Photo-induced Low Temperature Structural Transition in the "114" YbaFe4O7 oxide

Duffort, V.; Caignaert, Vincent; Pralong, V.; Raveau, B.; Suchomel, M. R.; Mitchell, J. F.

doi:10.1016/j.ssc.2013.11.006

Title: Photo-induced Low Temperature Structural Transition in the "114" YbaFe₄O₇ oxide

Abstract

Synchrotron irradiation of the oxide YBaFe₄O_7.0 below 190 K converts the low temperature monoclinic structure to a higher symmetry tetragonal form analogous to the room temperature structure. This photo-induced metastable tetragonal form is stable even in the absence of irradiation over the range 4-60 K, however, above 60 K the photo-transition is reversible. These structural phenomena are correlated to the magnetic behaviour of this system, suggesting possible spin-lattice coupling. Lastly, a scenario explaining the low temperature photo-induced transition is proposed, based on the different distributions of the valence electrons in the iron sub-lattice of the monoclinic and tetragonal phases.

Authors:

Duffort, V. ^[1]; Caignaert, Vincent ^[1]; Pralong, V. ^[1]; Raveau, B. ^[1]; Suchomel, M. R. ^[2]; Mitchell, J. F. ^[3]

Laboratoire de cristallographie et sciences des materiaux (CRISMAT), Caen (France)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division

Publication Date:: Mon Nov 11 00:00:00 EST 2013

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1114911

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Solid State Communications

Additional Journal Information:: Journal Volume: 182; Journal Issue: 2014; Journal ID: ISSN 0038-1098

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; photo-induced transition; iron oxide; powder diffraction; 114 structure

Citation Formats


                    Duffort, V., Caignaert, Vincent, Pralong, V., Raveau, B., Suchomel, M. R., and Mitchell, J. F. Photo-induced Low Temperature Structural Transition in the "114" YbaFe4O7 oxide.  United States: N. p., 2013. 
Web.  doi:10.1016/j.ssc.2013.11.006.

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                    Duffort, V., Caignaert, Vincent, Pralong, V., Raveau, B., Suchomel, M. R., & Mitchell, J. F. Photo-induced Low Temperature Structural Transition in the "114" YbaFe4O7 oxide.  United States.  https://doi.org/10.1016/j.ssc.2013.11.006

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                    Duffort, V., Caignaert, Vincent, Pralong, V., Raveau, B., Suchomel, M. R., and Mitchell, J. F. Mon .  
"Photo-induced Low Temperature Structural Transition in the "114" YbaFe4O7 oxide".  United States.  https://doi.org/10.1016/j.ssc.2013.11.006.  https://www.osti.gov/servlets/purl/1114911.

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@article{osti_1114911,

  title        = {Photo-induced Low Temperature Structural Transition in the "114" YbaFe4O7 oxide},

  author       = {Duffort, V. and Caignaert, Vincent and Pralong, V. and Raveau, B. and Suchomel, M. R. and Mitchell, J. F.},

  abstractNote = {Synchrotron irradiation of the oxide YBaFe4O7.0 below 190 K converts the low temperature monoclinic structure to a higher symmetry tetragonal form analogous to the room temperature structure. This photo-induced metastable tetragonal form is stable even in the absence of irradiation over the range 4-60 K, however, above 60 K the photo-transition is reversible. These structural phenomena are correlated to the magnetic behaviour of this system, suggesting possible spin-lattice coupling. Lastly, a scenario explaining the low temperature photo-induced transition is proposed, based on the different distributions of the valence electrons in the iron sub-lattice of the monoclinic and tetragonal phases.},

  doi          = {10.1016/j.ssc.2013.11.006},

  journal      = {Solid State Communications},

  number       = 2014,

  volume       = 182,

  place        = {United States},

  year         = {Mon Nov 11 00:00:00 EST 2013},

  month        = {Mon Nov 11 00:00:00 EST 2013}

}

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Title: Photo-induced Low Temperature Structural Transition in the "114" YbaFe4O7 oxide

Abstract

Citation Formats

The structure of the new compound YBaCo4O7 with a magnetic feature journal, June 2002

Competing magnetic interactions in the extended Kagomé system Y Ba Co 4 O 7 journal, November 2006

Structural and magnetic properties of the Kagomé antiferromagnet YbBaCo4O7 journal, April 2006

