DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Carbon p electron ferromagnetism in silicon carbide

Journal Article · · Scientific Reports
DOI: https://doi.org/10.1038/srep08999 · OSTI ID:1201546
 [1];  [2];  [3];  [4];  [5];  [5];  [4];  [6];  [6];  [6];  [3];  [7];  [1];  [4]
  1. Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany); Technische Univ. Dresden, Dresden (Germany)
  2. Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany); Chinese Academy of Sciences, Beijing (China)
  3. Chinese Academy of Sciences, Beijing (China)
  4. Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany)
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  6. Technische Univ. Chemnitz, Chemnitz (Germany)
  7. Helmholtz-Zentrum Dresden-Rossendorf, Dresden (Germany); Technische Univ. Chemnitz, Chemnitz (Germany)

Ferromagnetism can occur in wide-band gap semiconductors as well as in carbon-based materials when specific defects are introduced. It is thus desirable to establish a direct relation between the defects and the resulting ferromagnetism. Here, we contribute to revealing the origin of defect-induced ferromagnetism using SiC as a prototypical example. We show that the long-range ferromagnetic coupling can be attributed to the p electrons of the nearest-neighbor carbon atoms around the VSiVC divacancies. Thus, the ferromagnetism is traced down to its microscopic electronic origin.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1201546
Journal Information:
Scientific Reports, Journal Name: Scientific Reports Vol. 5; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (36)

The Stopping and Range of Ions in Matter book January 1985
Magnetic order in graphite: Experimental evidence, intrinsic and extrinsic difficulties journal May 2010
Observation of Glassy Ferromagnetism in Al-Doped 4H-SiC journal February 2009
Unexpected magnetism in a dielectric oxide journal August 2004
Ferromagnetism of a graphite nodule from the Canyon Diablo meteorite journal November 2002
Room temperature coherent control of defect spin qubits in silicon carbide journal November 2011
Polytype control of spin qubits in silicon carbide journal May 2013
Dual origin of defect magnetism in graphene and its reversible switching by molecular doping journal June 2013
A silicon carbide room-temperature single-photon source journal November 2013
Room-temperature ferromagnetism in graphite driven by two-dimensional networks of point defects journal October 2009
Spin-half paramagnetism in graphene induced by point defects journal January 2012
Room-temperature quantum microwave emitters based on spin defects in silicon carbide journal December 2013
X-ray absorption near edge spectroscopy with a superconducting detector for nitrogen dopants in SiC journal November 2012
Towards intrinsic magnetism of graphene sheets with irregular zigzag edges journal September 2013
Room temperature ferromagnetism in pristine MgO thin films journal June 2010
Rise and fall of defect induced ferromagnetism in SiC single crystals journal May 2011
Emergence of magnetism in graphene materials and nanostructures journal April 2010
The role of hydrogen in room-temperature ferromagnetism at graphite surfaces journal December 2010
Electronic and magnetic properties of the graphene–ferromagnet interface journal December 2010
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism journal April 1990
Defect-induced magnetism in graphene journal March 2007
Disorder beneath epitaxial graphene on SiC(0001): An x-ray absorption study journal November 2008
Ubiquity of ferromagnetic signals in common diamagnetic oxide crystals journal June 2010
Disentangling defect-induced ferromagnetism in SiC journal January 2014
Magnetism in Disordered Graphene and Irradiated Graphite journal July 2008
Defect-Enhanced Charge Transfer by Ion-Solid Interactions in SiC using Large-Scale Ab Initio Molecular Dynamics Simulations journal July 2009
Missing Atom as a Source of Carbon Magnetism journal March 2010
Ferromagnetism in Dilute Magnetic Semiconductors through Defect Engineering: Li-Doped ZnO journal March 2010
Defect-Induced Magnetism in Neutron Irradiated 6 H -SiC Single Crystals journal February 2011
Absorption of circularly polarized x rays in iron journal February 1987
Generalized Gradient Approximation Made Simple journal October 1996
Induced Magnetic Ordering by Proton Irradiation in Graphite journal November 2003
Magnetism without Magnetic Ions: Percolation, Exchange, and Formation Energies of Magnetism-Promoting Intrinsic Defects in CaO journal March 2006
π -Electron Ferromagnetism in Metal-Free Carbon Probed by Soft X-Ray Dichroism journal May 2007
Principles of X-Ray Magnetic Dichroism Spectromicroscopy journal December 1998
First principles methods using CASTEP journal January 2005

Cited By (1)

Defect-induced magnetism in SiC journal July 2019

Similar Records

Stability and molecular pathways to the formation of spin defects in silicon carbide
Journal Article · Wed Nov 03 04:00:00 UTC 2021 · Nature Communications · OSTI ID:1829138

Angular correlation of annihilation radiation associated with vacancy defects in electron-irradiated 6H-SiC
Journal Article · Sun May 15 04:00:00 UTC 2005 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:20719011

First-Principles Investigation of Near-Surface Divacancies in Silicon Carbide
Journal Article · Tue Dec 05 04:00:00 UTC 2023 · Nano Letters · OSTI ID:2478067