Surface-functionalized silicon anode for high energy lithium ion batteries
Abstract
A composition includes a silicon nanoparticle having surface-attached groups, and the silicon nanoparticle is represented by the formula: [Si]-[linker]-[terminal group]. In the formula [Si] represents the surface of the silicon nanoparticle; [terminal group] is a moiety that is configured for further reaction or is compatible with the electrolyte; and [linker] is a group linking the surface of the silicon nanoparticle to the [terminal group].
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2222016
- Patent Number(s):
- 11710826
- Application Number:
- 16/847,952
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 04/14/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Zhang, Zhengcheng, and Jiang, Sisi. Surface-functionalized silicon anode for high energy lithium ion batteries. United States: N. p., 2023.
Web.
Zhang, Zhengcheng, & Jiang, Sisi. Surface-functionalized silicon anode for high energy lithium ion batteries. United States.
Zhang, Zhengcheng, and Jiang, Sisi. Tue .
"Surface-functionalized silicon anode for high energy lithium ion batteries". United States. https://www.osti.gov/servlets/purl/2222016.
@article{osti_2222016,
title = {Surface-functionalized silicon anode for high energy lithium ion batteries},
author = {Zhang, Zhengcheng and Jiang, Sisi},
abstractNote = {A composition includes a silicon nanoparticle having surface-attached groups, and the silicon nanoparticle is represented by the formula: [Si]-[linker]-[terminal group]. In the formula [Si] represents the surface of the silicon nanoparticle; [terminal group] is a moiety that is configured for further reaction or is compatible with the electrolyte; and [linker] is a group linking the surface of the silicon nanoparticle to the [terminal group].},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 25 00:00:00 EDT 2023},
month = {Tue Jul 25 00:00:00 EDT 2023}
}
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Works referenced in this record:
Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode
journal, October 2006
- Choi, Nam-Soon; Yew, Kyoung Han; Lee, Kyu Youl
- Journal of Power Sources, Vol. 161, Issue 2, p. 1254-1259
A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes
journal, February 2016
- Higgins, Thomas M.; Park, Sang-Hoon; King, Paul J.
- ACS Nano, Vol. 10, Issue 3
Sodium Carboxymethyl Cellulose
journal, January 2007
- Li, Jing; Lewis, R. B.; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 10, Issue 2
Design of Red Phosphorus Nanostructured Electrode for Fast-Charging Lithium-Ion Batteries with High Energy Density
journal, April 2019
- Sun, Yongming; Wang, Li; Li, Yanbin
- Joule, Vol. 3, Issue 4
Advanced electrolyte/additive for lithium-ion batteries with silicon anode
journal, August 2016
- Zhang, Shuo; He, Meinan; Su, Chi-Cheung
- Current Opinion in Chemical Engineering, Vol. 13
Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications
journal, January 2018
- Feng, Kun; Li, Matthew; Liu, Wenwen
- Small, Vol. 14, Issue 8
The existence of optimal molecular weight for poly(acrylic acid) binders in silicon/graphite composite anode for lithium-ion batteries
journal, February 2018
- Hu, Bin; Shkrob, Ilya A.; Zhang, Shuo
- Journal of Power Sources, Vol. 378
General Method of Manipulating Formation, Composition, and Morphology of Solid-Electrolyte Interphases for Stable Li-Alloy Anodes
journal, November 2017
- Gao, Yue; Yi, Ran; Li, Yuguang C.
- Journal of the American Chemical Society, Vol. 139, Issue 48
Ionically Conductive Self-Healing Binder for Low Cost Si Microparticles Anodes in Li-Ion Batteries
journal, February 2018
- Munaoka, Takatoshi; Yan, Xuzhou; Lopez, Jeffrey
- Advanced Energy Materials, Vol. 8, Issue 14
Confronting Issues of the Practical Implementation of Si Anode in High-Energy Lithium-Ion Batteries
journal, September 2017
- Chae, Sujong; Ko, Minseong; Kim, Kyungho
- Joule, Vol. 1, Issue 1
Electrolytes for advanced lithium ion batteries using silicon-based anodes
journal, January 2019
- Xu, Zhixin; Yang, Jun; Li, Hongping
- Journal of Materials Chemistry A, Vol. 7, Issue 16
Electron/Ion Transport Enhancer in High Capacity Li-Ion Battery Anodes
journal, September 2016
- Kwon, Yo Han; Minnici, Krysten; Huie, Matthew M.
