Catalysts for the production of hydrocarbons from carbon monoxide and water
Abstract
A method of converting low H2/CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200° to 350°C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: and for olefinic hydrocarbons: where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.
- Inventors:
- Issue Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1176566
- Patent Number(s):
- H000243
- Application Number:
- 06/797509
- Assignee:
- The United States of America as represented by the United States Department of Energy (Washington, DC)
- DOE Contract Number:
- AC02-76CH00016
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1985 Nov 06
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; statutory invention registration
Citation Formats
Sapienza, Richard S., Slegeir, William A., and Goldberg, Robert I. Catalysts for the production of hydrocarbons from carbon monoxide and water. United States: N. p., 1987.
Web.
Sapienza, Richard S., Slegeir, William A., & Goldberg, Robert I. Catalysts for the production of hydrocarbons from carbon monoxide and water. United States.
Sapienza, Richard S., Slegeir, William A., and Goldberg, Robert I. Tue .
"Catalysts for the production of hydrocarbons from carbon monoxide and water". United States. https://www.osti.gov/servlets/purl/1176566.
@article{osti_1176566,
title = {Catalysts for the production of hydrocarbons from carbon monoxide and water},
author = {Sapienza, Richard S. and Slegeir, William A. and Goldberg, Robert I.},
abstractNote = {A method of converting low H2/CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200° to 350°C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: and for olefinic hydrocarbons: where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 07 00:00:00 EDT 1987},
month = {Tue Apr 07 00:00:00 EDT 1987}
}
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