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Title: Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

Abstract

A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show how this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.

Authors:
 [1];  [2];  [2];  [3];  [3]
  1. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences
  2. Harvard Univ., Cambridge, MA (United States). Wyss Institute for Biologically Inspired Engineering
  3. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences; Harvard Univ., Cambridge, MA (United States). Wyss Institute for Biologically Inspired Engineering
Publication Date:
Research Org.:
Harvard Univ., Cambridge, MA (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1097119
Report Number(s):
DOE-HARVARD-AR0000326-3
Journal ID: ISSN 2041-1723
Grant/Contract Number:  
AR0000326
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 4; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; physical sciences; materials science; nanotechnology

Citation Formats

Vogel, Nicolas, Belisle, Rebecca A., Hatton, Benjamin, Wong, Tak-Sing, and Aizenberg, Joanna. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers. United States: N. p., 2013. Web. doi:10.1038/ncomms3176.
Vogel, Nicolas, Belisle, Rebecca A., Hatton, Benjamin, Wong, Tak-Sing, & Aizenberg, Joanna. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers. United States. doi:10.1038/ncomms3176.
Vogel, Nicolas, Belisle, Rebecca A., Hatton, Benjamin, Wong, Tak-Sing, and Aizenberg, Joanna. Wed . "Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers". United States. doi:10.1038/ncomms3176. https://www.osti.gov/servlets/purl/1097119.
@article{osti_1097119,
title = {Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers},
author = {Vogel, Nicolas and Belisle, Rebecca A. and Hatton, Benjamin and Wong, Tak-Sing and Aizenberg, Joanna},
abstractNote = {A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show how this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.},
doi = {10.1038/ncomms3176},
journal = {Nature Communications},
number = ,
volume = 4,
place = {United States},
year = {2013},
month = {7}
}

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Works referenced in this record:

Super-Water-Repellent Fractal Surfaces
journal, January 1996

  • Onda, T.; Shibuichi, S.; Satoh, N.
  • Langmuir, Vol. 12, Issue 9, p. 2125-2127
  • DOI: 10.1021/la950418o

Super-Hydrophobic Surfaces: From Natural to Artificial
journal, December 2002


Mimicking the Lotus Effect:  Influence of Double Roughness Structures and Slender Pillars
journal, September 2004


Designing Superoleophobic Surfaces
journal, December 2007


Robust omniphobic surfaces
journal, November 2008

  • Tuteja, A.; Choi, W.; Mabry, J. M.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 47, p. 18200-18205
  • DOI: 10.1073/pnas.0804872105

Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating
journal, December 2011


Hierarchically Structured Superoleophobic Surfaces with Ultralow Contact Angle Hysteresis
journal, August 2012

  • Kota, Arun K.; Li, Yongxin; Mabry, Joseph M.
  • Advanced Materials, Vol. 24, Issue 43
  • DOI: 10.1002/adma.201202554

Wetting Resistance at Its Topographical Limit: The Benefit of Mushroom and Serif T Structures
journal, January 2013

  • Hensel, René; Helbig, Ralf; Aland, Sebastian
  • Langmuir, Vol. 29, Issue 4
  • DOI: 10.1021/la304179b

Purity of the sacred lotus, or escape from contamination in biological surfaces
journal, April 1997


Robust superhydrophobic surfaces with mechanical durability and easy repairability
journal, January 2011

  • Zhu, Xiaotao; Zhang, Zhaozhu; Men, Xuehu
  • Journal of Materials Chemistry, Vol. 21, Issue 39
  • DOI: 10.1039/c1jm12513c

Effect of Surface Wettability on the Adsorption of Proteins and Detergents
journal, April 1998

  • Sigal, George B.; Mrksich, Milan; Whitesides, George M.
  • Journal of the American Chemical Society, Vol. 120, Issue 14
  • DOI: 10.1021/ja970819l

Role of hydrophobicity in bacterial adherence to carbon nanostructures and biofilm formation
journal, January 2010


Metastable Underwater Superhydrophobicity
journal, October 2010

  • Poetes, Rosa; Holtzmann, Kathrin; Franze, Kristian
  • Physical Review Letters, Vol. 105, Issue 16, Article No. 166104
  • DOI: 10.1103/PhysRevLett.105.166104

Quantitative Testing of Robustness on Superomniphobic Surfaces by Drop Impact
journal, December 2010

  • Nhung Nguyen, Thi Phuong; Brunet, Philippe; Coffinier, Yannick
  • Langmuir, Vol. 26, Issue 23, p. 18369-18373
  • DOI: 10.1021/la103097y

Insect aquaplaning: Nepenthes pitcher plants capture prey with the peristome, a fully wettable water-lubricated anisotropic surface
journal, September 2004

  • Bohn, H. F.; Federle, W.
  • Proceedings of the National Academy of Sciences, Vol. 101, Issue 39, p. 14138-14143
  • DOI: 10.1073/pnas.0405885101

Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity
journal, September 2011

  • Wong, Tak-Sing; Kang, Sung Hoon; Tang, Sindy K. Y.
  • Nature, Vol. 477, Issue 7365, p. 443-447
  • DOI: 10.1038/nature10447

Liquid-infused structured surfaces with exceptional anti-biofouling performance
journal, July 2012

  • Epstein, A. K.; Wong, T. -S.; Belisle, R. A.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 33
  • DOI: 10.1073/pnas.1201973109

Liquid-Infused Nanostructured Surfaces with Extreme Anti-Ice and Anti-Frost Performance
journal, June 2012

  • Kim, Philseok; Wong, Tak-Sing; Alvarenga, Jack
  • ACS Nano, Vol. 6, Issue 8
  • DOI: 10.1021/nn302310q

