Silicon oxide based high capacity anode materials for lithium ion batteries

Title: Silicon oxide based high capacity anode materials for lithium ion batteries

Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.

Inventors:: Deng, Haixia; Han, Yongbong; Masarapu, Charan; Anguchamy, Yogesh Kumar; Lopez, Herman A.; Kumar, Sujeet

Issue Date:: 2017-03-21

OSTI Identifier:: 1347561

Assignee:: Envia Systems, Inc. ARPA-E

Patent Number(s):: 9,601,228

Application Number:: 13/108,708

Contract Number:: AR0000034

Resource Relation:: Patent File Date: 2011 May 16

Research Org:: Envia Systems, Inc. Newark, CA (United States)

Sponsoring Org:: USDOE

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Full Text
View Full Text

Other works cited in this record:

Electrode including porous particles with embedded active material for use in a secondary electrochemical cell
patent, April 1978

Vissers, Donald R.; Nelson, Paul A.; Kaun, Thomas D.
US Patent Document 4,086,404
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4086404

Secondary battery
patent, July 1990

Miyabayashi, Mitsutaka; Nishii, Toshifumi; Yui, Hiroshi
US Patent Document 4,945,014
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F4945014

High energy electrochemical cell having composite solid-state anode
patent, September 1992

Beard, Kirby W.
US Patent Document 5,147,739
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5147739

Electrochemical secondary element
patent, November 1992

Herr, Rudolf; Hoge, Detlev; Bittihn, Rainer
US Patent Document 5,162,176
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5162176

Non-aqueous electrolyte secondary battery and its production method
patent, March 1995

Tahara, Kensuke; Ishikawa, Hideki; Iwasaki, Fumiharu
US Patent Document 5,395,711
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5395711

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell
patent, July 1995

Huang, Chen-Kuo; Surampudi, Subbarao; Attia, Alan I.
US Patent Document 5,436,093
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5436093

Method for intercalating alkali metal ions into carbon electrodes
patent, August 1995

Doeff, Marca M.; Ma, Yanping; Visco, Steven J.
US Patent Document 5,443,601
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5443601

Composite anode for nonaqueous secondary battery and method for producing the same
patent, July 1996

Mizumoto, Mamoru; Honbo, Hidetoshi; Horiba, Tatsuo
US Patent Document 5,541,022
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5541022

Process for prelithiation of carbon based anodes for lithium batteries
patent, January 1997

Olsen, Ib I.; Koksbang, Rene
US Patent Document 5,595,837
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5595837

Rechargeable lithium battery having improved reversible capacity
patent, February 1998

Jacobs, James K.; Dasgupta, Sankar
US Patent Document 5,721,067
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5721067

Method of making a cell using a lithium-deactivated carbon anode
patent, April 1998

Nazri, Gholam-Abbas; Howie, Blake James
US Patent Document 5,743,921
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5743921

Process for prelithiation of carbon based anodes for lithium ion electrochemical cells
patent, May 1998

Koksbang, Rene; Olsen, Ib I.; Barker, Jeremy
US Patent Document 5,753,388
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5753388

Negative electrode material for use in lithium-ion secondary battery and process for producing the same
patent, August 1998

Ejiri, Hiroshi; Yamazaki, Yoshinori; Nakajima, Hideyuki
US Patent Document 5,792,577
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5792577

Lithium ion electrochemical cell
patent, September 1999

Moses, Peter R.; Zeng, Shuming; Wang, Enoch
US Patent Document 5,948,569
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F5948569

Lithium ion cell
patent, February 2000

Herr, Rudolf
US Patent Document 6,025,093
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6025093

Non-aqueous electrolyte secondary battery
patent, July 2000

Watanabe, Shunji; Takasugi, Shinichi; Sakai, Tsugio
US Patent Document 6,083,644
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6083644

Nonaqueous secondary battery containing silicic material
patent, May 2001

Idota, Yoshio; Matsufuji, Akihiro; Mori, Nobufumi
US Patent Document 6,235,427
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6235427

Method of making activated carbon derived from pitches
patent, June 2011

Peng, Y. Lisa; Williams, Jimmie L.
US Patent Document 6,251,822
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6251822

Secondary lithium-ion cell with an auxiliary electrode
patent, January 2002

Meissner, Eberhard
US Patent Document 6,335,115
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6335115

Anodes for rechargeable lithium batteries
patent, March 2003

Thackeray, Michael M.; Kepler, Keith D.; Vaughey, John T.
US Patent Document 6,528,208
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6528208

Lithium secondary battery having oxide particles embedded in particles of carbonaceous material as a negative electrode-active material
patent, October 2003

Kaneda, Junya; Takeuchi, Seiji; Watanabe, Noriyuki
US Patent Document 6,638,662
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6638662

