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Title: Electrolytic production of neodymium without perfluorinated carbon compounds on the offgases

Abstract

A method of producing neodymium in an electrolytic cell without formation of perfluorinated carbon gases (PFCs), the method comprising the steps of providing an electrolyte in the electrolytic cell and providing an anode in an anode region of the electrolyte and providing a cathode in a cathode region of the electrolytic cell. Dissolving an oxygen-containing neodymium compound in the electrolyte in the anode region and maintaining a more intense electrolyte circulation in the anode region than in the cathode region. Passing an electrolytic current between said anode and said cathode and depositing neodymium metal at the cathode, preventing the formation of perfluorinated carbon gases by limiting anode over voltage.

Inventors:
 [1];  [2]
  1. Export, PA
  2. Pittsburgh, PA
Issue Date:
Research Org.:
EMEC Consultants, Export, PA (United States)
OSTI Identifier:
871851
Patent Number(s):
5810993
Assignee:
EMEC Consultants (Export, PA)
Patent Classifications (CPCs):
C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25C - PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS
DOE Contract Number:  
FC07-91ID13104
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
electrolytic; production; neodymium; perfluorinated; carbon; compounds; offgases; method; producing; cell; formation; gases; pfcs; comprising; steps; providing; electrolyte; anode; region; cathode; dissolving; oxygen-containing; compound; maintaining; intense; circulation; passing; current; depositing; metal; preventing; limiting; voltage; method comprising; electrolytic production; electrolytic cell; carbon compound; anode region; perfluorinated carbon; electrolyte circulation; carbon compounds; carbon gases; /205/

Citation Formats

Keller, Rudolf, and Larimer, Kirk T. Electrolytic production of neodymium without perfluorinated carbon compounds on the offgases. United States: N. p., 1998. Web.
Keller, Rudolf, & Larimer, Kirk T. Electrolytic production of neodymium without perfluorinated carbon compounds on the offgases. United States.
Keller, Rudolf, and Larimer, Kirk T. Thu . "Electrolytic production of neodymium without perfluorinated carbon compounds on the offgases". United States. https://www.osti.gov/servlets/purl/871851.
@article{osti_871851,
title = {Electrolytic production of neodymium without perfluorinated carbon compounds on the offgases},
author = {Keller, Rudolf and Larimer, Kirk T},
abstractNote = {A method of producing neodymium in an electrolytic cell without formation of perfluorinated carbon gases (PFCs), the method comprising the steps of providing an electrolyte in the electrolytic cell and providing an anode in an anode region of the electrolyte and providing a cathode in a cathode region of the electrolytic cell. Dissolving an oxygen-containing neodymium compound in the electrolyte in the anode region and maintaining a more intense electrolyte circulation in the anode region than in the cathode region. Passing an electrolytic current between said anode and said cathode and depositing neodymium metal at the cathode, preventing the formation of perfluorinated carbon gases by limiting anode over voltage.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 1998},
month = {Thu Jan 01 00:00:00 EST 1998}
}

Works referenced in this record:

Electrochemistry of rare earth fluoride molten salts
journal, March 1993


Preparation of cobalt-rare-earth alloys by electrolysis
journal, January 1969