Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same

Ren, Zhifeng; Yu, Fang; Zhou, Haiqing; Chen, Shuo

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Title: Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same

Abstract

A method of electrocatalytic water splitting by providing an anode and a cathode; and utilizing the anode and the cathode for alkaline water electrolysis. Each of the anode and the cathode comprises a uniform distribution of a bifunctional electrocatalyst comprising metallic phosphides on a conductive substrate. The metallic phosphides comprise arion phosphide (FeP) and dinickel phosphide (Ni₂P). The bifunctional electrocatalyst promotes hydrogen evolution reaction (HER) at the cathode, and oxygen evolution reaction (OER) at the anode.

Inventors:: Ren, Zhifeng; Yu, Fang; Zhou, Haiqing; Chen, Shuo

Issue Date:: Tue Aug 15 00:00:00 EDT 2023

Research Org.:: Univ. of Houston, TX (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 2222107

Patent Number(s):: 11725292

Application Number:: 17/828,172

Assignee:: University of Houston System (Houston, TX)

DOE Contract Number:: SC0010831

Resource Type:: Patent

Resource Relation:: Patent File Date: 05/31/2022

Country of Publication:: United States

Language:: English

Citation Formats


                    Ren, Zhifeng, Yu, Fang, Zhou, Haiqing, and Chen, Shuo. Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same.  United States: N. p., 2023. 
        Web.

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                    Ren, Zhifeng, Yu, Fang, Zhou, Haiqing, & Chen, Shuo. Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same.  United States.

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                    Ren, Zhifeng, Yu, Fang, Zhou, Haiqing, and Chen, Shuo. Tue .  
        "Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same".  United States.  https://www.osti.gov/servlets/purl/2222107.

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@article{osti_2222107,

  title        = {Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same},

  author       = {Ren, Zhifeng and Yu, Fang and Zhou, Haiqing and Chen, Shuo},

  abstractNote = {A method of electrocatalytic water splitting by providing an anode and a cathode; and utilizing the anode and the cathode for alkaline water electrolysis. Each of the anode and the cathode comprises a uniform distribution of a bifunctional electrocatalyst comprising metallic phosphides on a conductive substrate. The metallic phosphides comprise arion phosphide (FeP) and dinickel phosphide (Ni2P). The bifunctional electrocatalyst promotes hydrogen evolution reaction (HER) at the cathode, and oxygen evolution reaction (OER) at the anode.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Aug 15 00:00:00 EDT 2023},

  month        = {Tue Aug 15 00:00:00 EDT 2023}

}

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Title: Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same

Abstract

Citation Formats

Synthesis of metal metaphosphate for catalysts for oxygen evolution reactions patent, March 2022

Electro-Catalyst patent-application, August 2013

Iron-Doped Nickel Phosphide Nanosheet Arrays: An Efficient Bifunctional Electrocatalyst for Water Splitting journal, July 2017

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Composite, hierarchical electrocatalytic materials for water splitting patent-application, December 2021

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Bifunctional Water Splitting Catalysts and Associated Methods patent-application, October 2016

Metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions patent-application, April 2018

Scalable Two-Step Synthesis of Nickel–Iron Phosphide Electrodes for Stable and Efficient Electrocatalytic Hydrogen Evolution journal, December 2016

Method of synthesizing high-efficiency bifunctional electrocatalysts patent-application, November 2021

Ni3Se2 nanoforest/Ni foam as a hydrophilic, metallic, and self-supported bifunctional electrocatalyst for both H2 and O2 generations journal, June 2016

Method for preparing hierarchically porous doped carbon material and its use patent-application, July 2018

Single-atomic cobalt sites embedded in hierarchically ordered porous nitrogen-doped carbon as a superior bifunctional electrocatalyst journal, November 2018

An efficient bifunctional electrocatalyst for water splitting based on cobalt phosphide journal, May 2016

Oxygen electrode and a method of manufacturing the same patent-application, July 2017

Method for preparing transition metal phosphide patent-application, January 2017

Earth-Rich Transition Metal Phosphide for Energy Conversion and Storage journal, May 2016

High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting journal, June 2018

Selective phosphidation: an effective strategy toward CoP/CeO2 interface engineering for superior alkaline hydrogen evolution electrocatalysis journal, January 2018

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In-situ growth of iron/nickel phosphides hybrid on nickel foam as bifunctional electrocatalyst for overall water splitting journal, June 2019

A nanoporous metal phosphide catalyst for bifunctional water splitting journal, January 2018

Methods of phosphidation and structures made therefrom patent-application, March 2018

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