Method for hydroperoxide decomposition using novel porphyrins synthesized from dipyrromethanes and aldehydes
- Glen Mills, PA
- Wallingford, PA
The invention comprises a method for the oxidation of alkanes to alcohols and for decomposition of hydroperoxides to alcohols utilizing new compositions of matter, which are metal complexes of porphyrins. Preferred complexes have hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. Other preferred complexes are ones in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also disclosed.
- Research Organization:
- Sun Refining and Marketing Co., Marcus Hook, PA (United States)
- DOE Contract Number:
- FC21-90MC26029
- Assignee:
- Sun Company, Inc. (R&M) (Philadelphia, PA)
- Patent Number(s):
- US 5723677
- OSTI ID:
- 871397
- Country of Publication:
- United States
- Language:
- English
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Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes
Method for oxidizing alkanes using novel porphyrins synthesized from dipyrromethanes and aldehydes
Related Subjects
hydroperoxide
decomposition
novel
porphyrins
synthesized
dipyrromethanes
aldehydes
comprises
oxidation
alkanes
alcohols
hydroperoxides
utilizing
compositions
matter
metal
complexes
preferred
hydrogen
haloalkyl
haloaryl
meso
positions
opposed
atoms
ones
substituted
beta
halogen
synthesizing
porphyrinogens
disclosed
beta positions
halogen atoms
meso atoms
metal complexes
opposed meso
meso positions
metal complex
meso position
synthesizing porphyrinogens
novel porphyrins
porphyrins synthesized
alcohols utilizing
beta position
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