The radiation chemistry of ionic liquids: A review

Mincher, Bruce J.; Wishart, James F.

doi:10.1080/07366299.2014.925687

Title: The radiation chemistry of ionic liquids: A review

Journal Article · Thu Jul 03 00:00:00 EDT 2014 · Solvent Extraction and Ion Exchange

DOI: https://doi.org/10.1080/07366299.2014.925687 · OSTI ID:1173109

Mincher, Bruce J. ^[1]; Wishart, James F. ^[2]

Idaho National Lab. (INL), Idaho Falls, ID (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Ionic liquids have received increasing attention as media for radiochemical separations. Recent literature includes examinations of the efficiencies and mechanisms of the solvent extraction of lanthanides, actinides and fission products into ionic liquid solutions. For radiochemical applications, including as replacement solvents for nuclear fuel reprocessing, a thorough understanding of the radiation chemistry of ionic liquids will be required. Such an understanding can be achieved based on a combination of steady-state radiolysis experiments coupled with post-irradiation product identification and pulse-radiolysis experiments to acquire kinetic information. These techniques allow for the elucidation of radiolytic mechanisms. This contribution reviews the current ionic liquid radiation chemistry literature as it affects separations, with these considerations in mind.

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Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC07-05ID14517

OSTI ID:: 1173109

Report Number(s):: INL/JOU--13-30554

Journal Information:: Solvent Extraction and Ion Exchange, Journal Name: Solvent Extraction and Ion Exchange Journal Issue: 6 Vol. 32; ISSN 0736-6299

Publisher:: Taylor and FrancisCopyright Statement

Country of Publication:: United States

Language:: English

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An overview of eight- and nine-coordinate N-donor solvated lanthanoid(III) and actinoid(III) ions Lundberg, Daniel Journal of Radioanalytical and Nuclear Chemistry, Vol. 316, Issue 2 https://doi.org/10.1007/s10967-018-5757-9	journal	February 2018
Role of anions in radiation-induced transformations of 18-crown-6 complexes with barium salts: simulating the effects of extraction mechanism on radiation stability of macrocyclic extractants Nesterov, Sergey V.; Zakurdaeva, Olga A.; Kurkin, Tikhon S. Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 3 https://doi.org/10.1007/s10967-018-6093-9	journal	August 2018
Actinide ion extraction using room temperature ionic liquids: opportunities and challenges for nuclear fuel cycle applications Mohapatra, Prasanta Kumar Dalton Transactions, Vol. 46, Issue 6 https://doi.org/10.1039/c6dt04898f	journal	January 2017
Ligands for f-element extraction used in the nuclear fuel cycle Leoncini, Andrea; Huskens, Jurriaan; Verboom, Willem Chemical Society Reviews, Vol. 46, Issue 23 https://doi.org/10.1039/c7cs00574a	journal	January 2017
Dynamics of an excess hole in the 1-methyl-1-butyl-pyrrolidinium dicyanamide ionic-liquid Wu, Fei; Xu, Changhui; Margulis, Claudio J. The Journal of Chemical Physics, Vol. 148, Issue 19 https://doi.org/10.1063/1.5009940	journal	May 2018
Gamma Radiolysis of TODGA and CyMe ₄ BTPhen in the Ionic Liquid Tri- n -Octylmethylammonium Nitrate Zsabka, Peter; Van Hecke, Karen; Wilden, Andreas Solvent Extraction and Ion Exchange, Vol. 38, Issue 2 https://doi.org/10.1080/07366299.2019.1710918	journal	January 2020

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