A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

Wan, Shun; Jiang, Xueguang; Guo, Bingkun; Dai, Sheng; Goodenough, John B.; Sun, Xiao-Guang

doi:10.1039/C5CC01428J

Title: A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application

Journal Article · Mon Apr 27 04:00:00 UTC 2015 · ChemComm

DOI: https://doi.org/10.1039/C5CC01428J · OSTI ID:1185994

Wan, Shun ^[1]; Jiang, Xueguang ^[2]; Guo, Bingkun ^[3]; Dai, Sheng ^[4]; Goodenough, John B. ^[3]; Sun, Xiao-Guang ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Texas, Austin, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. A 0.8 M LiBMFMB solution is obtained in a mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.). The new LiBMFMB based electrolyte exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1185994

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 48 Vol. 51; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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A Novel Electrolyte Salt Additive for Lithium-Ion Batteries with Voltages Greater than 4.7 V Li, Yunchao; Wan, Shun; Veith, Gabriel M. Advanced Energy Materials, Vol. 7, Issue 4 https://doi.org/10.1002/aenm.201601397	journal	November 2016
Designing Low Impedance Interface Films Simultaneously on Anode and Cathode for High Energy Batteries Liao, Bo; Li, Hongying; Xu, Mengqing Advanced Energy Materials, Vol. 8, Issue 22 https://doi.org/10.1002/aenm.201800802	journal	May 2018
Fluor und Lithium: Ideale Partner für Elektrolyte in wiederaufladbaren Hochleistungsbatterien Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie, Vol. 131, Issue 45 https://doi.org/10.1002/ange.201901381	journal	July 2019
Fluorine and Lithium: Ideal Partners for High‐Performance Rechargeable Battery Electrolytes Aspern, N.; Röschenthaler, G. ‐V.; Winter, M. Angewandte Chemie International Edition, Vol. 58, Issue 45 https://doi.org/10.1002/anie.201901381	journal	November 2019
Unsymmetrical fluorinated malonatoborate as an amphoteric additive for high-energy-density lithium-ion batteries Han, Jung-Gu; Lee, Jae Bin; Cha, Aming Energy & Environmental Science, Vol. 11, Issue 6 https://doi.org/10.1039/c8ee00372f	journal	January 2018
X-ray Raman spectroscopy of lithium-ion battery electrolyte solutions in a flow cell Ketenoglu, Didem; Spiekermann, Georg; Harder, Manuel Journal of Synchrotron Radiation, Vol. 25, Issue 2 https://doi.org/10.1107/s1600577518001662	journal	February 2018

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