Catalytic Applications of Vanadium: A Mechanistic Perspective

Langeslay, Ryan R.; Kaphan, David M.; Marshall, Christopher L.; Stair, Peter C.; Sattelberger, Alfred P.; Delferro, Massimiliano

doi:10.1021/acs.chemrev.8b00245

Title: Catalytic Applications of Vanadium: A Mechanistic Perspective

Journal Article · Mon Oct 08 00:00:00 EDT 2018 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.8b00245· OSTI ID:1509906

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^[1]; Stair, Peter C. ^[2]; Sattelberger, Alfred P. ^[1];

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Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Northwestern Univ., Evanston, IL (United States)

The chemistry of vanadium has seen remarkable activity in the past SO years. In the present review, reactions catalyzed by homogeneous and supported vanadium complexes from 2008 to 2018 are summarized and discussed. Here particular attention is given to mechanistic and kinetics studies of vanadium-catalyzed reactions including oxidations of alkanes, alkenes, arenes, alcohols, aldehydes, ketones, and sulfur species, as well as oxidative C-C and C-O bond cleavage, carbon carbon bond formation, deoxydehydration, haloperoxidase, cyanation, hydrogenation, dehydrogenation, ring-opening metathesis polymerization, and oxo/imido heterometathesis. Additionally, insights into heterogeneous vanadium catalysis are provided when parallels can be drawn from the homogeneous literature.

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Title: Catalytic Applications of Vanadium: A Mechanistic Perspective

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