Condensation of a tetrahedra rigid-body libration mode in HoBaCo 4 O 7 : the origin of phase transition at 355 K journal, April 2010

Single-crystal structure of HoBaCo 4 O 7 at ambient conditions, at low temperature, and at high pressure journal, February 2009

Magnetic measurements and neutron studies on and journal, March 2007

Syntheses and structures of compounds with YBaCo4O7-type structure journal, March 2004

Structural and magnetic phase transitions of kagome-like compounds REBaCo4O7 (RE=Dy, Ho, Er, Tm, Yb, Lu) journal, May 2010

Orthorhombic kagome cobaltite CaBaCo4O7: A new ferrimagnet with a of 70 K journal, March 2009

Magnetic structure of CaBaCo 4 O 7 : Lifting of geometrical frustration towards ferrimagnetism journal, March 2010

Magnetic Correlations in the Extended Kagome YBaCo 4 O 7 Probed by Single-Crystal Neutron Scattering journal, July 2009

Kinetic control of structural and magnetic states in LuBaCo 4 O 7 journal, March 2012

Structure and magnetic properties of LnBaFe4O7 oxides: Ln size effect journal, January 2009

A Series of Novel Mixed Valent Ferrimagnetic Oxides with a T C up to 270 K: Ca 1− x Y x BaFe 4 O 7 journal, September 2008

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Frustrated rare earth magnetism: Spin glasses, spin liquids and spin ices in pyrochlore oxides journal, February 2006

Tetragonal YBaFe4O7.0: A stoichiometric polymorph of the “114” ferrite family journal, July 2012

Lifting the geometric frustration through a monoclinic distortion in “114” YBaFe4O7.0: Magnetism and transport journal, September 2013

Structural changes, clustering, and photoinduced phase segregation in Pr 0.7 Ca 0.3 MnO 3 journal, February 1998

An X-ray-induced insulator–metal transition in a magnetoresistive manganite journal, April 1997

X-ray-induced structural transition in La 0.875 Sr 0.125 MnO 3 journal, March 1999

X-ray-induced disordering of the dimerization pattern and apparent low-temperature enhancement of lattice symmetry in spinel CuIr 2 S 4 journal, October 2002

Rich Crystal Chemistry and Magnetism of “114” Stoichiometric LnBaFe 4 O 7.0 Ferrites journal, August 2013

Title: Photo-induced Low Temperature Structural Transition in the "114" YbaFe₄O₇ oxide

The structure of the new compound YBaCo4O7 with a magnetic feature
journal, June 2002

Competing magnetic interactions in the extended Kagomé system $Y Ba {Co}_{4} O_{7}$
journal, November 2006

Structural and magnetic properties of the Kagomé antiferromagnet YbBaCo4O7
journal, April 2006

Condensation of a tetrahedra rigid-body libration mode in HoBaCo ₄ O ₇ : the origin of phase transition at 355 K
journal, April 2010

Single-crystal structure of ${HoBaCo}_{4} O_{7}$ at ambient conditions, at low temperature, and at high pressure
journal, February 2009

Magnetic measurements and neutron studies on and
journal, March 2007

Syntheses and structures of compounds with YBaCo4O7-type structure
journal, March 2004

Structural and magnetic phase transitions of kagome-like compounds REBaCo4O7 (RE=Dy, Ho, Er, Tm, Yb, Lu)
journal, May 2010

Orthorhombic kagome cobaltite CaBaCo4O7: A new ferrimagnet with a of 70 K
journal, March 2009

Magnetic structure of ${CaBaCo}_{4} O_{7}$ : Lifting of geometrical frustration towards ferrimagnetism
journal, March 2010

Magnetic Correlations in the Extended Kagome ${YBaCo}_{4} O_{7}$ Probed by Single-Crystal Neutron Scattering
journal, July 2009

Kinetic control of structural and magnetic states in LuBaCo $_{4}$ O $_{7}$
journal, March 2012

Structure and magnetic properties of LnBaFe4O7 oxides: Ln size effect
journal, January 2009

A Series of Novel Mixed Valent Ferrimagnetic Oxides with a T _C up to 270 K: Ca _{1− x} Y _x BaFe ₄ O ₇
journal, September 2008

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journal, April 1997

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