Manipulation of two-photon-induced fluorescence spectra of chromophore aggregates with entangled photons: A simulation study

Schlawin, Frank; Dorfman, Konstantin E.; Fingerhut, Benjamin P.; Mukamel, Shaul

doi:10.1103/PhysRevA.86.023851

Title: Manipulation of two-photon-induced fluorescence spectra of chromophore aggregates with entangled photons: A simulation study

Full Record
Other Related Research

Authors:: Schlawin, Frank; Dorfman, Konstantin E.; Fingerhut, Benjamin P.; Mukamel, Shaul

Publication Date:: Wed Aug 29 00:00:00 EDT 2012

Sponsoring Org.:: USDOE

OSTI Identifier:: 1103208

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review A

Additional Journal Information:: Journal Volume: 86; Journal Issue: 2; Journal ID: ISSN 1050-2947

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Schlawin, Frank, Dorfman, Konstantin E., Fingerhut, Benjamin P., and Mukamel, Shaul. Manipulation of two-photon-induced fluorescence spectra of chromophore aggregates with entangled photons: A simulation study.  United States: N. p., 2012. 
Web.  doi:10.1103/PhysRevA.86.023851.

Copy to clipboard


                    Schlawin, Frank, Dorfman, Konstantin E., Fingerhut, Benjamin P., & Mukamel, Shaul. Manipulation of two-photon-induced fluorescence spectra of chromophore aggregates with entangled photons: A simulation study.  United States.  https://doi.org/10.1103/PhysRevA.86.023851

Copy to clipboard


                    Schlawin, Frank, Dorfman, Konstantin E., Fingerhut, Benjamin P., and Mukamel, Shaul. Wed .  
"Manipulation of two-photon-induced fluorescence spectra of chromophore aggregates with entangled photons: A simulation study".  United States.  https://doi.org/10.1103/PhysRevA.86.023851.

Copy to clipboard


                    
@article{osti_1103208,

  title        = {Manipulation of two-photon-induced fluorescence spectra of chromophore aggregates with entangled photons: A simulation study},

  author       = {Schlawin, Frank and Dorfman, Konstantin E. and Fingerhut, Benjamin P. and Mukamel, Shaul},

  abstractNote = {},

  doi          = {10.1103/PhysRevA.86.023851},

  journal      = {Physical Review A},

  number       = 2,

  volume       = 86,

  place        = {United States},

  year         = {Wed Aug 29 00:00:00 EDT 2012},

  month        = {Wed Aug 29 00:00:00 EDT 2012}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1103/PhysRevA.86.023851

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 27 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Investigating Fluorescent Amino Acids with Entangled Two-Photon Excited Fluorescence

Conference Eshun, A ; Wilson, A ; Shelby, M ; ...
Full Text Available
Photoisomerization transition state manipulation by entangled two-photon absorption

Journal Article Gu, Bing ; Keefer, Daniel ; Aleotti, Flavia ; ... - Proceedings of the National Academy of Sciences of the United States of America

We demonstrate how two-photon excitation with quantum light can influence elementary photochemical events. The azobenzene trans → cis isomerization following entangled two-photon excitation is simulated using quantum nuclear wave packet dynamics. Photon entanglement modulates the nuclear wave packets by coherently controlling the transition pathways. The photochemical transition state during passage of the reactive conical intersection in azobenzene photoisomerization is strongly affected with a noticeable alteration of the product yield. Quantum entanglement thus provides a novel control knob for photochemical reactions. The distribution of the vibronic coherences during the conical intersection passage strongly depends on the shape of the initial wavemore »« less
https://doi.org/10.1073/pnas.2116868118
Single-photon two-qubit SWAP gate for entanglement manipulation

Journal Article Fiorentino, Marco ; Kim, Taehyun ; Wong, Franco N.C. - Physical Review. A

A SWAP operation between different types of qubits of single photons is essential for manipulating hyperentangled photons for a variety of applications. We have implemented an efficient SWAP gate for the momentum and polarization degrees of freedom of a single photon. The SWAP gate was utilized in a single-photon two-qubit quantum logic circuit to deterministically transfer momentum entanglement between a pair of down-converted photons to polarization entanglement. The polarization entanglement thus obtained violates Bell's inequality by more than 150 standard deviations.
https://doi.org/10.1103/PhysRevA.72.012318
Manipulating Two-Photon Absorption of Molecules through Efficient Optimization of Entangled Light

Journal Article Giri, Sajal Kumar ; Schatz, George C. - Journal of Physical Chemistry Letters

We report how the unique temporal and spectral features of pulsed entangled photons from a parametric downconversion source can be utilized for manipulating electronic excitations through the optimization of their spectral phase. A new comprehensive optimization protocol based on Bayesian optimization has been developed in this work to selectively excite electronic states accessible by two-photon absorption. Using our optimization method, the entangled two-photon absorption probability for a thiophene dendrimer can be enhanced by up to a factor of 20, while classical light turns out to be nonoptimizable. Moreover, the optimization involving photon entanglement enables selective excitation that would not bemore »« less
https://doi.org/10.1021/acs.jpclett.2c02842

Full Text Available
Excited-state characterization and effective three-photon absorption model of two-photon-induced excited-state absorption in organic push-pull charge-transfer chromophores

Journal Article Sutherland, Richard L ; Brant, Mark C ; Heinrichs, Jim ; ... - Journal of the Optical Society of America. Part B, Optical Physics

We report experimental investigations of two-photon and excited-state absorption in D-{pi}-A chromophores and propose a model to explain nonlinear absorption in the nanosecond regime. The key parameter is an effective three-photon absorption coefficient that depends on the two-photon absorption cross section and excited-state photophysical properties. We obtain all these parameters from independent measurements and then compare the model with nanosecond nonlinear transmission measurements. We find good agreement with the data, using no free parameters, for specific values of some published two-photon absorption cross sections. We conclude that excited singlet-singlet and triplet-triplet absorption are the dominant sources of nonlinear transmittance lossmore »« less
https://doi.org/10.1364/JOSAB.22.001939

Similar Records