Pressure-induced symmetry breaking in tetragonal CsAuI3

Wang, Shibing; Hirai, Shigeto; Shapiro, Max C.; Riggs, Scott C.; Geballe, Ted H.; Mao, Wendy L.; Fisher, Ian R.

doi:10.1103/PhysRevB.87.054104

Title: Pressure-induced symmetry breaking in tetragonal CsAuI₃

Authors:: Wang, Shibing; Hirai, Shigeto; Shapiro, Max C.; Riggs, Scott C.; Geballe, Ted H.; Mao, Wendy L.; Fisher, Ian R.

Publication Date:: Wed Feb 06 00:00:00 EST 2013

Sponsoring Org.:: USDOE

OSTI Identifier:: 1102027

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Review. B, Condensed Matter and Materials Physics

Additional Journal Information:: Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Volume: 87 Journal Issue: 5; Journal ID: ISSN 1098-0121

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Citation Formats


                    Wang, Shibing, Hirai, Shigeto, Shapiro, Max C., Riggs, Scott C., Geballe, Ted H., Mao, Wendy L., and Fisher, Ian R. Pressure-induced symmetry breaking in tetragonal CsAuI3.  United States: N. p., 2013. 
Web.  doi:10.1103/PhysRevB.87.054104.

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                    Wang, Shibing, Hirai, Shigeto, Shapiro, Max C., Riggs, Scott C., Geballe, Ted H., Mao, Wendy L., & Fisher, Ian R. Pressure-induced symmetry breaking in tetragonal CsAuI3.  United States.  https://doi.org/10.1103/PhysRevB.87.054104

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                    Wang, Shibing, Hirai, Shigeto, Shapiro, Max C., Riggs, Scott C., Geballe, Ted H., Mao, Wendy L., and Fisher, Ian R. Wed .  
"Pressure-induced symmetry breaking in tetragonal CsAuI3".  United States.  https://doi.org/10.1103/PhysRevB.87.054104.

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@article{osti_1102027,

  title        = {Pressure-induced symmetry breaking in tetragonal CsAuI3},

  author       = {Wang, Shibing and Hirai, Shigeto and Shapiro, Max C. and Riggs, Scott C. and Geballe, Ted H. and Mao, Wendy L. and Fisher, Ian R.},

  abstractNote = {},

  doi          = {10.1103/PhysRevB.87.054104},

  journal      = {Physical Review. B, Condensed Matter and Materials Physics},

  number       = 5,

  volume       = 87,

  place        = {United States},

  year         = {Wed Feb 06 00:00:00 EST 2013},

  month        = {Wed Feb 06 00:00:00 EST 2013}

}

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Works referenced in this record:

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Single crystal growth by self-flux method of the mixed valence gold halides Cs2[AuIX2][AuIIIX4] (X=Br,I)
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Kitagawa, Hiroshi; Kojima, Norimichi; Nakajima, Tsuyoshi
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Metallization and phase transitions of the three-dimensional halogen-bridge mixed-valence complex Cs2Au2I6 under high pressure
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Polymorphism in BaPb $_{1 - x}$ Bi $_{x}$ O $_{3}$ at the superconducting composition
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Single crystal X-ray diffraction study of a mixed-valence gold compound, Cs2AuIAuIIICl6 under high pressures up to 18GPa: Pressure-induced phase transition coupled with gold valence transition
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Sakata, Makoto; Itsubo, Takafumi; Nishibori, Eiji
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Divalent gold in perovskite type CsAuI3
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Title: Pressure-induced symmetry breaking in tetragonal CsAuI3

Citation Formats

Studies of mixed-valence states in three-dimensional halogen-bridged gold compounds, Cs2Au I Au III X6(X = Cl, Br or I). Part 1. Synthesis, X-ray powder diffraction, and electron spin resonance studies of CsAu0.6Br2.6 journal, January 1991

P-T Phase Diagram and Gold Valence State of the Perovskite-Type Mixed-Valence Compounds Cs2Au2X6 (X = Cl, Br, and I) under High Pressures journal, December 1994

Pressure suppression of charge order without metallisation in Cs2Au2I6 journal, January 2010

Electronic structure of the gold complexes Cs 2 Au 2 X 6 ( X =I, Br, and Cl) journal, March 1999

Single crystal growth by self-flux method of the mixed valence gold halides Cs2[AuIX2][AuIIIX4] (X=Br,I) journal, September 2012

Studies of mixed-valence states in three-dimensional halogen-bridged gold compounds, Cs2Au I Au III X6, (X = Cl, Br or I). Part 2. X-Ray photoelectron spectroscopic study journal, January 1991

The influence of high hydrostatic pressure on the crystal structure of cesium gold chloride (Cs 2 Au I Au III Cl 6 ) in the pressure range up to 52 × 10 8 Pa journal, May 1979

Valence state of Tm in Tm X ( X = S , Se , Te ) investigated by resonant inelastic x-ray scattering journal, August 2005

