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Title: Metal phosphide catalysts and methods for making the same and uses thereof

Abstract

The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1568591
Patent Number(s):
10350583
Application Number:
15/458,397
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 03/14/2017
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Habas, Susan Ellen, Wang, Jun, Ruddy, Daniel A., Baddour, Frederick Raymond Gabriel, and Schaidle, Joshua. Metal phosphide catalysts and methods for making the same and uses thereof. United States: N. p., 2019. Web.
Habas, Susan Ellen, Wang, Jun, Ruddy, Daniel A., Baddour, Frederick Raymond Gabriel, & Schaidle, Joshua. Metal phosphide catalysts and methods for making the same and uses thereof. United States.
Habas, Susan Ellen, Wang, Jun, Ruddy, Daniel A., Baddour, Frederick Raymond Gabriel, and Schaidle, Joshua. Tue . "Metal phosphide catalysts and methods for making the same and uses thereof". United States. https://www.osti.gov/servlets/purl/1568591.
@article{osti_1568591,
title = {Metal phosphide catalysts and methods for making the same and uses thereof},
author = {Habas, Susan Ellen and Wang, Jun and Ruddy, Daniel A. and Baddour, Frederick Raymond Gabriel and Schaidle, Joshua},
abstractNote = {The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh3)2(CO)4, Pd(PPh3)4, Ru(PPh3)3Cl2, Ru(PPh3)2(CO)2Cl2, Co(PPh3)(CO)2(NO), and/or Rh(PPh3)2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru2P, Co2P, Rh2P, and/or Pd3P, and the metal phosphide nanoparticle is not hollow.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {7}
}

Works referenced in this record:

Method of synthesizing phosphide materials
patent, June 2013


III-V nanoparticles and method for their manufacture
patent, June 2014


Metal Phosphorus Compound For Preparing Biodiesel And Method For Preparing Biodiesel Using The Same
patent-application, June 2014


Processes for Synthesizing Nanocrystals and Nanocrystal Compositions
patent-application, June 2014