- Chemistry of Materials, Vol. 28, Issue 18
Nanostructured silicon for high capacity lithium battery anodes
journal, January 2011
- Szczech, Jeannine R.; Jin, Song
- Energy Environ. Sci., Vol. 4, Issue 1
The Effects of Native Oxide Surface Layer on the Electrochemical Performance of Si Nanoparticle-Based Electrodes
journal, January 2011
- Xun, S.; Song, X.; Wang, L.
- Journal of The Electrochemical Society, Vol. 158, Issue 12
Enhancement of the Cyclability of a Si/Graphite@Graphene composite as anode for Lithium-ion batteries
journal, January 2014
- Su, Mingru; Wang, Zhixing; Guo, Huajun
- Electrochimica Acta, Vol. 116
Nanostructured silicon sol-gel surface treatments for Al 2024-T3 protection
journal, April 2001
- Vreugdenhil, A. J.; Balbyshev, V. N.; Donley, M. S.
- Journal of Coatings Technology, Vol. 73, Issue 4
Surface Functionalization of Silicon Nanoparticles Produced by Laser-Driven Pyrolysis of Silane followed by HF−HNO 3 Etching
journal, May 2004
- Li, Xuegeng; He, Yuanqing; Swihart, Mark T.
- Langmuir, Vol. 20, Issue 11
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011
- Kovalenko, I.; Zdyrko, B.; Magasinski, A.
- Science, Vol. 334, Issue 6052
Enhancing Electrochemical Performance of Silicon Film Anode by Vinylene Carbonate Electrolyte Additive
journal, January 2006
- Chen, Libao; Wang, Ke; Xie, Xiaohua
- Electrochemical and Solid-State Letters, Vol. 9, Issue 11
Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012
- Wu, Hui; Cui, Yi
- Nano Today, Vol. 7, Issue 5
Review on recent progress of nanostructured anode materials for Li-ion batteries
journal, July 2014
- Goriparti, Subrahmanyam; Miele, Ermanno; De Angelis, Francesco
- Journal of Power Sources, Vol. 257
Tuning Confinement in Colloidal Silicon Nanocrystals with Saturated Surface Ligands
journal, April 2018
- Carroll, Gerard M.; Limpens, Rens; Neale, Nathan R.
- Nano Letters, Vol. 18, Issue 5
Silyl Radical Abstraction in the Functionalization of Plasma-Synthesized Silicon Nanocrystals
journal, September 2015
- Wheeler, Lance M.; Anderson, Nicholas C.; Palomaki, Peter K. B.
- Chemistry of Materials, Vol. 27, Issue 19, p. 6869-6878
Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation
journal, May 2016
- Nguyen, Cao Cuong; Yoon, Taeho; Seo, Daniel M.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 19
Molecular structure and fracture properties of ZrOX/Epoxysilane hybrid films
journal, June 2010
- Oliver, Mark S.; Blohowiak, Kay Y.; Dauskardt, Reinhold H.
- Journal of Sol-Gel Science and Technology, Vol. 55, Issue 3
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
The effect of electrolyte additives on electrochemical performance of silicon/mesoporous carbon (Si/MC) for anode materials for lithium-ion batteries
journal, September 2017
- Rezqita, Arlavinda; Sauer, Markus; Foelske, Annette
- Electrochimica Acta, Vol. 247
A comparative study of polyacrylic acid (PAA) and carboxymethyl cellulose (CMC) binders for Si-based electrodes
journal, December 2017
- Karkar, Z.; Guyomard, D.; Roué, L.
