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Title: Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers

Journal Article · · Nature Communications
DOI: https://doi.org/10.1038/ncomms3176 · OSTI ID:1097119
 [1];  [2];  [2];  [3];  [3]
  1. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences; Wyss Institute at Harvard
  2. Harvard Univ., Cambridge, MA (United States). Wyss Institute for Biologically Inspired Engineering
  3. Harvard Univ., Cambridge, MA (United States). School of Engineering and Applied Sciences; Harvard Univ., Cambridge, MA (United States). Wyss Institute for Biologically Inspired Engineering

A transparent coating that repels a wide variety of liquids, prevents staining, is capable of self-repair and is robust towards mechanical damage can have a broad technological impact, from solar cell coatings to self-cleaning optical devices. Here we employ colloidal templating to design transparent, nanoporous surface structures. A lubricant can be firmly locked into the structures and, owing to its fluidic nature, forms a defect-free, self-healing interface that eliminates the pinning of a second liquid applied to its surface, leading to efficient liquid repellency, prevention of adsorption of liquid-borne contaminants, and reduction of ice adhesion strength. We further show how this method can be applied to locally pattern the repellent character of the substrate, thus opening opportunities to spatially confine any simple or complex fluids. The coating is highly defect-tolerant due to its interconnected, honeycomb wall structure, and repellency prevails after the application of strong shear forces and mechanical damage. The regularity of the coating allows us to understand and predict the stability or failure of repellency as a function of lubricant layer thickness and defect distribution based on a simple geometric model.

Research Organization:
Harvard Univ., Cambridge, MA (United States)
Sponsoring Organization:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
Grant/Contract Number:
AR0000326
OSTI ID:
1097119
Report Number(s):
DOE-HARVARD--AR0000326-3
Journal Information:
Nature Communications, Journal Name: Nature Communications Vol. 4; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

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Wafer-Scale Fabrication of Ordered Binary Colloidal Monolayers with Adjustable Stoichiometries journal May 2011
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Silver nanosheet-coated inverse opal film as a highly active and uniform SERS substrate journal January 2012
From soft to hard: the generation of functional and complex colloidal monolayers for nanolithography journal January 2012
Perfluoropolyether-infused nano-texture: a versatile approach to omniphobic coatings with low hysteresis and high transparency journal January 2013
Robust superhydrophobic surfaces with mechanical durability and easy repairability journal January 2011
Wettability of porous surfaces journal January 1944
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Metastable Underwater Superhydrophobicity journal October 2010
Designing Superoleophobic Surfaces journal December 2007
Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating journal December 2011
Estimating Health Care-Associated Infections and Deaths in U.S. Hospitals, 2002 journal March 2007

Cited By (53)

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Surface Patterning with SiO 2 @PNiPAm Core–Shell Particles journal September 2018
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Extremely durable biofouling-resistant metallic surfaces based on electrodeposited nanoporous tungstite films on steel journal October 2015
Zwitterionic Nanofibers of Super-Glue for Transparent and Biocompatible Multi-Purpose Coatings journal September 2015
Bio-inspired dewetted surfaces based on SiC/Si interlocked structures for enhanced-underwater stability and regenerative-drag reduction capability journal April 2016
Amphiphobic Nanostructured Coatings for Industrial Applications journal March 2019
Emerging Anti-Fouling Methods: Towards Reusability of 3D-Printed Devices for Biomedical Applications journal April 2018
Electrowetting on liquid-infused film (EWOLF): Complete reversibility and controlled droplet oscillation suppression for fast optical imaging preprint January 2014
Integration of Self-Lubrication and Near-Infrared Photothermogenesis for Excellent Anti-Icing/Deicing Performance journal May 2015
Lubricant-Infused Anisotropic Porous Surface Design of Reduced Graphene Oxide Toward Electrically Driven Smart Control of Conductive Droplets' Motion journal April 2017
Photoelectric Synergetic Responsive Slippery Surfaces Based on Tailored Anisotropic Films Generated by Interfacial Directional Freezing journal May 2018
Slippery Lubricant-Infused Surfaces: Properties and Emerging Applications journal December 2018
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Bioinspired Materials: from Low to High Dimensional Structure journal September 2014
Lithographic Design of Overhanging Microdisk Arrays Toward Omniphobic Surfaces journal November 2015
Single-Step Fabrication of High-Density Microdroplet Arrays of Low-Surface-Tension Liquids journal February 2016
Complex High-Aspect-Ratio Metal Nanostructures by Secondary Sputtering Combined with Block Copolymer Self-Assembly journal August 2016
Droplet Microarrays: From Surface Patterning to High-Throughput Applications journal March 2018
Multistimuli Responsive Liquid‐Release in Dynamic Polymer Coatings for Controlling Surface Slipperiness and Optical Performance journal August 2019
Self‐Supplying Liquidity Oil‐Adsorbed Slippery Smooth Surface for Both Liquid and Solid Repellency journal December 2019
Slippery Surface Based on Photoelectric Responsive Nanoporous Composites with Optimal Wettability Region for Droplets' Multifunctional Manipulation journal November 2018
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Direct observation of drops on slippery lubricant-infused surfaces journal January 2015
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A superrepellent coating with dynamic fluorine chains for frosting suppression: effects of polarity, coalescence and ice nucleation free energy barrier journal January 2016
Durable gels with ultra-low adhesion to ice journal January 2016
Facilitating tumor spheroid-based bioassays and in vitro blood vessel modeling via bioinspired self-formation microstructure devices journal January 2018
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Fundamentals of icing and common strategies for designing biomimetic anti-icing surfaces journal January 2018
A stable solid slippery surface with thermally assisted self-healing ability journal January 2018
A facile approach to achieve bioinspired PDMS@Fe 3 O 4 fabric with switchable wettability for liquid transport and water collection journal January 2018
Bio-inspired intelligent structural color materials journal January 2019
Temperature-induced switchable interfacial interactions on slippery surfaces for controllable liquid manipulation journal January 2019
Design of surfaces for controlling hard and soft fouling
  • Halvey, Alex Kate; Macdonald, Brian; Dhyani, Abhishek
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2138 https://doi.org/10.1098/rsta.2018.0266
journal December 2018
Bioinspired shape-memory graphene film with tunable wettability journal June 2017
Supramolecular silicone coating capable of strong substrate bonding, readily damage healing, and easy oil sliding journal November 2019
Immobilized liquid layers: A new approach to anti-adhesion surfaces for medical applications journal March 2016
Amphiphobic Nanostructured Coatings for Industrial Applications journal March 2019
Fluoropolymer-Containing Opals and Inverse Opals by Melt-Shear Organization journal January 2019
Single-Step Fabrication of High-Density Microdroplet Arrays of Low-Surface-Tension Liquids text January 2016
Droplet Microarrays: From Surface Patterning to High-Throughput Applications text January 2018
Slippery Lubricant-Infused Surfaces: Properties and Emerging Applications text January 2019

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