methane combustion journal September 2001
Alumina supported, perovskite oxide based catalytic materials and their auto-exhaust application journal September 2001
Methane combustion on some perovskite-like mixed oxides journal March 1998
Surface properties and catalytic performance in methane combustion of Sr-substituted lanthanum manganites journal February 2000
Preparation and characterisation of supported La0.8Sr0.2MnO3+x journal March 2001
Hydrogen peroxide decomposition over Ln1−xAxMnO3 (Ln = La or Nd and A = K or Sr) perovskites journal July 2001
Evidence of phase cooperation in the LaCoO3–CeO2–Co3O4 catalytic system in relation to activity in methane combustion journal May 2002
XAS characterization and CO oxidation on zirconia-supported LaFeO3 perovskite journal September 2002
Mesoporous silica supported LaCoO3 perovskites as catalysts for methane oxidation journal July 2002
Supported Co-based perovskites as catalysts for total oxidation of methane journal March 2005
Characterization and catalytic properties of nanosized cobaltate particles prepared by in situ synthesis inside mesoporous molecular sieves journal September 2006
In situ hydrothermally synthesized mesoporous LaCoO3/SBA-15 catalysts: High activity for the complete oxidation of toluene and ethyl acetate journal January 2009
Three-dimensionally ordered macroporous SrFeO3−δ with high surface area: Active catalysts for the complete oxidation of toluene journal May 2012
A comparative study of bulk and 3DOM-structured Co3O4, Eu0.6Sr0.4FeO3, and Co3O4/Eu0.6Sr0.4FeO3: Preparation, characterization, and catalytic activities for toluene combustion journal December 2012
Supported perovskites for total oxidation of toluene journal September 2005
Ceria-based oxides as supports for LaCoO3 perovskite; catalysts for total oxidation of VOC journal January 2007
LaCoO3: Effect of synthesis conditions on properties and reactivity journal March 2007
High specific surface area LaFeCo perovskites—Synthesis by nanocasting and catalytic behavior in the reduction of NO with CO journal August 2009
Catalytic combustion of methane on nano-structured perovskite-type oxides fabricated by ultrasonic spray combustion journal February 2010
Three-dimensionally ordered macroporous Eu0.6Sr0.4FeO3 supported cobalt oxides: Highly active nanocatalysts for the combustion of toluene journal January 2013
CO oxidation on perovskite-type LaCoO3 synthesized using ethylene glycol and citric acid journal May 2008
PMMA-templating preparation and catalytic properties of high-surface-area three-dimensional macroporous La2CuO4 for methane combustion journal October 2011
Dual role of carbon in the catalytic layers of perovskite/carbon composites for the electrocatalytic oxygen reduction reaction journal July 2012
Nanocrystalline LaCoO3 perovskite particles confined in SBA-15 silica as a new efficient catalyst for hydrocarbon oxidation journal February 2005
Easy synthesis of three-dimensionally ordered macroporous La1−xKxCoO3 catalysts and their high activities for the catalytic combustion of soot journal August 2011
Controlled preparation and high catalytic performance of three-dimensionally ordered macroporous LaMnO3 with nanovoid skeletons for the combustion of toluene journal March 2012
Electrolysis of water on oxide surfaces journal September 2007
Bifunctional oxygen/air electrodes journal April 2006
Activity of perovskite La1−xSrxMnO3 catalysts towards oxygen reduction in alkaline electrolytes journal March 2009
Preparation of La1−Ca MnO3 perovskite–graphene composites as oxygen reduction reaction electrocatalyst in alkaline medium journal December 2014
Sol–gel based Pechini method synthesis and characterization of Sm1−xCaxFeO3 perovskite 0.1≤x≤0.5 journal October 2012
Precise oxygen evolution catalysts: Status and opportunities journal March 2014
Boosting Oxygen Reduction Reaction Activity of Palladium by Stabilizing Its Unusual Oxidation States in Perovskite journal April 2015