- Electrochimica Acta, Vol. 258
Surface-Functionalized Silicon Nanoparticles as Anode Material for Lithium-Ion Battery
journal, November 2018
- Jiang, Sisi; Hu, Bin; Sahore, Ritu
- ACS Applied Materials & Interfaces, Vol. 10, Issue 51
Investigating the Doping Mechanism of Pyrene Based Methacrylate Functional Conductive Binder in Silicon Anodes for Lithium-Ion Batteries
journal, January 2017
- Ling, Min; Liu, Michael; Zheng, Tianyue
- Journal of The Electrochemical Society, Vol. 164, Issue 4
Physically Cross-linked Polymer Binder Induced by Reversible Acid–Base Interaction for High-Performance Silicon Composite Anodes
journal, October 2015
- Lim, Sanghyun; Chu, Hodong; Lee, Kukjoo
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
Polydopamine Wrapping Silicon Cross-linked with Polyacrylic Acid as High-Performance Anode for Lithium-Ion Batteries
journal, January 2016
- Bie, Yitian; Yang, Jun; Liu, Xiaolin
- ACS Applied Materials & Interfaces, Vol. 8, Issue 5
Alumina-Coated Patterned Amorphous Silicon as the Anode for a Lithium-Ion Battery with High Coulombic Efficiency
journal, September 2011
- He, Yu; Yu, Xiqian; Wang, Yanhong
- Advanced Materials, Vol. 23, Issue 42
Hybrid Micellar Hydrogels of a Thermosensitive ABA Triblock Copolymer and Hairy Nanoparticles: Effect of Spatial Location of Hairy Nanoparticles on Gel Properties
journal, September 2014
- Hu, Bin; Henn, Daniel M.; Wright, Roger A. E.
- Langmuir, Vol. 30, Issue 37
Effect of surface modification on electrochemical performance of nano-sized Si as an anode material for Li-ion batteries
journal, January 2016
- Li, Chao; Shi, Tongfei; Li, Decheng
- RSC Advances, Vol. 6, Issue 41
Stabilizing the Solid Electrolyte Interphase Layer and Cycling Performance of Silicon–Graphite Battery Anode by Using a Binary Additive of Fluorinated Carbonates
journal, September 2016
- Jo, Hyuntak; Kim, Jaeram; Nguyen, Dan-Thien
- The Journal of Physical Chemistry C, Vol. 120, Issue 39
Nonthermal Plasma Synthesis of Nanocrystals: Fundamental Principles, Materials, and Applications
journal, August 2016
- Kortshagen, Uwe R.; Sankaran, R. Mohan; Pereira, Rui N.
- Chemical Reviews, Vol. 116, Issue 18
Side-Chain Conducting and Phase-Separated Polymeric Binders for High-Performance Silicon Anodes in Lithium-Ion Batteries
journal, February 2015
- Park, Sang-Jae; Zhao, Hui; Ai, Guo
- Journal of the American Chemical Society, Vol. 137, Issue 7
Scalable synthesis of spherical Si/C granules with 3D conducting networks as ultrahigh loading anodes in lithium-ion batteries
journal, May 2018
- Xu, Quan; Sun, Jian-Kun; Li, Jin-Yi
- Energy Storage Materials, Vol. 12
High-Yield Plasma Synthesis of Luminescent Silicon Nanocrystals
journal, April 2005
- Mangolini, L.; Thimsen, E.; Kortshagen, U.
- Nano Letters, Vol. 5, Issue 4
Quantifying capacity loss due to solid-electrolyte-interphase layer formation on silicon negative electrodes in lithium-ion batteries
journal, October 2012
- Nadimpalli, Siva P. V.; Sethuraman, Vijay A.; Dalavi, Swapnil
- Journal of Power Sources, Vol. 215
Electrochemical performance and interfacial investigation on Si composite anode for lithium ion batteries in full cell
journal, August 2017
- Shobukawa, Hitoshi; Alvarado, Judith; Yang, Yangyuchen
- Journal of Power Sources, Vol. 359
Structural study of sol–gel silicate glasses by IR and Raman spectroscopies
journal, April 2009
- Aguiar, H.; Serra, J.; González, P.
- Journal of Non-Crystalline Solids, Vol. 355, Issue 8
Toward an Ideal Polymer Binder Design for High-Capacity Battery Anodes
journal, July 2013
- Wu, Mingyan; Xiao, Xingcheng; Vukmirovic, Nenad
- Journal of the American Chemical Society, Vol. 135, Issue 32
Watermelon-Inspired Si/C Microspheres with Hierarchical Buffer Structures for Densely Compacted Lithium-Ion Battery Anodes
journal, October 2016
- Xu, Quan; Li, Jin-Yi; Sun, Jian-Kun
- Advanced Energy Materials, Vol. 7, Issue 3
Measuring the Grafting Density of Nanoparticles in Solution by Analytical Ultracentrifugation and Total Organic Carbon Analysis
journal, September 2012
- Benoit, Denise N.; Zhu, Huiguang; Lilierose, Michael H.
