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Synthesis of Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N thin films by ion beam enhanced deposition method and their structure and properties

Abstract

Some Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N films were synthesized by N ion beam enhanced deposition and synchronized N-Ti ion beams enhanced deposition methods respectively. The microstructure of the films was determined to be of {gamma}-Mo{sub 2}N phase by the X-ray diffraction and transmission electron diffraction experiments. The scratch tests demonstrated that the metal ion beam could effectively improve adhesion of the films. The scratch critical loading of the Mo{sub 2-x}Ti{sub x}N film was measured to be about 3000 gf, which is about twice as large as that of the Mo{sub 2}N film. The corrosion resistance of the films was analyzed by the anode polarizing tests. The corrosion-self voltage and corrosion-self current of the Mo{sub 2}N film and the Mo{sub 2-x}Ti{sub x}N film in a 0.5 mol/L H{sub 2}SO{sub 4} solution were found to be 32 mV, 0.5 {mu}A/cm{sup 2} and 166 mV, 0.26 {mu}A/cm{sup 2} respectively. These results indicated that the corrosion resistance of the Mo{sub 2-x}Ti{sub x}N film was much better than that of the Mo{sub 2}N film.
Authors:
Bangzhi, Liu; Guoqing, Li; Zongxin, Mu; Jialiang, Zhang; Yan, Cui; [1]  Wong, N B; Aoron, H [2] 
  1. The Key Natinal Laboratory for Materials Surface Modification, Dalian Univ. of Technology, Dalian (China)
  2. City Uiversity of Hong Kong (China)
Publication Date:
Jul 01, 2000
Product Type:
Journal Article
Reference Number:
EDB-01:078763
Resource Relation:
Journal Name: Nuclear Techniques; Journal Volume: 23; Journal Issue: 7; Other Information: PBD: Jul 2000
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CORROSION RESISTANCE; DEPOSITION; ION BEAMS; MICROSTRUCTURE; MOLYBDENUM NITRIDES; NITROGEN IONS; THIN FILMS; TITANIUM IONS; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION
OSTI ID:
20186153
Country of Origin:
China
Language:
Chinese
Other Identifying Numbers:
Journal ID: ISSN 0253-3219; NUTEDL; TRN: CN0102129040322
Submitting Site:
INIS
Size:
page(s) 483-487
Announcement Date:
Sep 28, 2001

Citation Formats

Bangzhi, Liu, Guoqing, Li, Zongxin, Mu, Jialiang, Zhang, Yan, Cui, Wong, N B, and Aoron, H. Synthesis of Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N thin films by ion beam enhanced deposition method and their structure and properties. China: N. p., 2000. Web.
Bangzhi, Liu, Guoqing, Li, Zongxin, Mu, Jialiang, Zhang, Yan, Cui, Wong, N B, & Aoron, H. Synthesis of Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N thin films by ion beam enhanced deposition method and their structure and properties. China.
Bangzhi, Liu, Guoqing, Li, Zongxin, Mu, Jialiang, Zhang, Yan, Cui, Wong, N B, and Aoron, H. 2000. "Synthesis of Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N thin films by ion beam enhanced deposition method and their structure and properties." China.
@misc{etde_20186153,
title = {Synthesis of Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N thin films by ion beam enhanced deposition method and their structure and properties}
author = {Bangzhi, Liu, Guoqing, Li, Zongxin, Mu, Jialiang, Zhang, Yan, Cui, Wong, N B, and Aoron, H}
abstractNote = {Some Mo{sub 2}N and Mo{sub 2-x}Ti{sub x}N films were synthesized by N ion beam enhanced deposition and synchronized N-Ti ion beams enhanced deposition methods respectively. The microstructure of the films was determined to be of {gamma}-Mo{sub 2}N phase by the X-ray diffraction and transmission electron diffraction experiments. The scratch tests demonstrated that the metal ion beam could effectively improve adhesion of the films. The scratch critical loading of the Mo{sub 2-x}Ti{sub x}N film was measured to be about 3000 gf, which is about twice as large as that of the Mo{sub 2}N film. The corrosion resistance of the films was analyzed by the anode polarizing tests. The corrosion-self voltage and corrosion-self current of the Mo{sub 2}N film and the Mo{sub 2-x}Ti{sub x}N film in a 0.5 mol/L H{sub 2}SO{sub 4} solution were found to be 32 mV, 0.5 {mu}A/cm{sup 2} and 166 mV, 0.26 {mu}A/cm{sup 2} respectively. These results indicated that the corrosion resistance of the Mo{sub 2-x}Ti{sub x}N film was much better than that of the Mo{sub 2}N film.}
journal = []
issue = {7}
volume = {23}
journal type = {AC}
place = {China}
year = {2000}
month = {Jul}
}