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode
patent, November 2003

Tsutsumi, Masami; Horiuchi, Hiroshi; Yamamoto, Tamotsu
US Patent Document 6,645,671
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6645671

Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004

Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
US Patent Document 6,677,082
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6677082

Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004

Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
US Patent Document 6,680,143
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6680143

Amorphous electrode compositions
patent, March 2004

Turner, Robert L.; Fredericksen, Brian D.; Krause, Larry J.
US Patent Document 6,699,336
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6699336

Lithium metal dispersion in secondary battery anodes
patent, December 2001

Gao, Yuan; Burba, III, John L.
US Patent Document 6,706,447
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6706447

Double current collector negative electrode design for alkali metal ion electrochemical cells
patent, May 2004

Gan, Hong; Rubino, Robert S.; Takeuchi, Esther S
US Patent Document 6,737,191
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6737191

Silicon oxide powder and making method
patent, July 2004

Fukuoka, Hirofumi; Miyawaki, Satoru; Ooka, Kenji
US Patent Document 6,759,160
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6759160

Secondary battery
patent, April 2005

Fujita, Shigeru; Akashi, Hiroyuki; Adachi, Momoe
US Patent Document 6,884,546
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6884546

Lithium-containing silicon oxide powder and making method
patent, May 2005

Fukuoka, Hirofumi; Miyawaki, Satoru; Aramata, Mikio
US Patent Document 6,893,621
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6893621

Electrochemical cell electrodes comprising coal-based carbon foam
patent, May 2005

Rogers, Darren K.; Plucinski, Janusz Wladyslaw
US Patent Document 6,899,970
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6899970

Battery including carbon foam current collectors
patent, December 2005

Kelley, Kurtis Chad; Votoupal, John J.
US Patent Document 6,979,513
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F6979513

Conductive silicon composite, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent, May 2006

Aramata, Mikio; Miyawaki, Satoru; Ueno, Susumu
US Patent Document 7,037,581
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7037581

Electrode for use in lithium battery and rechargeable lithium battery
patent, March 2007

Fujimoto, Masahisa; Fujitani, Shin; Shima, Masaki
US Patent Document 7,195,842
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7195842

Layered cathode materials for lithium ion rechargeable batteries
patent, April 2007

Kang, Sun-Ho; Amine, Khalil
US Patent Document 7,205,072
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7205072

Electrode for use in lithium battery and rechargeable lithium battery
patent, June 2007

Fujimoto, Masahisa; Fujitani, Shin; Shima, Masaki
US Patent Document 7,235,33
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7235330

Nonaqueous electrolyte secondary battery
patent, August 2007

Takeuchi, Masanobu; Yoshimura, Seiji
US Patent Document 7,252,907
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7252907

Lithium metal dispersion in secondary battery anodes
patent, October 2007

Gao, Yuan; Burba, III, John L.
US Patent Document 7,276,314
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7276314

Negative electrode for rechargeable lithium battery and method for fabrication thereof
patent, November 2007

Fukui, Atsushi; Torimae, Mariko; Kusumoto, Yasuyuki
US Patent DOcument 7,297,446
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7297446

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent, October 2008

Jeong, Goo-Jin; Lee, Sang-Min; Kim, Sung-Soo
US Patent Document 7,432,015
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7432015

Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries
patent, October 2008

Kang, Sun-Ho; Amine, Khalil
US Patent Document 7,435,402
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7435402

Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery comprising same
patent, November 2008

Lee, Sang-Min; Kim, Sung-Soo; Sheem, Kyou-Yoon
US Patent Document 7,452,632
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7452632

Method of producing porous silicon particles by stain-etching and silicon nanoparticles from stain-etched silicon powder
patent, April 2009

Li, Yunjun; Pavlovsky, Igor
US Patent Document 7,514,369
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7514369

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent, April 2009

Jeong, Goo-Jin; Lee, Sang-Min; Kim, Sung-Soo
US Patent Document 7,517,614
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7517614

Lithium-ion battery
patent, July 2009

Howard, William G.; Schmidt, Craig L.; Scott, Erik R.
US Patent Document 7,563,541
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7563541

Lithium secondary battery
patent, August 2009

Kawamura, Naoya; Kawakami, Soichiro
US Patent Document 7,575,830
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7575830

Lithium-ion battery
patent, September 2009

Howard, William G.; Schmidt, Craig L.; Scott, Erik R.
US Patent Document 7,582,387
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7582387

Stabilized lithium metal powder for li-ion application, composition and process
patent, September 2009

Dover, B. Troy; Woltermann, Christopher Jay; Yakovleva, Marina
US Patent Document 7,588,623
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7588623

Electrode structure for lithium secondary battery and secondary battery having such electrode structure
patent, November 2009

Kawakami, Soichiro; Morita, Akira; Ogura, Takao
US Patent Document 7,615,314
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7615314

Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, February 2010

Aramata, Mikio; Miyawaki, Satoru; Fukuoka, Hirofumi
US Patent Document 7,658,863
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7658863

Battery including an electrolyte solution comprising a halogenated carbonate derivative
patent, July 2010

Yamaguchi, Akira; Nakajima, Kaoru; Fujishige, Yusuke
US Patent Document 7,754,389
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7754389

Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, August 2010

Aramata, Mikio; Watanabe, Koichiro; Miyawaki, Satoru
US Patent Document 7,776,473
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7776473

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent, September 2010

Aramata, Mikio; Miyawaki, Satoru; Fukuoka, Hirofumi
US Patent Document 7,790,316
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7790316

Anode active material, method of preparing the same, and anode and lithium battery containing the material
patent, November 2010

Kim, Han-su; Mah, Sang-kook
US Patent Document 7,833,662
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7833662

Alloy compositions for lithium ion batteries
patent, December 2010

Obrovac, Mark N.; Christensen, Leif
US Patent Document 7,851,085
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7851085

Alloy composition for lithium ion batteries
patent, January 2011

Obrovac, Mark N.; Christensen, Leif
US Patent Document 7,871,727
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7871727

Non-aqueous electrolyte secondary battery
patent, April 2011

Yamamoto, Teruaki; Ueda, Tomohiro; Waki, Shinichi
US Patent Document 7,923,150
URL: http://patft.uspto.gov/netacgi/nph-Parser?Sect2=PTO1&Sect2=HITOFF&p=1&u=%2Fnetahtml%2FPTO%2Fsearch-bool.html&r=1&f=G&l=50&d=PALL&RefSrch=yes&Query=PN%2F7923150

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries
journal, January 1999

Chiang, Yet-Ming; Sadoway, Donald R.; Jang, Young‐Il
Electrochemical and Solid-State Letters, Vol. 2, Issue 3, p. 107-110
DOI: 10.1149/1.1390750

Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni_0.17Li_0.2Co_0.07Mn_0.56]O₂
journal, January 2010

Ito, Atsushi; Li, Decheng; Sato, Yuichi
Journal of Power Sources, Vol. 195, Issue 2, p. 567-573
DOI: 10.1016/j.jpowsour.2009.07.052

A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment
journal, August 2008

Ito, Atsushi; Li, Decheng; Ohsawa, Yasuhiko
Journal of Power Sources, Vol. 183, Issue 1, p. 344-346
DOI: 10.1016/j.jpowsour.2008.04.086

Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes
journal, June 2009

Ruffo, Riccardo; Hong, Seung Sae; Chan, Candace K.
The Journal of Physical Chemistry C, Vol. 113, Issue 26, p. 11390-11398
DOI: 10.1021/jp901594g

Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling
journal, January 1998

Wang, C. S.; Wu, G. T.; Zhang, X. B.
Journal of The Electrochemical Society, Vol. 145, Issue 8, p. 2751-2758
DOI: 10.1149/1.1838709

Electrochemical Behavior of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries
journal, January 2009

Achiha, Takashi; Nakajima, Tsuyoshi; Ohzawa, Yoshimi
Journal of The Electrochemical Society, Vol. 156, Issue 6, p. A483-A488
DOI: 10.1149/1.3111904

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Chan, Candace K.; Peng, Hailin; Liu, Gao
Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
DOI: 10.1038/nnano.2007.411

Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode
journal, October 2006

Choi, Nam-Soon; Yew, Kyoung Han; Lee, Kyu Youl
Journal of Power Sources, Vol. 161, Issue 2, p. 1254-1259
DOI: 10.1016/j.jpowsour.2006.05.049

Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries
journal, September 2009

Cui, Li-Feng; Yang, Yuan; Hsu, Ching-Mei
Nano Letters, Vol. 9, Issue 9, p. 3370-3374
DOI: 10.1021/nl901670t

SiO_x–graphite as negative for high energy Li-ion batteries
journal, July 2011

Guerfi, A.; Charest, P.; Dontigny, M.
Journal of Power Sources, Vol. 196, Issue 13, p. 5667-5673
DOI: 10.1016/j.jpowsour.2011.02.018

Li-Ion Battery Performance with FSI-Based Ionic Liquid Electrolyte and Fluorinated Solvent-Based Electrolyte
journal, January 2011

Ishikawa, Masashi; Yamagata, Masaki; Sugimoto, Toshinori
DOI: 10.1149/1.3563087

A Nanostructured SiAl_0.2O Anode Material for Lithium Batteries
journal, October 2010

Jeong, Goojin; Kim, Young-Ugk; Krachkovskiy, Sergey A.
Chemistry of Materials, Vol. 22, Issue 19, p. 5570-5579
DOI: 10.1021/cm101747w

Enhancing the rate capability of high capacity xLi₂MnO₃ · (1−x)LiMO₂ (M=Mn, Ni, Co) electrodes by Li–Ni–PO₄ treatment
journal, April 2009

