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Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO:Cu{sup 2+} nanorods

Abstract

Copper doped ZnO nanoparticles were synthesized by the chemical technique based on the hydrothermal method. The crystallite structure, morphology and size were determined by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and scanning electron microscopy (SEM) for different doping percentages of Cu{sup 2+} (1-10%). TEM/SEM images showed formation of uniform nanorods, the aspect ratio of which varied with doping percentage of Cu{sup 2+}. The wurtzite structure of ZnO gradually degrades with the increasing Cu{sup 2+} doping concentration and an additional CuO associated diffraction peak was observed above 8% of Cu{sup 2+} doping. The change in magnetic behavior of the nanoparticles of ZnO with varying Cu{sup 2+} doping concentrations was investigated using a vibrating sample magnetometer (VSM). Initially these nanoparticles showed strong room-temperature ferromagnetic behavior, however at higher doping percentage of copper the ferromagnetic behavior was suppressed and paramagnetic nature was enhanced.
Authors:
Sharma, Prashant K. , E-mail: prashantnac@gmail.com; [1]  Dutta, Ranu K; Pandey, Avinash C [1] 
  1. Nanophosphor Application Centre, University of Allahabad, Allahabad 211002 (India)
Publication Date:
Dec 15, 2009
Product Type:
Journal Article
Resource Relation:
Journal Name: Journal of Magnetism and Magnetic Materials; Journal Volume: 321; Journal Issue: 24; Other Information: DOI: 10.1016/j.jmmm.2009.07.066; PII: S0304-8853(09)00803-8; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Subject:
36 MATERIALS SCIENCE; ASPECT RATIO; COPPER IONS; COPPER OXIDES; DOPED MATERIALS; FERROMAGNETISM; HYDROTHERMAL SYNTHESIS; MAGNETIC SEMICONDUCTORS; MORPHOLOGY; NANOSTRUCTURES; PARAMAGNETISM; SCANNING ELECTRON MICROSCOPY; TEMPERATURE RANGE 0273-0400 K; TRANSMISSION ELECTRON MICROSCOPY; VIBRATING SAMPLE MAGNETOMETERS; X-RAY DIFFRACTION; ZINC OXIDES
OSTI ID:
21259330
Country of Origin:
Netherlands
Language:
English
Other Identifying Numbers:
Journal ID: ISSN 0304-8853; JMMMDC; TRN: NL09S1078010147
Availability:
Available from http://dx.doi.org/10.1016/j.jmmm.2009.07.066;INIS
Submitting Site:
NLN
Size:
page(s) 4001-4005
Announcement Date:
Mar 04, 2010

Citation Formats

Sharma, Prashant K. , E-mail: prashantnac@gmail.com, Dutta, Ranu K, and Pandey, Avinash C. Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO:Cu{sup 2+} nanorods. Netherlands: N. p., 2009. Web. doi:10.1016/j.jmmm.2009.07.066.
Sharma, Prashant K. , E-mail: prashantnac@gmail.com, Dutta, Ranu K, & Pandey, Avinash C. Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO:Cu{sup 2+} nanorods. Netherlands. https://doi.org/10.1016/j.jmmm.2009.07.066
Sharma, Prashant K. , E-mail: prashantnac@gmail.com, Dutta, Ranu K, and Pandey, Avinash C. 2009. "Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO:Cu{sup 2+} nanorods." Netherlands. https://doi.org/10.1016/j.jmmm.2009.07.066.
@misc{etde_21259330,
title = {Doping dependent room-temperature ferromagnetism and structural properties of dilute magnetic semiconductor ZnO:Cu{sup 2+} nanorods}
author = {Sharma, Prashant K. , E-mail: prashantnac@gmail.com, Dutta, Ranu K, and Pandey, Avinash C}
abstractNote = {Copper doped ZnO nanoparticles were synthesized by the chemical technique based on the hydrothermal method. The crystallite structure, morphology and size were determined by X-ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and scanning electron microscopy (SEM) for different doping percentages of Cu{sup 2+} (1-10%). TEM/SEM images showed formation of uniform nanorods, the aspect ratio of which varied with doping percentage of Cu{sup 2+}. The wurtzite structure of ZnO gradually degrades with the increasing Cu{sup 2+} doping concentration and an additional CuO associated diffraction peak was observed above 8% of Cu{sup 2+} doping. The change in magnetic behavior of the nanoparticles of ZnO with varying Cu{sup 2+} doping concentrations was investigated using a vibrating sample magnetometer (VSM). Initially these nanoparticles showed strong room-temperature ferromagnetic behavior, however at higher doping percentage of copper the ferromagnetic behavior was suppressed and paramagnetic nature was enhanced.}
doi = {10.1016/j.jmmm.2009.07.066}
journal = []
issue = {24}
volume = {321}
place = {Netherlands}
year = {2009}
month = {Dec}
}