Electrochemical process for the preparation of nitrogen fertilizers
Abstract
Methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia are disclosed. Embodiments include (1) ammonium nitrate produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source: (3) ammonia produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source.
- Inventors:
- Issue Date:
- Research Org.:
- Energy & Environmental Research Center Foundation, Grand Forks, ND (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1178014
- Patent Number(s):
- 9005422
- Application Number:
- 12/905,600
- Assignee:
- Energy & Environmental Research Center Foundation (Grand Forks, ND)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
C - CHEMISTRY C05 - FERTILISERS C05C - NITROGENOUS FERTILISERS
- DOE Contract Number:
- FC36-03GO13055
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2010 Oct 15
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES
Citation Formats
Jiang, Junhua, Aulich, Ted R, and Ignatchenko, Alexey V. Electrochemical process for the preparation of nitrogen fertilizers. United States: N. p., 2015.
Web.
Jiang, Junhua, Aulich, Ted R, & Ignatchenko, Alexey V. Electrochemical process for the preparation of nitrogen fertilizers. United States.
Jiang, Junhua, Aulich, Ted R, and Ignatchenko, Alexey V. Tue .
"Electrochemical process for the preparation of nitrogen fertilizers". United States. https://www.osti.gov/servlets/purl/1178014.
@article{osti_1178014,
title = {Electrochemical process for the preparation of nitrogen fertilizers},
author = {Jiang, Junhua and Aulich, Ted R and Ignatchenko, Alexey V},
abstractNote = {Methods and apparatus for the preparation of nitrogen fertilizers including ammonium nitrate, urea, urea-ammonium nitrate, and/or ammonia are disclosed. Embodiments include (1) ammonium nitrate produced via the reduction of a nitrogen source at the cathode and the oxidation of a nitrogen source at the anode; (2) urea or its isomers produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source: (3) ammonia produced via the reduction of nitrogen source at the cathode and the oxidation of a hydrogen source or a hydrogen equivalent such as carbon monoxide or a mixture of carbon monoxide and hydrogen at the anode; and (4) urea-ammonium nitrate produced via the simultaneous cathodic reduction of a carbon source and a nitrogen source, and anodic oxidation of a nitrogen source.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 14 00:00:00 EDT 2015},
month = {Tue Apr 14 00:00:00 EDT 2015}
}
Works referenced in this record:
Process for the synthesis of ammonia using catalysts supported on graphite containing carbon
patent, August 1979
- Foster, Alan I.; James, Peter G.; McCarroll, John J.
- US Patent Document 4,163,775
Electrolytic oxidation/apparatus
patent, June 1988
- Bachot, Jean; Dumousseau, Jean-Yves
- US Patent Document 4,749,462
Direct electrochemical reduction of nitric acid to hydroxylamine nitrate
patent, July 1989
- Dotson, Ronald L.; Hernandez, Debra Y.
- US Patent Document 4,849,073
Electrolytic cell for producing a mixed oxidant gas
patent, April 1998
- Allen, Jeffrey D.
- US Patent Document 5,736,016
Method and apparatus for recovering condensables in vapor from a urea vacuum evaporator
patent, April 1998
- Singh, Vishnu D.; Strait, Richard; Czuppon, Thomas
- US Patent Document 5,744,009
Large-scale production of anhydrous nitric acid and nitric acid solutions of dinitrogen pentoxide
patent, March 2001
- Harrar, Jackson E.; Quong, Roland; Rigdon, Lester P.
- US Patent Document 6,200,456
Electrochemical synthesis of ammonia
patent, January 2008
- Murphy, Oliver J.; Denvir, Adrian J.; Teodorescu, Sorin Gabriel
- US Patent Document 7,314,544
Organic compound hydrogenation apparatus and method for hydrogenating organic compound
patent, December 2010
- Koyama, Saburo; Takagi, Fumiaki; Fuchigami, Toshio
- US Patent Document 7,846,319
Electrochemical process for the preparation of nitrogen fertilizers
patent, April 2012
- Aulich, Ted R.; Olson, Edwin S.; Jiang, Junhua
- US Patent Document 8,152,988
Process for the selective electrochemical oxidation of organic compounds
patent-application, March 2002
- Van Berkel, F. P. F.; Duda, Mark; Kuhnle, Adolf
- US Patent Application 09/866638; 20020031694
Hydrogen production from coal, water and electrons
journal, May 1979
- Coughlin, Robert W.; Farooque, M.
- Nature, Vol. 279, Issue 5711
Electrochemical Synthesis of Urea at Gas-Diffusion Electrodes
journal, January 1998
- Shibata, Masami
- Journal of The Electrochemical Society, Vol. 145, Issue 2
Electrochemical membrane reactor for the reduction of carbondioxide to formate
journal, November 2006
- Subramanian, K.; Asokan, K.; Jeevarathinam, D.
- Journal of Applied Electrochemistry, Vol. 37, Issue 2, p. 255-260