Enhanced Condensation on Lubricant-Impregnated Nanotextured Surfaces
journal, October 2012

  • Anand, Sushant; Paxson, Adam T.; Dhiman, Rajeev
  • ACS Nano, Vol. 6, Issue 11, p. 10122-10129
  • DOI: 10.1021/nn303867y

Perfluoropolyether-infused nano-texture: a versatile approach to omniphobic coatings with low hysteresis and high transparency
journal, January 2013

  • Ma, Wei; Higaki, Yuji; Otsuka, Hideyuki
  • Chem. Commun., Vol. 49, Issue 6
  • DOI: 10.1039/C2CC37576A

Hierarchical or Not? Effect of the Length Scale and Hierarchy of the Surface Roughness on Omniphobicity of Lubricant-Infused Substrates
journal, March 2013

  • Kim, Philseok; Kreder, Michael J.; Alvarenga, Jack
  • Nano Letters, Vol. 13, Issue 4, p. 1793-1799
  • DOI: 10.1021/nl4003969

Vapor-Phase Synthesis of Mesoporous Silica Thin Films
journal, February 2003

  • Nishiyama, Norikazu; Tanaka, Shunsuke; Egashira, Yasuyuki
  • Chemistry of Materials, Vol. 15, Issue 4
  • DOI: 10.1021/cm021011p

Two-dimensional hierarchical porous silica film and its tunable superhydrophobicity
journal, December 2005


Silver Hierarchical Bowl-Like Array:  Synthesis, Superhydrophobicity, and Optical Properties
journal, September 2007

  • Li, Yue; Li, Cuncheng; Cho, Sung Oh
  • Langmuir, Vol. 23, Issue 19
  • DOI: 10.1021/la700847c

Silver nanosheet-coated inverse opal film as a highly active and uniform SERS substrate
journal, January 2012

  • He, Lifang; Huang, Jianan; Xu, Tingting
  • J. Mater. Chem., Vol. 22, Issue 4
  • DOI: 10.1039/C1JM14144A

From soft to hard: the generation of functional and complex colloidal monolayers for nanolithography
journal, January 2012

  • Vogel, Nicolas; Weiss, Clemens K.; Landfester, Katharina
  • Soft Matter, Vol. 8, Issue 15, p. 4044-4061
  • DOI: 10.1039/C1SM06650A

Minimal Size of Coffee Ring Structure
journal, April 2010

  • Shen, Xiaoying; Ho, Chih-Ming; Wong, Tak-Sing
  • The Journal of Physical Chemistry B, Vol. 114, Issue 16
  • DOI: 10.1021/jp912190v

Nanochromatography Driven by the Coffee Ring Effect
journal, March 2011

  • Wong, Tak-Sing; Chen, Ting-Hsuan; Shen, Xiaoying
  • Analytical Chemistry, Vol. 83, Issue 6
  • DOI: 10.1021/ac102963x

Wafer-Scale Fabrication of Ordered Binary Colloidal Monolayers with Adjustable Stoichiometries
journal, May 2011

  • Vogel, Nicolas; de Viguerie, Laurence; Jonas, Ulrich
  • Advanced Functional Materials, Vol. 21, Issue 16, p. 3064-3073
  • DOI: 10.1002/adfm.201100414

A Convenient Method to Produce Close- and Non-close-Packed Monolayers using Direct Assembly at the Air-Water Interface and Subsequent Plasma-Induced Size Reduction
journal, June 2011

  • Vogel, Nicolas; Goerres, Sebastian; Landfester, Katharina
  • Macromolecular Chemistry and Physics, Vol. 212, Issue 16, p. 1719-1734
  • DOI: 10.1002/macp.201100187

Superhydrophobic Coatings on Curved Surfaces Featuring Remarkable Supporting Force
journal, October 2007

  • Li, Yue; Lee, Eun Je; Cho, Sung Oh
  • The Journal of Physical Chemistry C, Vol. 111, Issue 40
  • DOI: 10.1021/jp073672l

Probing guided modes in a monolayer colloidal crystal on a flat metal film
journal, November 2012


Bacterial biofilms: from the Natural environment to infectious diseases
journal, February 2004

  • Hall-Stoodley, Luanne; Costerton, J. William; Stoodley, Paul
  • Nature Reviews Microbiology, Vol. 2, Issue 2, p. 95-108
  • DOI: 10.1038/nrmicro821

Estimating Health Care-Associated Infections and Deaths in U.S. Hospitals, 2002
journal, March 2007

  • Klevens, R. Monina; Edwards, Jonathan R.; Richards, Chesley L.
  • Public Health Reports, Vol. 122, Issue 2
  • DOI: 10.1177/003335490712200205

Bacterial flagella explore microscale hummocks and hollows to increase adhesion
journal, March 2013

  • Friedlander, R. S.; Vlamakis, H.; Kim, P.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 14
  • DOI: 10.1073/pnas.1219662110

Relationships between Water Wettability and Ice Adhesion
journal, October 2010

  • Meuler, Adam J.; Smith, J. David; Varanasi, Kripa K.
  • ACS Applied Materials & Interfaces, Vol. 2, Issue 11, p. 3100-3110
  • DOI: 10.1021/am1006035

Resistance Of Solid Surfaces To Wetting By Water
journal, August 1936

  • Wenzel, Robert N.
  • Industrial & Engineering Chemistry, Vol. 28, Issue 8, p. 988-994
  • DOI: 10.1021/ie50320a024

    Works referencing / citing this record:

    Fundamentals of icing and common strategies for designing biomimetic anti-icing surfaces
    journal, January 2018

    • Li, Qi; Guo, Zhiguang
    • Journal of Materials Chemistry A, Vol. 6, Issue 28
    • DOI: 10.1039/c8ta03259a