Kang, Sun-Ho; Thackeray, Michael M.
Electrochemistry Communications, Vol. 11, Issue 4, p. 748-751
DOI: 10.1016/j.elecom.2009.01.025

Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries
journal, August 2005

Kang, S.-H.; Amine, K.
Journal of Power Sources, Vol. 146, Issue 1-2, p. 654-657
DOI: 10.1016/j.jpowsour.2005.03.152

Synthesis of spherical Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ as positive electrode material for lithium-ion battery
journal, February 2006

Kim, Gil-Ho; Myung, Seung-Taek; Kim, Hyun-Soo
Electrochimica Acta, Vol. 51, Issue 12, p. 2447-2453
DOI: 10.1016/j.electacta.2005.07.026

Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries
journal, July 2005

Kim, G.-H.; Kim, J.-H.; Myung, S.-T.
Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1707-A1713
DOI: 10.1149/1.1952747

High capacity Li[Li_0.2Ni_0.2Mn_0.6]O₂ cathode materials via a carbonate co-precipitation method
journal, November 2006

Lee, D.-K.; Park, S.-H.; Amine, K.
Journal of Power Sources, Vol. 162, Issue 2, p. 1346-1350
DOI: 10.1016/j.jpowsour.2006.07.064

Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating
journal, April 2009

Liu, Y.; Wen, Z. Y.; Wang, X. Y.
Journal of Power Sources, Vol. 189, Issue 1, p. 480-484
DOI: 10.1016/j.jpowsour.2008.12.045

Electrical transport in doped multiwalled carbon nanotubes
journal, April 2001

Liu, K.; Avouris, Ph.; Martel, R.
Physical Review B, Vol. 63, Issue 16, Article No. 161404(R)
DOI: 10.1103/PhysRevB.63.161404

Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
journal, September 1999

McMillan, Rod; Slegr, Helen; Shu, Z. X.
Journal of Power Sources, Vol. 81-82, p. 20-26
DOI: 10.1016/S0378-7753(98)00201-8

Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries
journal, January 2007

Miyachi, Mariko; Yamamoto, Hironori; Kawai, Hidemasa
Journal of The Electrochemical Society, Vol. 154, Issue 4, p. A376-A380
DOI: 10.1149/1.2455963

Nonflammable Hydrofluoroether for Lithium-Ion Batteries: Enhanced Rate Capability, Cyclability, and Low-Temperature Performance
journal, January 2009

Naoi, Katsuhiko; Iwama, Etsuro; Ogihara, Nobuhiro
Journal of The Electrochemical Society, Vol. 156, Issue 4, p. A272-A276
DOI: 10.1149/1.3073552

Enhanced thermal properties of the solid electrolyte interphase formed on graphite in an electrolyte with fluoroethylene carbonate
journal, July 2009

Profatilova, Irina A.; Kim, Sung-Soo; Choi, Nam-Soon
Electrochimica Acta, Vol. 54, Issue 19, p. 4445-4450
DOI: 10.1016/j.electacta.2009.03.032

Nano-SnSb alloy deposited on MCMB as an anode material for lithium ion batteries
journal, January 2001

Shi, Lihong; Li, Hong; Wang, Zhaoxiang
Journal of Materials Chemistry, Vol. 11, Issue 5, p. 1502-1505
DOI: 10.1039/b009907o

AlF₃-Coating to Improve High Voltage Cycling Performance of Li[Ni_1∕3]Co_1∕3]Mn_1∕3]O₂ Cathode Materials for Lithium Secondary Batteries
journal, January 2007

Sun, Y.-K.; Cho, S.-W.; Lee, S.-W.
Journal of The Electrochemical Society, Vol. 154, Issue 3, p. A168-A172
DOI: 10.1149/1.2422890

Significant improvement of high voltage cycling behavior AlF₃-coated LiCoO₂ cathode
journal, May 2006

Sun, Y.; Han, J.; Myung, S.
Electrochemistry Communications, Vol. 8, Issue 5, p. 821-826
DOI: 10.1016/j.elecom.2006.03.040

Li-doping process for Li_xSiO-negative active material synthesized by chemical method for lithium-ion cells
journal, August 2005

Tabuchi, Toru; Yasuda, Hideo; Yamachi, Masanori
Journal of Power Sources, Vol. 146, Issue 1-2, p. 507-509
DOI: 10.1016/j.jpowsour.2005.03.100

Comments on the structural complexity of lithium-rich Li_1+xM_1−xO₂ electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006

Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538
DOI: 10.1016/j.elecom.2006.06.030

Improvement of cycle behaviour of SiO/C anode composite by thermochemically generated Li₄SiO₄ inert phase for lithium batteries
journal, March 2009

Veluchamy, Angathevar; Doh, