Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons

Li, Xufan; Budai, John D.; Liu, Feng; Chen, Yu-Sheng; Howe, Jane Y.; Sun, Chengjun; Tischler, Jonathan Zachary; Meltzer, Richard; Pan, Zhengwei

doi:10.1039/C4TC02002B

Title: Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons

Abstract

We report the synthesis and characterization of three series of new quaternary strontium europium aluminate (Sr-Eu-Al-O; SEAO) luminescent nanoribbons that show blue, green, and yellow luminescence from localized Eu2+ luminescent centers. These three series of SEAO nanoribbons are: blue luminescent, tetragonal Sr1-xEuxAl6O10 (0 < x < 1) (b-SEAO), green luminescent, monoclinic Sr1-xEuxAl2O4 (0 < x < 1) (g-SEAO), and yellow luminescent, hexagonal Sr1-xEuxAl2O4 (0 < x < 1) (y-SEAO). Among these three series of SEAO nanoribbons, the b-SEAOs and y-SEAOs are new compounds that have not been reported before. The crystal structures of the SEAO nanoribbons were comprehensively studied using various synchrotron X-ray diffraction techniques and the effects of crystal structures on materials' luminescence properties were investigated. These one-dimensional SEAO luminescent nanoribbons can function as both light generators and waveguides, and thus have promising potential as the building blocks in miniaturized photonic circuitry.

Authors:

Li, Xufan ^[1]; Budai, John D. ^[2]; Liu, Feng ^[1]; Chen, Yu-Sheng ^[3]; Howe, Jane Y. ^[2]; Sun, Chengjun ^[3]; Tischler, Jonathan Zachary ^[2]; Meltzer, Richard ^[1]; Pan, Zhengwei ^[1]

Univ. of Georgia, Athens, GA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Wed Nov 12 00:00:00 EST 2014

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1185341

Alternate Identifier(s):: OSTI ID: 1352747

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. C

Additional Journal Information:: Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2050-7526

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Li, Xufan, Budai, John D., Liu, Feng, Chen, Yu-Sheng, Howe, Jane Y., Sun, Chengjun, Tischler, Jonathan Zachary, Meltzer, Richard, and Pan, Zhengwei. Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons.  United States: N. p., 2014. 
Web.  doi:10.1039/C4TC02002B.

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                    Li, Xufan, Budai, John D., Liu, Feng, Chen, Yu-Sheng, Howe, Jane Y., Sun, Chengjun, Tischler, Jonathan Zachary, Meltzer, Richard, & Pan, Zhengwei. Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons.  United States.  https://doi.org/10.1039/C4TC02002B

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                    Li, Xufan, Budai, John D., Liu, Feng, Chen, Yu-Sheng, Howe, Jane Y., Sun, Chengjun, Tischler, Jonathan Zachary, Meltzer, Richard, and Pan, Zhengwei. Wed .  
"Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons".  United States.  https://doi.org/10.1039/C4TC02002B.  https://www.osti.gov/servlets/purl/1185341.

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@article{osti_1185341,

  title        = {Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons},

  author       = {Li, Xufan and Budai, John D. and Liu, Feng and Chen, Yu-Sheng and Howe, Jane Y. and Sun, Chengjun and Tischler, Jonathan Zachary and Meltzer, Richard and Pan, Zhengwei},

  abstractNote = {We report the synthesis and characterization of three series of new quaternary strontium europium aluminate (Sr-Eu-Al-O; SEAO) luminescent nanoribbons that show blue, green, and yellow luminescence from localized Eu2+ luminescent centers. These three series of SEAO nanoribbons are: blue luminescent, tetragonal Sr1-xEuxAl6O10 (0 < x < 1) (b-SEAO), green luminescent, monoclinic Sr1-xEuxAl2O4 (0 < x < 1) (g-SEAO), and yellow luminescent, hexagonal Sr1-xEuxAl2O4 (0 < x < 1) (y-SEAO). Among these three series of SEAO nanoribbons, the b-SEAOs and y-SEAOs are new compounds that have not been reported before. The crystal structures of the SEAO nanoribbons were comprehensively studied using various synchrotron X-ray diffraction techniques and the effects of crystal structures on materials' luminescence properties were investigated. These one-dimensional SEAO luminescent nanoribbons can function as both light generators and waveguides, and thus have promising potential as the building blocks in miniaturized photonic circuitry.},

  doi          = {10.1039/C4TC02002B},

  journal      = {Journal of Materials Chemistry. C},

  number       = 4,

  volume       = 3,

  place        = {United States},

  year         = {Wed Nov 12 00:00:00 EST 2014},

  month        = {Wed Nov 12 00:00:00 EST 2014}

}

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Title: Crystal structures and optical properties of new quaternary strontium europium aluminate luminescent nanoribbons

Abstract

Citation Formats

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Gallium Nitride-Based Nanowire Radial Heterostructures for Nanophotonics journal, October 2004

Color Point Tuning for (Sr,Ca,Ba)Si2O2N2:Eu2+ for White Light LEDs journal, December 2008

Luminescence Decay by Energy Migration and Transfer: Observation of Diffusion-Limited Relaxation journal, November 1971

Single-nanowire electrically driven lasers journal, January 2003

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Large-Scale, Solution-Phase Growth of Single-Crystalline SnO 2 Nanorods journal, May 2004

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Applications of inductively coupled plasma mass spectrometry and laser ablation inductively coupled plasma mass spectrometry in materials science journal, December 2002

Three-dimensional X-ray structural microscopy with submicrometre resolution journal, February 2002

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