Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy
Abstract
The field of supercapacitors (electrochemical capacitors) is constantly evolving. The global motivation is to create devices that possess a significant energy density without compromising the power density. To achieve this goal, new materials must be discovered and complex electrode architectures developed.
- Authors:
- Drexel Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering and A.J. Drexel Nanomaterials Inst.
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1188237
- Report Number(s):
- BNL-108018-2015-JA
Journal ID: ISSN 1614-6832; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 5; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; capacitance; two-dimensional; carbide; MXene; XAS; pseudocapacitance
Citation Formats
Lukatskaya, Maria R., Bak, Seong -Min, Yu, Xiqian, Yang, Xiao -Qing, Barsoum, Michel W., and Gogotsi, Yury. Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy. United States: N. p., 2015.
Web. doi:10.1002/aenm.201500589.
Lukatskaya, Maria R., Bak, Seong -Min, Yu, Xiqian, Yang, Xiao -Qing, Barsoum, Michel W., & Gogotsi, Yury. Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy. United States. doi:10.1002/aenm.201500589.
Lukatskaya, Maria R., Bak, Seong -Min, Yu, Xiqian, Yang, Xiao -Qing, Barsoum, Michel W., and Gogotsi, Yury. Thu .
"Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy". United States. doi:10.1002/aenm.201500589. https://www.osti.gov/servlets/purl/1188237.
@article{osti_1188237,
title = {Probing the mechanism of high capacitance in two-dimensional titanium carbide using in-situ X-Ray absorption spectroscopy},
author = {Lukatskaya, Maria R. and Bak, Seong -Min and Yu, Xiqian and Yang, Xiao -Qing and Barsoum, Michel W. and Gogotsi, Yury},
abstractNote = {The field of supercapacitors (electrochemical capacitors) is constantly evolving. The global motivation is to create devices that possess a significant energy density without compromising the power density. To achieve this goal, new materials must be discovered and complex electrode architectures developed.},
doi = {10.1002/aenm.201500589},
journal = {Advanced Energy Materials},
number = 5,
volume = 10,
place = {United States},
year = {2015},
month = {5}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 53 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Materials for electrochemical capacitors
journal, November 2008
- Simon, Patrice; Gogotsi, Yury
- Nature Materials, Vol. 7, Issue 11
A Sandwich-Like Hierarchically Porous Carbon/Graphene Composite as a High-Performance Anode Material for Sodium-Ion Batteries
journal, January 2014
- Yan, Yang; Yin, Ya-Xia; Guo, Yu-Guo
- Advanced Energy Materials, Vol. 4, Issue 8
Reversibility and Growth Behavior of Surface Oxide Films at Ruthenium Electrodes
journal, January 1978
- Hadz̄i-Jordanov, S.
- Journal of The Electrochemical Society, Vol. 125, Issue 9
Hydrous Ruthenium Oxide as an Electrode Material for Electrochemical Capacitors
journal, January 1995
- Zheng, J. P.
- Journal of The Electrochemical Society, Vol. 142, Issue 8
Direct synthesis of electroactive mesoporous hydrous crystalline RuO2 templated by a cationic surfactant
journal, January 2010
- Oh, Si Hyoung; Nazar, Linda F.
- Journal of Materials Chemistry, Vol. 20, Issue 19
Block‐Copolymer‐Templated Synthesis of Electroactive RuO 2 ‐Based Mesoporous Thin Films
journal, June 2009
- Sassoye, Capucine; Laberty, Christel; Le Khanh, Hung
- Advanced Functional Materials, Vol. 19, Issue 12
Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide
journal, September 2013
- Lukatskaya, M. R.; Mashtalir, O.; Ren, C. E.
- Science, Vol. 341, Issue 6153
Two-Dimensional Materials: 25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials (Adv. Mater. 7/2014)
journal, February 2014
- Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W.
- Advanced Materials, Vol. 26, Issue 7
The New Skinny in Two-Dimensional Nanomaterials
journal, May 2013
- Koski, Kristie J.; Cui, Yi
- ACS Nano, Vol. 7, Issue 5
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011
- Naguib, Michael; Kurtoglu, Murat; Presser, Volker
- Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films
journal, March 2014
- Halim, Joseph; Lukatskaya, Maria R.; Cook, Kevin M.
