Flow injection trace gas analysis method for on-site determination of organoarsenicals
Abstract
A method for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere.
- Inventors:
-
- (Orland Park, IL)
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- OSTI Identifier:
- 871016
- Patent Number(s):
- 5641686
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Classifications (CPCs):
-
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- flow; injection; trace; gas; analysis; method; on-site; determination; organoarsenicals; real-time; concentration; lewisite; ambient; atmosphere; separating; collecting; sample; collection; chamber; converting; collected; arsenite; solution; pumping; containing; electrochemical; detector; connected; electrochemically; detecting; converted; whereby; detected; proportional; gas analysis; flow injection; ambient atmosphere; collection chamber; analysis method; electrochemical detector; containing sample; trace gas; /436/204/422/
Citation Formats
Aldstadt, III, Joseph H. Flow injection trace gas analysis method for on-site determination of organoarsenicals. United States: N. p., 1997.
Web.
Aldstadt, III, Joseph H. Flow injection trace gas analysis method for on-site determination of organoarsenicals. United States.
Aldstadt, III, Joseph H. Wed .
"Flow injection trace gas analysis method for on-site determination of organoarsenicals". United States. https://www.osti.gov/servlets/purl/871016.
@article{osti_871016,
title = {Flow injection trace gas analysis method for on-site determination of organoarsenicals},
author = {Aldstadt, III, Joseph H.},
abstractNote = {A method for real-time determination of the concentration of Lewisite in the ambient atmosphere, the method includes separating and collecting a Lewisite sample from the atmosphere in a collection chamber, converting the collected Lewisite to an arsenite ion solution sample, pumping the arsenite ion containing sample to an electrochemical detector connected to the collection chamber, and electrochemically detecting the converted arsenite ions in the sample, whereby the concentration of arsenite ions detected is proportional to the concentration of Lewisite in the atmosphere.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 1997},
month = {Wed Jan 01 00:00:00 EST 1997}
}
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