Porphyrins and their synthesis from dipyrromethanes and aldehydes
Abstract
The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided.
- Inventors:
- Issue Date:
- Research Org.:
- Sun Refining and Marketing Company
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 672552
- Patent Number(s):
- 5760217
- Application Number:
- PAN: 8-672,524
- Assignee:
- Sun Co., Inc., Marcus Hook, PA (United States)
- DOE Contract Number:
- FC21-90MC26029
- Resource Type:
- Patent
- Resource Relation:
- Other Information: PBD: 2 Jun 1998
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 40 CHEMISTRY; PORPHYRINS; CHEMICAL PREPARATION; IRON COMPLEXES; MANGANESE COMPLEXES; COBALT COMPLEXES; RUTHENIUM COMPLEXES; ORGANIC HALOGEN COMPOUNDS
Citation Formats
Wijesekera, T, Lyons, J E, and Ellis, Jr, P E. Porphyrins and their synthesis from dipyrromethanes and aldehydes. United States: N. p., 1998.
Web.
Wijesekera, T, Lyons, J E, & Ellis, Jr, P E. Porphyrins and their synthesis from dipyrromethanes and aldehydes. United States.
Wijesekera, T, Lyons, J E, and Ellis, Jr, P E. Tue .
"Porphyrins and their synthesis from dipyrromethanes and aldehydes". United States.
@article{osti_672552,
title = {Porphyrins and their synthesis from dipyrromethanes and aldehydes},
author = {Wijesekera, T and Lyons, J E and Ellis, Jr, P E},
abstractNote = {The invention comprises new compositions of matter, which are iron, manganese, cobalt or ruthenium complexes of porphyrins having hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. The invention also comprises new compositions of matter in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also provided.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1998},
month = {6}
}
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