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Title: Fireside corrosion in oxy-fuel combustion of coal

Journal Article · · ECS Transactions
DOI: https://doi.org/10.1149/1.4718001 · OSTI ID:1051404
 [1];  [1];  [2];  [2];  [2];  [2];  [2]
  1. National Energy Technology Lab. (NETL), Albany, OR (United States)
  2. Univ. of Pittsburgh, Pittsburgh, PA (United States); National Energy Technology Lab., Pittsburgh, PA (United States)

Oxy-fuel combustion is based on burning fossil fuels in a mixture of recirculated flue gas and oxygen, rather than in air. An optimized oxy-combustion power plant will have ultra-low emissions since the flue gas that results from oxy-fuel combustion consists almost entirely of CO2 and water vapor. Once the water vapor is condensed, it is relatively easy to sequester the CO2 so that it does not escape into the atmosphere. A variety of laboratory tests comparing air-firing to oxy-firing conditions, and tests examining specific simpler combinations of oxidants, were conducted at 650-700 C. Alloys studied included model Fe-Cr and Ni-Cr alloys, commercial ferritic steels, austenitic steels, and nickel base superalloys. Furthermore, the observed corrosion behavior shows accelerated corrosion even with sulfate additions that remain solid at the tested temperatures, encapsulation of ash components in outer iron oxide scales, and a differentiation between oxy-fuel combustion flue gas recirculation choices.

Research Organization:
National Energy Technology Lab. (NETL), Albany, OR (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
OSTI ID:
1051404
Report Number(s):
NETL-PUB--228
Journal Information:
ECS Transactions, Journal Name: ECS Transactions Journal Issue: 42 Vol. 41; ISSN 1938-5862
Publisher:
Electrochemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

Cited By (1)

Simulated fireside corrosion of T91 in oxy-combustion systems with an emphasis on coal/biomass environments journal March 2019

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