Photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts
Abstract
This disclosure relates to photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. In certain embodiments, the disclosure relates to compositions comprising water, a complex of a tetra-metal oxide cluster and VW.sub.9O.sub.34 ligands, and a photosensitizer. Typically, the metal oxide cluster is Co. In certain embodiments, the disclosure relates to electrodes and other devices comprising water oxidation catalysts disclosed herein and uses in generating fuels and electrical power from solar energy.
- Inventors:
- Issue Date:
- Research Org.:
- Emory Univ., Atlanta, GA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1376223
- Patent Number(s):
- 9737880
- Application Number:
- 14/387,745
- Assignee:
- Emory University
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- DOE Contract Number:
- FG02-03ER15461
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Mar 28
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; 14 SOLAR ENERGY
Citation Formats
Hill, Craig L., Gueletii, Iourii V., Song, Jie, Lv, Hongjin, Musaev, Djamaladdin, and Luo, Zhen. Photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. United States: N. p., 2017.
Web.
Hill, Craig L., Gueletii, Iourii V., Song, Jie, Lv, Hongjin, Musaev, Djamaladdin, & Luo, Zhen. Photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. United States.
Hill, Craig L., Gueletii, Iourii V., Song, Jie, Lv, Hongjin, Musaev, Djamaladdin, and Luo, Zhen. Tue .
"Photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts". United States. https://www.osti.gov/servlets/purl/1376223.
@article{osti_1376223,
title = {Photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts},
author = {Hill, Craig L. and Gueletii, Iourii V. and Song, Jie and Lv, Hongjin and Musaev, Djamaladdin and Luo, Zhen},
abstractNote = {This disclosure relates to photocatalytic polyoxometalate compositions of tungstovanadates and uses as water oxidation catalysts. In certain embodiments, the disclosure relates to compositions comprising water, a complex of a tetra-metal oxide cluster and VW.sub.9O.sub.34 ligands, and a photosensitizer. Typically, the metal oxide cluster is Co. In certain embodiments, the disclosure relates to electrodes and other devices comprising water oxidation catalysts disclosed herein and uses in generating fuels and electrical power from solar energy.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 22 00:00:00 EDT 2017},
month = {Tue Aug 22 00:00:00 EDT 2017}
}
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