- Analytical Chemistry, Vol. 84, Issue 21
Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes
journal, April 2009
- Chan, Candace K.; Ruffo, Riccardo; Hong, Seung Sae
- Journal of Power Sources, Vol. 189, Issue 2, p. 1132-1140
Partially Oxidized Silicon Particles for Stable Aqueous Slurries and Practical Large-Scale Making of Si-Based Electrodes
journal, January 2015
- Touidjine, Amina; Morcrette, Mathieu; Courty, Matthieu
- Journal of The Electrochemical Society, Vol. 162, Issue 8
Role of the LiPF 6 Salt for the Long-Term Stability of Silicon Electrodes in Li-Ion Batteries – A Photoelectron Spectroscopy Study
journal, January 2013
- Philippe, Bertrand; Dedryvère, Rémi; Gorgoi, Mihaela
- Chemistry of Materials, Vol. 25, Issue 3
Mechanical Properties and Chemical Reactivity of Li x SiO y Thin Films
journal, October 2018
- Xu, Yun; Stetson, Caleb; Wood, Kevin
- ACS Applied Materials & Interfaces, Vol. 10, Issue 44
Infrared spectra-structure correlations for organosilicon compounds
journal, January 1960
- Smith, A. Lee
- Spectrochimica Acta, Vol. 16, Issue 1-2
Standardization of peeling tests for assessing the cohesion and consolidation characteristics of historic stone surfaces
journal, September 2011
- Drdácký, Miloš; Lesák, Jaroslav; Rescic, Silvia
- Materials and Structures, Vol. 45, Issue 4
Inorganic–organic interpenetrating polymer networks involving polyhedral oligomeric silsesquioxane and poly(ethylene oxide)
journal, February 2007
- Mu, Jiangfeng; Liu, Yonghong; Zheng, Sixun
- Polymer, Vol. 48, Issue 5
High performance polymer binders inspired by chemical finishing of textiles for silicon anodes in lithium ion batteries
journal, January 2017
- Wei, Liangming; Hou, Zhongyu
- J. Mater. Chem. A, Vol. 5, Issue 42
Strategy for Boosting Li-Ion Current in Silicon Nanoparticles
journal, August 2018
- Song, Min-Sang; Chang, Geewoo; Jung, Dae-Woong
- ACS Energy Letters, Vol. 3, Issue 9
Si Oxidation and H 2 Gassing During Aqueous Slurry Preparation for Li-Ion Battery Anodes
journal, April 2018
- Hays, Kevin A.; Key, Baris; Li, Jianlin
- The Journal of Physical Chemistry C, Vol. 122, Issue 18
Tailoring the Surface of Silicon Nanoparticles for Enhanced Chemical and Electrochemical Stability for Li-Ion Batteries
journal, August 2019
- Jiang, Sisi; Hu, Bin; Sahore, Ritu
- ACS Applied Energy Materials, Vol. 2, Issue 9
Size matters: why nanomaterials are different
journal, January 2006
- Roduner, Emil
- Chemical Society Reviews, Vol. 35, Issue 7
Toward Silicon Anodes for Next-Generation Lithium Ion Batteries: A Comparative Performance Study of Various Polymer Binders and Silicon Nanopowders
journal, July 2013
- Erk, Christoph; Brezesinski, Torsten; Sommer, Heino
- ACS Applied Materials & Interfaces, Vol. 5, Issue 15
Understanding Fluoroethylene Carbonate and Vinylene Carbonate Based Electrolytes for Si Anodes in Lithium Ion Batteries with NMR Spectroscopy
journal, July 2018
- Jin, Yanting; Kneusels, Nis-Julian H.; Marbella, Lauren E.
- Journal of the American Chemical Society, Vol. 140, Issue 31
A Mechanically Robust and Highly Ion-Conductive Polymer-Blend Coating for High-Power and Long-Life Lithium-Ion Battery Anodes
journal, November 2014
- Li, Fu-Sheng; Wu, Yu-Shiang; Chou, Jackey
- Advanced Materials, Vol. 27, Issue 1
Size-Dependent Asymmetric Auger Interactions in Plasma-Produced n- and p-Type-Doped Silicon Nanocrystals
journal, February 2019
- Limpens, Rens; Pach, Gregory F.; Mulder, David W.
