Hypercrosslinked phenolic polymers with well developed mesoporous frameworks

Zhang, Jinshui; Qiao, Zhenan -An; Mahurin, Shannon Mark; Jiang, Xueguang; Chai, Song -Hai; Lu, Hanfeng; Nelson, Kimberly M.; Dai, Sheng

doi:10.1002/anie.201500305

Title: Hypercrosslinked phenolic polymers with well developed mesoporous frameworks

Journal Article · Wed Feb 11 23:00:00 EST 2015 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201500305 · OSTI ID:1185912

Zhang, Jinshui ^[1]; Qiao, Zhenan -An ^[1]; Mahurin, Shannon Mark ^[1]; Jiang, Xueguang ^[2]; Chai, Song -Hai ^[1]; Lu, Hanfeng ^[1]; Nelson, Kimberly M. ^[1]; Dai, Sheng ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

A soft chemistry synthetic strategy based on a Friedel Crafts alkylation reaction is developed for the textural engineering of phenolic resin (PR) with a robust mesoporous framework to avoid serious framework shrinkage and maximize retention of organic functional moieties. By taking advantage of the structural benefits of molecular bridges, the resultant sample maintains a bimodal micro-mesoporous architecture with well-preserved organic functional groups, which is effective for carbon capture. Furthermore, this soft chemistry synthetic protocol can be further extended to nanotexture other aromatic-based polymers with robust frameworks.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1185912

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 15 Vol. 54; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2 capture
Friedel-Crafts alkylation reaction
hypercross-linking
mesoporous frameworks
phenolic polymer

Title: Hypercrosslinked phenolic polymers with well developed mesoporous frameworks

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