Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones
Abstract
Provided are methods of producing carbonyl compounds (e.g., carbonyl containing compounds) and catalysts for producing carbonyl compounds. Also provided are methods of making polymers from carbonyl compounds and polymers formed from carbonyl compounds. A method may produce carbonyl compounds, such as, for example α,α-disubstituted carbonyl compounds (e.g., α,α-disubstituted β-lactones). The polymers may be produced from α,α-disubstituted β-lactones, which may be produced by a method described herein.
- Inventors:
- Issue Date:
- Research Org.:
- Cornell Univ., Ithaca, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2294029
- Patent Number(s):
- 11851416
- Application Number:
- 16/936,322
- Assignee:
- Cornell University (Ithaca, NY)
- DOE Contract Number:
- FG02-05ER15687
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 07/22/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Coates, Geoffrey W., Lamb, Jessica Rachel, Klimovica, Kristine, and Hubbell, Aran Kathleen. Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones. United States: N. p., 2023.
Web.
Coates, Geoffrey W., Lamb, Jessica Rachel, Klimovica, Kristine, & Hubbell, Aran Kathleen. Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones. United States.
Coates, Geoffrey W., Lamb, Jessica Rachel, Klimovica, Kristine, and Hubbell, Aran Kathleen. Tue .
"Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones". United States. https://www.osti.gov/servlets/purl/2294029.
@article{osti_2294029,
title = {Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones},
author = {Coates, Geoffrey W. and Lamb, Jessica Rachel and Klimovica, Kristine and Hubbell, Aran Kathleen},
abstractNote = {Provided are methods of producing carbonyl compounds (e.g., carbonyl containing compounds) and catalysts for producing carbonyl compounds. Also provided are methods of making polymers from carbonyl compounds and polymers formed from carbonyl compounds. A method may produce carbonyl compounds, such as, for example α,α-disubstituted carbonyl compounds (e.g., α,α-disubstituted β-lactones). The polymers may be produced from α,α-disubstituted β-lactones, which may be produced by a method described herein.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 26 00:00:00 EST 2023},
month = {Tue Dec 26 00:00:00 EST 2023}
}
Works referenced in this record:
Synthesis of β-Lactones: A Highly Active and Selective Catalyst for Epoxide Carbonylation
journal, February 2002
- Getzler, Yutan D. Y. L.; Mahadevan, Viswanath; Lobkovsky, Emil B.
- Journal of the American Chemical Society, Vol. 124, Issue 7, p. 1174-1175
Synthesis of β-Lactones by the Regioselective, Cobalt and Lewis Acid Catalyzed Carbonylation of Simple and Functionalized Epoxides
journal, August 2001
- Lee, Jong Tae; Thomas, P. J.; Alper, Howard
- The Journal of Organic Chemistry, Vol. 66, Issue 16
Catalytic carbonylation of three and four membered heterocycles
patent-application, August 2003
- Coates, Geoffrey W.; Getzler, Yutan D. Y. L.; Wolczanski, Peter
- US Patent Application 10/307520; 20030162961