- The Journal of Physical Chemistry C, Vol. 123, Issue 9
Improved Performance of the Silicon Anode for Li-Ion Batteries: Understanding the Surface Modification Mechanism of Fluoroethylene Carbonate as an Effective Electrolyte Additive
journal, March 2015
- Xu, Chao; Lindgren, Fredrik; Philippe, Bertrand
- Chemistry of Materials, Vol. 27, Issue 7
Silicon Nanoparticles: Stability in Aqueous Slurries and the Optimization of the Oxide Layer Thickness for Optimal Electrochemical Performance
journal, September 2017
- Zhang, Linghong; Liu, Yuzi; Key, Baris
- ACS Applied Materials & Interfaces, Vol. 9, Issue 38
What makes lithium substituted polyacrylic acid a better binder than polyacrylic acid for silicon-graphite composite anodes?
journal, April 2018
- Hays, Kevin A.; Ruther, Rose E.; Kukay, Alexander J.
- Journal of Power Sources, Vol. 384
Effect of Binder Architecture on the Performance of Silicon/Graphite Composite Anodes for Lithium Ion Batteries
journal, January 2018
- Cao, Peng-Fei; Naguib, Michael; Du, Zhijia
- ACS Applied Materials & Interfaces, Vol. 10, Issue 4
From Hydrogen Silsesquioxane to Functionalized Silicon Nanocrystals
journal, October 2016
- Clark, Rhett J.; Aghajamali, Maryam; Gonzalez, Christina M.
- Chemistry of Materials, Vol. 29, Issue 1
Characterization of Silicon Nanocrystal Surfaces by Multidimensional Solid-State NMR Spectroscopy
journal, November 2017
- Hanrahan, Michael P.; Fought, Ellie L.; Windus, Theresa L.
- Chemistry of Materials, Vol. 29, Issue 24
Li-ion battery materials: present and future
journal, June 2015
- Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
- Materials Today, Vol. 18, Issue 5
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid
journal, October 2010
- Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor
- ACS Applied Materials & Interfaces, Vol. 2, Issue 11
Hollow Carbon Nanospheres with Superior Rate Capability for Sodium-Based Batteries
journal, May 2012
- Tang, Kun; Fu, Lijun; White, Robin J.
- Advanced Energy Materials, Vol. 2, Issue 7
Understanding of pre-lithiation of poly(acrylic acid) binder: Striking the balances between the cycling performance and slurry stability for silicon-graphite composite electrodes in Li-ion batteries
journal, March 2019
- Hu, Bin; Jiang, Sisi; Shkrob, Ilya A.
- Journal of Power Sources, Vol. 416
Surface Binding of Polypyrrole on Porous Silicon Hollow Nanospheres for Li-Ion Battery Anodes with High Structure Stability
journal, July 2014
- Du, Fei-Hu; Li, Bo; Fu, Wei
- Advanced Materials, Vol. 26, Issue 35
Nonthermal Plasma-Synthesized Phosphorus–Boron co-Doped Si Nanocrystals: A New Approach to Nontoxic NIR-Emitters
journal, May 2019
- Limpens, Rens; Pach, Gregory F.; Neale, Nathan R.
- Chemistry of Materials, Vol. 31, Issue 12
Quantifying gas generation from slurries used in fabrication of Si-containing electrodes for lithium-ion cells
journal, August 2018
- Rodrigues, Marco-Tulio F.; Trask, Stephen E.; Shkrob, Ilya A.
- Journal of Power Sources, Vol. 395
Effect of vinylene carbonate (VC) as electrolyte additive on electrochemical performance of Si film anode for lithium ion batteries
journal, December 2007
- Chen, Libao; Wang, Ke; Xie, Xiaohua
- Journal of Power Sources, Vol. 174, Issue 2
Improved Initial Performance of Si Nanoparticles by Surface Oxide Reduction for Lithium-Ion Battery Application
journal, January 2011
- Xun, S.; Song, X.; Grass, M. E.
- Electrochemical and Solid-State Letters, Vol. 14, Issue 5