Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom
Abstract
Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (>15% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there ismore »
- Inventors:
-
- Sante Fe, NM
- Los Alamos, NM
- Issue Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- OSTI Identifier:
- 873137
- Patent Number(s):
- 6099907
- Assignee:
- Regents of University of California (Los Alamos, NM)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
D - TEXTILES D01 - NATURAL OR MAN-MADE THREADS OR FIBRES D01F - CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- DOE Contract Number:
- W-7405-ENG-36
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- stable; concentrated; solutions; molecular; weight; polyaniline; articles; therefrom; process; quality; fibers; possessing; mechanical; properties; solution; concentrations; chosen; polymer; range; 15-30; moreover; desirable; consistent; solubility; inherently; unstable; forming; gels; processing; achieved; describes; addition; inhibitors; gis; permitting; 15; 120; 000; 30; emeraldine; base; dissolved; secondary; amines; purpose; compared; otherwise; cosolvent; role; resulting; useful; generating; excellent; films; coatings; significant; time; periods; deterioration; demonstrated; found; cosolvents; gelation; times; directly; proportional; concentration; particular; preferred; exceeded; causes; structural; electrical; conductivity; degradation; heating; significantly; improves; weight polyaniline; articles therefrom; concentrated solution; concentrated solutions; resulting solution; significantly improves; solution concentrations; molecular weight; time period; mechanical properties; electrical conductivity; directly proportional; polymer solution; time periods; quality fibers; resulting solutions; significant time; resulting articles; resulting article; secondary amines; solubility properties; solutions significantly; weight poly; weight consistent; articles possessing; polymer deterioration; preferred concentration; causes structural; chosen polymer; gelation times; emeraldine base; exceeded causes; excellent fibers; generating excellent; gis found; cosolvent role; conductivity degradation; improves solubility; inherently unstable; forming gels; significantly improve; secondary amine; solution concentration; /427/528/
Citation Formats
Mattes, Benjamin R, and Wang, Hsing-Lin. Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom. United States: N. p., 2000.
Web.
Mattes, Benjamin R, & Wang, Hsing-Lin. Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom. United States.
Mattes, Benjamin R, and Wang, Hsing-Lin. Sat .
"Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom". United States. https://www.osti.gov/servlets/purl/873137.
@article{osti_873137,
title = {Stable, concentrated solutions of high molecular weight polyaniline and articles therefrom},
author = {Mattes, Benjamin R and Wang, Hsing-Lin},
abstractNote = {Stable, concentrated solutions of high molecular weight polyaniline. In order to process high quality fibers and other articles possessing good mechanical properties, it is known that solution concentrations of the chosen polymer should be in the range from 15-30% (w/w). Moreover, it is desirable to use the highest molecular weight consistent with the solubility properties of the polymer. However, such solutions are inherently unstable, forming gels before processing can be achieved. The present invention describes the addition gel inhibitors (GIs) to the polymer solution, thereby permitting high concentrations (>15% (w/w)) of high molecular weight ((M.sub.w)>120,000, and (M.sub.n)>30,000) emeraldine base (EB) polyaniline to be dissolved. Secondary amines have been used for this purpose in concentrations which are small compared to those which might otherwise be used in a cosolvent role therefor. The resulting solutions are useful for generating excellent fibers, films, coatings and other objects, since the solutions are stable for significant time periods, and the GIs are present in too small concentrations to cause polymer deterioration. It is demonstrated that the GIs found to be useful do not act as cosolvents, and that gelation times of the solutions are directly proportional to the concentration of GI. In particular, there is a preferred concentration of GI, which if exceeded causes structural and electrical conductivity degradation of resulting articles. Heating of the solutions significantly improves solubility.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 2000},
month = {Sat Jan 01 00:00:00 EST 2000}
}
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