- Chemistry of Materials, Vol. 26, Issue 7
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
journal, November 2014
- Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang
- Nature, Vol. 516, Issue 7529
MXene: a promising transition metal carbide anode for lithium-ion batteries
journal, March 2012
- Naguib, Michael; Come, Jérémy; Dyatkin, Boris
- Electrochemistry Communications, Vol. 16, Issue 1, p. 61-64
New Two-Dimensional Niobium and Vanadium Carbides as Promising Materials for Li-Ion Batteries
journal, October 2013
- Naguib, Michael; Halim, Joseph; Lu, Jun
- Journal of the American Chemical Society, Vol. 135, Issue 43
Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries
journal, February 2015
- Liang, Xiao; Garsuch, Arnd; Nazar, Linda F.
- Angewandte Chemie International Edition, Vol. 54, Issue 13
High capacitance of surface-modified 2D titanium carbide in acidic electrolyte
journal, November 2014
- Dall'Agnese, Yohan; Lukatskaya, Maria R.; Cook, Kevin M.
- Electrochemistry Communications, Vol. 48
Solving the Capacitive Paradox of 2D MXene using Electrochemical Quartz-Crystal Admittance and In Situ Electronic Conductance Measurements
journal, August 2014
- Levi, Mikhael D.; Lukatskaya, Maria R.; Sigalov, Sergey
- Advanced Energy Materials, Vol. 5, Issue 1
Towards the mechanism of electrochemical hydrogen storage in nanostructured carbon materials
journal, April 2004
- Jurewicz, K.; Frackowiak, E.; Béguin, F.
- Applied Physics A, Vol. 78, Issue 7
In situ Mn K-edge X-ray absorption spectroscopic studies of anodically deposited manganese oxide with relevance to supercapacitor applications
journal, April 2007
- Chang, Jeng-Kuei; Lee, Ming-Tsung; Tsai, Wen-Ta
- Journal of Power Sources, Vol. 166, Issue 2
In Situ Mn K-edge X-ray Absorption Spectroscopy Studies of Electrodeposited Manganese Oxide Films for Electrochemical Capacitors
journal, January 2007
- Nam, Kyung-Wan; Kim, Min Gyu; Kim, Kwang-Bum
- The Journal of Physical Chemistry C, Vol. 111, Issue 2
In Situ Ru K-Edge X-Ray Absorption Fine Structure Studies of Electroprecipitated Ruthenium Dioxide Films with Relevance to Supercapacitor Applications
journal, October 2000
- Mo, Yibo; Antonio, Mark R.; Scherson, Daniel A.
- The Journal of Physical Chemistry B, Vol. 104, Issue 42
NEXAFS investigations of transition metal oxides, nitrides, carbides, sulfides and other interstitial compounds
journal, January 1997
- Chen, J. G.
- Surface Science Reports, Vol. 30, Issue 1-3
Role of Surface Structure on Li-Ion Energy Storage Capacity of Two-Dimensional Transition-Metal Carbides
journal, April 2014
- Xie, Yu; Naguib, Michael; Mochalin, Vadym N.
- Journal of the American Chemical Society, Vol. 136, Issue 17
Lithium Storage in Amorphous TiO[sub 2] Nanoparticles
journal, January 2010
- Borghols, Wouter J. H.; Lützenkirchen-Hecht, Dirk; Haake, Ullrich
- Journal of The Electrochemical Society, Vol. 157, Issue 5
The electronic structure and ionic diffusion of nanoscale LiTiO2 anatase
journal, January 2009
- Borghols, W. J. H.; Lützenkirchen-Hecht, D.; Haake, U.
- Physical Chemistry Chemical Physics, Vol. 11, Issue 27
Works referencing / citing this record:
Scalable nanomanufacturing of inkjet-printed wearable energy storage devices
journal, January 2019
- Huang, Tao-Tse; Wu, Wenzhuo
- Journal of Materials Chemistry A, Vol. 7, Issue 41