DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: High optical transparency polymer aerogels using low refractive index monomers

Abstract

A method of producing a polymer aerogel includes dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, wherein at least one of the monomers or at least one of the crosslinkers has a refractive index of 1.5 or lower, polymerizing the precursor solution to form a gel polymer, and removing the solvent from the gel polymer to produce the polymer aerogel. A method of producing a polymer aerogel include dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, polymerizing the precursor solution to form a gel polymer, removing the solvent from the gel polymer to produce the polymer aerogel, and reducing a refractive index of one of either the gel polymer or the polymer aerogel.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
Xerox Corporation, Norwalk, CT (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
2294001
Patent Number(s):
11851543
Application Number:
17/245,418
Assignee:
Xerox Corporation (Norwalk, CT)
DOE Contract Number:  
AR0000074
Resource Type:
Patent
Resource Relation:
Patent File Date: 04/30/2021
Country of Publication:
United States
Language:
English

Citation Formats

Bulger, Eli, Chintapalli, Mahati, Iftime, Gabriel, Van Overmeere, Quentin, Rivest, Jessica Louis Baker, Neelakantan, Ravi, and Meckler, Stephen. High optical transparency polymer aerogels using low refractive index monomers. United States: N. p., 2023. Web.
Bulger, Eli, Chintapalli, Mahati, Iftime, Gabriel, Van Overmeere, Quentin, Rivest, Jessica Louis Baker, Neelakantan, Ravi, & Meckler, Stephen. High optical transparency polymer aerogels using low refractive index monomers. United States.
Bulger, Eli, Chintapalli, Mahati, Iftime, Gabriel, Van Overmeere, Quentin, Rivest, Jessica Louis Baker, Neelakantan, Ravi, and Meckler, Stephen. Tue . "High optical transparency polymer aerogels using low refractive index monomers". United States. https://www.osti.gov/servlets/purl/2294001.
@article{osti_2294001,
title = {High optical transparency polymer aerogels using low refractive index monomers},
author = {Bulger, Eli and Chintapalli, Mahati and Iftime, Gabriel and Van Overmeere, Quentin and Rivest, Jessica Louis Baker and Neelakantan, Ravi and Meckler, Stephen},
abstractNote = {A method of producing a polymer aerogel includes dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, wherein at least one of the monomers or at least one of the crosslinkers has a refractive index of 1.5 or lower, polymerizing the precursor solution to form a gel polymer, and removing the solvent from the gel polymer to produce the polymer aerogel. A method of producing a polymer aerogel include dissolving precursors into a solvent, wherein the precursors include monomers, crosslinkers, a controlling agent and an initiator to form a precursor solution, polymerizing the precursor solution to form a gel polymer, removing the solvent from the gel polymer to produce the polymer aerogel, and reducing a refractive index of one of either the gel polymer or the polymer aerogel.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 26 00:00:00 EST 2023},
month = {Tue Dec 26 00:00:00 EST 2023}
}

Works referenced in this record:

Highly porous and mechanically strong ceramic oxide aerogels
patent, June 2010


Telechelic Hybrid Aerogels
patent-application, September 2011


Cellulose-enabled orientationally ordered flexible gels
patent-application, August 2018


Polymer Composition
patent-application, April 2004


Polymer Aerogel for Window Glazings
patent-application, April 2018


Glazing Unit with Transparent Filler
patent-application, July 2010


Aerogels, calcined and crystalline articles and methods of making the same
patent-application, July 2015


Process for the preparation of monolithic silica aerogels
patent, August 1998


Method to produce transparent polymer aerogels using chain transfer agents
patent-application, April 2019


The Influence of RAFT on the Microstructure and the Mechanical Properties of Photopolymerized Poly(butyl acrylate) Networks
journal, December 2013


Polymer Composition
patent-application, January 2003


Hildebrand and Hansen solubility parameters from Molecular Dynamics with applications to electronic nose polymer sensors
journal, January 2004


Determining the complex refractive index of cellulose nanocrystals by combination of Beer-Lambert and immersion matching methods
journal, September 2019


Durable polymer-aerogel based superhydrophobic coatings, a composite material
patent, March 2014


Aerogel-foam Composites
patent-application, December 2011


Aerogel Window Film System
patent-application, March 2014


Telechelic Hybrid Aerogels
patent-application, March 2014


Process for producing styrenic polymer
patent, March 1998


Polymer composition
patent, March 2004


High optical transparency polymer aerogels using low refractive index monomers
patent, May 2021


50th Anniversary Perspective : RAFT Polymerization—A User Guide
journal, September 2017