High optical transparency polymer aerogels using low refractive index monomers
Abstract
A method of producing a polymer aerogel includes dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, wherein at least one of the monomers or at least one of the crosslinkers has a refractive index of 1.5 or lower, polymerizing the precursor solution to form a gel polymer, and removing the solvent from the gel polymer to produce the polymer aerogel. A method of producing a polymer aerogel include dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, polymerizing the precursor solution to form a gel polymer, removing the solvent from the gel polymer to produce the polymer aerogel, and reducing a refractive index of one of either the gel polymer or the polymer aerogel.
- Inventors:
- Issue Date:
- Research Org.:
- Xerox Corporation, Norwalk, CT (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 2294001
- Patent Number(s):
- 11851543
- Application Number:
- 17/245,418
- Assignee:
- Xerox Corporation (Norwalk, CT)
- DOE Contract Number:
- AR0000074
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 04/30/2021
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Bulger, Eli, Chintapalli, Mahati, Iftime, Gabriel, Van Overmeere, Quentin, Rivest, Jessica Louis Baker, Neelakantan, Ravi, and Meckler, Stephen. High optical transparency polymer aerogels using low refractive index monomers. United States: N. p., 2023.
Web.
Bulger, Eli, Chintapalli, Mahati, Iftime, Gabriel, Van Overmeere, Quentin, Rivest, Jessica Louis Baker, Neelakantan, Ravi, & Meckler, Stephen. High optical transparency polymer aerogels using low refractive index monomers. United States.
Bulger, Eli, Chintapalli, Mahati, Iftime, Gabriel, Van Overmeere, Quentin, Rivest, Jessica Louis Baker, Neelakantan, Ravi, and Meckler, Stephen. Tue .
"High optical transparency polymer aerogels using low refractive index monomers". United States. https://www.osti.gov/servlets/purl/2294001.
@article{osti_2294001,
title = {High optical transparency polymer aerogels using low refractive index monomers},
author = {Bulger, Eli and Chintapalli, Mahati and Iftime, Gabriel and Van Overmeere, Quentin and Rivest, Jessica Louis Baker and Neelakantan, Ravi and Meckler, Stephen},
abstractNote = {A method of producing a polymer aerogel includes dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, wherein at least one of the monomers or at least one of the crosslinkers has a refractive index of 1.5 or lower, polymerizing the precursor solution to form a gel polymer, and removing the solvent from the gel polymer to produce the polymer aerogel. A method of producing a polymer aerogel include dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, polymerizing the precursor solution to form a gel polymer, removing the solvent from the gel polymer to produce the polymer aerogel, and reducing a refractive index of one of either the gel polymer or the polymer aerogel.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 26 00:00:00 EST 2023},
month = {Tue Dec 26 00:00:00 EST 2023}
}
Works referenced in this record:
Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)
journal, November 2009
- Jenkins, Aubrey D.; Jones, Richard G.; Moad, Graeme
- Pure and Applied Chemistry, Vol. 82, Issue 2
Highly porous and mechanically strong ceramic oxide aerogels
patent, June 2010
- Leventis, Nicholas; Meador, Mary Ann B.; Johnston, James C.
- US Patent Document 7,732,496
Telechelic Hybrid Aerogels
patent-application, September 2011
- Wu, Jung-Sheng; Seth, Jayshree; Determan, Michael D.
- US Patent Application 13/133419; 20110237692
Cellulose-enabled orientationally ordered flexible gels
patent-application, August 2018
- Hess, Andrew J.; Liu, Qingkun; Smalyukh, Ivan I.
- US Patent Application 15/868714; 20180237608
Polymer Composition
patent-application, April 2004
- Chisholm, Michael S.; Slark, Andrew T.; Sherrington, David
- US Patent Application 10/662418; 20040063880
Polymer Nanofibers with Outstanding Thermal Conductivity and Thermal Stability: Fundamental Linkage between Molecular Characteristics and Macroscopic Thermal Properties
journal, August 2014
- Zhang, Teng; Wu, Xufei; Luo, Tengfei
- The Journal of Physical Chemistry C, Vol. 118, Issue 36
Polymer Aerogel for Window Glazings
patent-application, April 2018
- Van Overmeere, Quentin L.; Iftime, Gabriel; Afshinmanesh, Farzaneh
- US Patent Application 15/285660; 20180093456
Glazing Unit with Transparent Filler
patent-application, July 2010
- Milburn, Douglas I.
- US Patent Application 12/717521; 20100163157
Aerogels, calcined and crystalline articles and methods of making the same
patent-application, July 2015
- Kolb, Brant U.; Feisel, Bryan C.; Goetzinger, Martin
- US Patent Application 14/347382; 20150203650
Process for the preparation of monolithic silica aerogels
patent, August 1998
- Pajonk, Gerard; Elaloui, Elimame; Begag, Redouane
- US Patent Document 5,795,557
Method to produce transparent polymer aerogels using chain transfer agents
patent-application, April 2019
- Chintapalli, Mahati; Keoshkerian, Barkev; Iftime, Gabriel
- US Patent Application 15/728385; 20190106543
The Influence of RAFT on the Microstructure and the Mechanical Properties of Photopolymerized Poly(butyl acrylate) Networks
journal, December 2013
- Henkel, Rouven; Vana, Philipp
- Macromolecular Chemistry and Physics, Vol. 215, Issue 2
Polymer Composition
patent-application, January 2003
- Chisholm, Michael Stephen; Slark, Andrew Trevithick; Sherrington, David
- US Patent Application 09/601110; 20030013822
Hildebrand and Hansen solubility parameters from Molecular Dynamics with applications to electronic nose polymer sensors
journal, January 2004
- Belmares, M.; Blanco, M.; Goddard, W. A.
- Journal of Computational Chemistry, Vol. 25, Issue 15
Determining the complex refractive index of cellulose nanocrystals by combination of Beer-Lambert and immersion matching methods
journal, September 2019
- Niskanen, Ilpo; Suopajärvi, Terhi; Liimatainen, Henrikki
- Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 235
Durable polymer-aerogel based superhydrophobic coatings, a composite material
patent, March 2014
- Kissel, David J.; Brinker, Charles Jeffrey
- US Patent Document 8,663,742
Aerogel-foam Composites
patent-application, December 2011
- Cho, Myung-Dong; Park, Sang-Ho; Kim, Kwang-Hee
- US Patent Application 13/165578; 20110311802
Aerogel Window Film System
patent-application, March 2014
- Showers, Robert James
- US Patent Application 14/073333; 20140065329
Telechelic Hybrid Aerogels
patent-application, March 2014
- Wu, Jung-Sheng; Seth, Jayshree; Determan, Michael D.
- US Patent Application 14/086077; 20140080934
Process for producing styrenic polymer
patent, March 1998
- Fujita, Masayuki; Kihara, Hayato; Ishii, Takahiro
- US Patent Document 5,723,554
Polymer composition
patent, March 2004
- Chisholm, Michael Stephen; Slark, Andrew
- US Patent Document 6,713,584
High optical transparency polymer aerogels using low refractive index monomers
patent, May 2021
- Bulger, Eli; Chintapalli, Mahati; Iftime, Gabriel
- US Patent Document 10,995,191
50th Anniversary Perspective : RAFT Polymerization—A User Guide
journal, September 2017
- Perrier, Sébastien
- Macromolecules, Vol. 50, Issue 19