Metallization and phase transitions of the three-dimensional halogen-bridge mixed-valence complex Cs2Au2I6 under high pressure journal, June 1991

Polymorphism in BaPb 1 − x Bi x O 3 at the superconducting composition journal, May 2011

Single crystal X-ray diffraction study of a mixed-valence gold compound, Cs2AuIAuIIICl6 under high pressures up to 18GPa: Pressure-induced phase transition coupled with gold valence transition journal, April 2007

EXPGUI , a graphical user interface for GSAS journal, April 2001

Ultrafast pump-probe measurements of short small-polaron lifetimes in the mixed-valence perovskite Cs 2 Au 2 I 6 under high pressures journal, February 2012

P–T phase diagram and Au valence state of the perovskite-type Au mixed-valence complexes M2[AuIX2][AuIIIX4] (M=K, Rb, Cs; X=Cl, Br, I) journal, March 2000

Gold Valence Transition and Phase Diagram in the Mixed-Valence Complexes, M 2 [Au I X 2 ][Au III X 4 ] (M = Rb, Cs; X = Cl, Br, and I) journal, July 2000

Charge density study under high pressure journal, December 2004

Divalent gold in perovskite type CsAuI3 journal, September 1994

The Crystal Structure of Cesium Aurous Auric Chloride, Cs 2 AuAuCl 6 , and Cesium Argentous Auric Chloride, Cs 2 AgAuCl 6 journal, August 1938

Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions journal, January 1986

A Three-Dimensional Iodo-Bridged Mixed-Valence Gold(I, III) Compound, Cs 2 Au I Au III I 6 journal, June 1997

Two-dimensional detector software: From real detector to idealised image or two-theta scan journal, January 1996

Title: Pressure-induced symmetry breaking in tetragonal CsAuI₃

Studies of mixed-valence states in three-dimensional halogen-bridged gold compounds, Cs2Au I Au III X6(X = Cl, Br or I). Part 1. Synthesis, X-ray powder diffraction, and electron spin resonance studies of CsAu0.6Br2.6
journal, January 1991

P-T Phase Diagram and Gold Valence State of the Perovskite-Type Mixed-Valence Compounds Cs2Au2X6 (X = Cl, Br, and I) under High Pressures
journal, December 1994

Pressure suppression of charge order without metallisation in Cs2Au2I6
journal, January 2010

Electronic structure of the gold complexes ${Cs}_{2} {Au}_{2} X_{6} (X$ =I, Br, and Cl)
journal, March 1999

Single crystal growth by self-flux method of the mixed valence gold halides Cs2[AuIX2][AuIIIX4] (X=Br,I)
journal, September 2012

Studies of mixed-valence states in three-dimensional halogen-bridged gold compounds, Cs2Au I Au III X6, (X = Cl, Br or I). Part 2. X-Ray photoelectron spectroscopic study
journal, January 1991

The influence of high hydrostatic pressure on the crystal structure of cesium gold chloride (Cs ₂ Au ^I Au ^III Cl ₆ ) in the pressure range up to 52 × 10 ⁸ Pa
journal, May 1979

Valence state of $Tm$ in $Tm X$ $(X = S, Se, Te)$ investigated by resonant inelastic x-ray scattering
journal, August 2005

Metallization and phase transitions of the three-dimensional halogen-bridge mixed-valence complex Cs2Au2I6 under high pressure
journal, June 1991

Polymorphism in BaPb $_{1 - x}$ Bi $_{x}$ O $_{3}$ at the superconducting composition
journal, May 2011

Single crystal X-ray diffraction study of a mixed-valence gold compound, Cs2AuIAuIIICl6 under high pressures up to 18GPa: Pressure-induced phase transition coupled with gold valence transition
journal, April 2007

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Ultrafast pump-probe measurements of short small-polaron lifetimes in the mixed-valence perovskite Cs $_{2}$ Au $_{2}$ I $_{6}$ under high pressures
journal, February 2012

P–T phase diagram and Au valence state of the perovskite-type Au mixed-valence complexes M2[AuIX2][AuIIIX4] (M=K, Rb, Cs; X=Cl, Br, I)
journal, March 2000

Gold Valence Transition and Phase Diagram in the Mixed-Valence Complexes, M ₂ [Au ^I X ₂ ][Au ^III X ₄ ] (M = Rb, Cs; X = Cl, Br, and I)
journal, July 2000

Charge density study under high pressure
journal, December 2004

Divalent gold in perovskite type CsAuI3
journal, September 1994

The Crystal Structure of Cesium Aurous Auric Chloride, Cs ₂ AuAuCl ₆ , and Cesium Argentous Auric Chloride, Cs ₂ AgAuCl ₆
journal, August 1938

Calibration of the ruby pressure gauge to 800 kbar under quasi-hydrostatic conditions
journal, January 1986

A Three-Dimensional Iodo-Bridged Mixed-Valence Gold(I, III) Compound, Cs ₂ Au ^I Au ^III I ₆
journal, June 1997

Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996