Highly Active Epitaxial La (1– x ) Sr x MnO 3 Surfaces for the Oxygen Reduction Reaction: Role of Charge Transfer journal April 2015
New Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid journal March 2015
Design of Highly Active Perovskite Oxides for Oxygen Evolution Reaction by Combining Experimental and ab Initio Studies journal June 2015
Perovskites by Design:  A Toolbox of Solid-State Reactions journal April 2002
A Macroporous Perovskite Manganite from Colloidal Templates with a Curie Temperaure of 320 K journal May 2003
Facile Procedure To Prepare Three-Dimensionally Ordered Macroporous (3DOM) Perovskite-type Mixed Metal Oxides by Colloidal Crystal Templating Method journal June 2005
Influence of the Arrangement of the Octahedrally Coordinated Trivalent Cobalt Cations on the Electrical Charge Transport and Surface Reactivity journal July 2010
Supramolecular Aggregates as Templates: Ordered Mesoporous Polymers and Carbons journal February 2008
Factors Governing Oxygen Reduction in Solid Oxide Fuel Cell Cathodes journal October 2004
Solar Water Splitting Cells journal November 2010
Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality journal September 2014
Chemical Structures and Performance of Perovskite Oxides journal July 2001
Electrocatalysts for Nonaqueous Lithium–Air Batteries: Status, Challenges, and Perspective journal April 2012
Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis journal August 2014
Mechanism and Tafel Lines of Electro-Oxidation of Water to Oxygen on RuO 2 (110) journal December 2010
CO Oxidation on Inverse CeO x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O 2 journal March 2011
Structure-Induced Enhancement in Electrooxidation of Trimetallic FePtAu Nanoparticles journal March 2012
Synthetic Control of FePtM Nanorods (M = Cu, Ni) To Enhance the Oxygen Reduction Reaction journal May 2013
Tuning Nanoparticle Structure and Surface Strain for Catalysis Optimization journal May 2014
Structure–Property Relationship of Bifunctional MnO 2 Nanostructures: Highly Efficient, Ultra-Stable Electrochemical Water Oxidation and Oxygen Reduction Reaction Catalysts Identified in Alkaline Media journal August 2014
Lab-in-a-Shell: Encapsulating Metal Clusters for Size Sieving Catalysis journal August 2014
Monodisperse Core/Shell Ni/FePt Nanoparticles and Their Conversion to Ni/Pt to Catalyze Oxygen Reduction journal November 2014
Constructing Hierarchical Interfaces: TiO 2 -Supported PtFe–FeO x Nanowires for Room Temperature CO Oxidation journal August 2015
Oxygen Reduction Reaction Activity of La-Based Perovskite Oxides in Alkaline Medium: A Thin-Film Rotating Ring-Disk Electrode Study journal February 2012
Combustion of Methane over Palladium-Based Catalysts: Catalytic Deactivation and Role of the Support journal April 2012
Design Insights for Tuning the Electrocatalytic Activity of Perovskite Oxides for the Oxygen Evolution Reaction journal April 2015
Nanocasted Synthesis of Mesoporous LaCoO 3 Perovskite with Extremely High Surface Area and Excellent Activity in Methane Combustion journal September 2008
Synthesis and Activities of Rutile IrO 2 and RuO 2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions journal January 2012
Highly Active, Nonprecious Metal Perovskite Electrocatalysts for Bifunctional Metal–Air Battery Electrodes journal March 2013
Enhancing Bi-functional Electrocatalytic Activity of Perovskite by Temperature Shock: A Case Study of LaNiO 3−δ journal August 2013
Highly Active and Durable Core–Corona Structured Bifunctional Catalyst for Rechargeable Metal–Air Battery Application journal January 2012
Monodisperse M x Fe 3– x O 4 (M = Fe, Cu, Co, Mn) Nanoparticles and Their Electrocatalysis for Oxygen Reduction Reaction journal May 2013
Low-cost Oxygen Electrode Material journal May 1970
Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries journal June 2011
A general approach to crystalline and monomodal pore size mesoporous materials journal December 2013
Redox activity of surface oxygen anions in oxygen-deficient perovskite oxides during electrochemical reactions journal January 2015
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces journal February 2007
Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes journal June 2014
Heterogeneous photocatalyst materials for water splitting journal January 2009
Ionic liquid-mediated synthesis of meso-scale porous lanthanum-transition-metal perovskites with high CO oxidation performance journal January 2015
Active LaNi 1−x Fe x O 3 bifunctional catalysts for air cathodes in alkaline media journal January 2015
Large magnetoresistance in three dimensionally ordered macroporous perovskite manganites prepared by a colloidal templating method journal January 2004
Enhanced catalytic activity of perovskite oxide nanofibers for combustion of methane in coal mine ventilation air journal January 2010
Carbon monoxide oxidation at room temperature on Pt/CeO2–ZrO2–Bi2O3 catalysts journal January 2011
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts journal January 2012
Novel oxygen carriers for chemical looping combustion: La1−xCexBO3 (B = Co, Mn) perovskites synthesized by reactive grinding and nanocasting journal January 2011
Perovskite Sr0.95Ce0.05CoO3−δ loaded with copper nanoparticles as a bifunctional catalyst for lithium-air batteries journal January 2012
Oxygen electrocatalysis on (001)-oriented manganese perovskite films: Mn valency and charge transfer at the nanoscale journal January 2013
3D ordered macroporous LaFeO3 as efficient electrocatalyst for Li–O2 batteries with enhanced rate capability and cyclic performance journal January 2014
Chemisorption and catalysis on LaMO3 oxides
  • Kremenić, Gojko; Nieto, José M. L.; Tascón, Juan M. D.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 81, Issue 4 https://doi.org/10.1039/f19858100939
journal January 1985
Hierarchical mesoporous perovskite La0.5Sr0.5CoO2.91 nanowires with ultrahigh capacity for Li-air batteries journal November 2012
Crystal and Ligand Field Models of Solid Catalysts journal January 1972
Strontium-Doped Perovskites Rival Platinum Catalysts for Treating NOx in Simulated Diesel Exhaust journal March 2010
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles journal October 2011
Optimizing Perovskites for the Water-Splitting Reaction journal December 2011
Preparation of LaMnO3-CNF and Its Activity for Oxygen Electrode Reaction in 0.1 mol dm-3 KOH Solution journal April 2015
Catalytic Activities of Rare-Earth Manganites for Cathodic Reduction of Oxygen in Alkaline Solution journal January 1996
Electrode Kinetics of Porous Mixed-Conducting Oxygen Electrodes journal January 1996
Preparation of Air Electrodes and Long Run Tests journal January 1991
The Electrocatalysis of Oxygen Evolution on Perovskites journal January 1984
Lanthanum Nickelate as Electrocatalyst: Oxygen Evolution journal October 1982
Electrocatalytic Measurement Methodology of Oxide Catalysts Using a Thin-Film Rotating Disk Electrode journal January 2010
Durability of Carbon-Supported La-Mn-Based Perovskite-Type Oxides as Oxygen Reduction Catalysts in Strong Alkaline Solution journal January 2011
Electrocatalytic Activities of La0.6Ca0.4CoO3 and La0.6Ca0.4CoO3-Carbon Composites Toward the Oxygen Reduction Reaction in Concentrated Alkaline Electrolytes journal January 2011
High-Performance Oxygen Reduction Catalyst Using Carbon-Supported La-Mn-Based Perovskite-Type Oxide journal January 2011
Electrocatalytic Activity of Non-Stoichiometric Perovskites toward Oxygen Reduction Reaction in Alkaline Electrolytes conference January 2011
On Activity and Stability of Rhombohedral LaNiO3 Catalyst towards ORR and OER in Alkaline Electrolyte journal January 2015
Oxygen Electrocatalysis on Epitaxial La 0.6 Sr 0.4 CoO 3- δ Perovskite Thin Films for Solid Oxide Fuel Cells journal January 2012
A Critical Review of Li∕Air Batteries journal January 2012
Catalytic Properties of Perovskite-Type Mixed Oxides (ABO 3 ) Consisting of Rare Earth and 3d Transition Metals. The Roles of the A- and B-Site Ions journal March 1988
Preparation of Perovskite-type Mixed Oxide (La 1−X Sr X CoO 3 ) Supported on Cordierite. An Efficient Combustion Catalyst journal August 1986
Pronounced Catalytic Activity of La 1−x Sr x CoO 3 Highly Dispersed on ZrO 2 for Complete Oxidation of Propane journal November 1987
Preparation of Perovskite-type Oxides with Large Surface Area by Citrate Process journal April 1987
Preparation of Ordered Macroporous Sr 0.5 Sm 0.5 CoO 3 as Cathode for Solid Oxide Fuel Cells journal October 2001

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Recent Advances in Novel Nanostructuring Methods of Perovskite Electrocatalysts for Energy-Related Applications journal May 2018
La0.1Ca0.9MnO3/Co3O4 for oxygen reduction and evolution reactions (ORER) in alkaline electrolyte journal January 2018
Notable hydrogen production on La x Ca1−xCoO3 perovskites via two-step thermochemical water splitting journal January 2018
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Exceptional electrocatalytic oxygen evolution via tunable charge transfer interactions in La0.5Sr1.5Ni1−xFexO4±δ Ruddlesden-Popper oxides journal August 2018
Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation journal June 2019
Physico-chemical properties and catalytic activity of the sol-gel prepared Ce-ion doped LaMnO3 perovskites journal May 2019
Facile synthesis of three-dimensionally ordered macroporous silicon-doped La 0.8 K 0.2 CoO 3 perovskite catalysts for soot combustion journal January 2016
Recent advances in ordered meso/macroporous metal oxides for heterogeneous catalysis: a review journal January 2017
Supercapacitor performance of perovskite La 1−x Sr x MnO 3 journal January 2017
Synthesis and applications of nanoporous perovskite metal oxides journal January 2018
Acid–base catalysis over perovskites: a review journal January 2018
Ordered meso- and macroporous perovskite oxide catalysts for emerging applications journal January 2018
Hydration and ion association of La 3+ and Eu 3+ salts in aqueous solution journal January 2018
Multifunctional nanostructured electrocatalysts for energy conversion and storage: current status and perspectives journal January 2018
Tuning the structure of bifunctional Pt/SmMn 2 O 5 interfaces for promoted low-temperature CO oxidation activity journal January 2019
Perovskite nanostructures for photovoltaic and energy storage devices journal January 2018
Perovskite La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3−δ sensitized SnO 2 fiber-in-tube scaffold: highly selective and sensitive formaldehyde sensing journal January 2018
Rare-earth-containing perovskite nanomaterials: design, synthesis, properties and applications journal January 2020
Nanostructured manganese oxides: natural/artificial formation and their induced catalysis for wastewater remediation journal January 2020
IrO 2 -incorporated La 0.8 Sr 0.2 MnO 3 as a bifunctional oxygen electrocatalyst with enhanced activities journal January 2019
Polar or not polar? The interplay between reconstruction, Sr enrichment, and reduction at the La 0.75 Sr 0.25 MnO 3 (001) surface journal January 2020
Ultraviolet Detection and Photocatalytic Activity of Nanostructured LaCoO 3 Prepared by Solution-Polymerization journal January 2019
LaCoO 3 Nanostructures Modified Glassy Carbon Electrode for Simultaneous Electrochemical Detection of Dopamine, Ascorbic Acid and Uric Acid journal January 2017
Novel UV Sensing and Photocatalytic Properties of DyCoO 3 journal June 2019
Perovskite nanocrystals for energy conversion and storage journal July 2019
Graphene/Strontium Titanate: Approaching Single Crystal–Like Charge Transport in Polycrystalline Oxide Perovskite Nanocomposites through Grain Boundary Engineering text January 2020
Perovskite Structure Associated with Precious Metals: Influence on Heterogenous Catalytic Process journal August 2019
Perovskite-Type Lanthanum Cobaltite LaCoO3: Aspects of Processing Route toward Practical Applications book December 2019

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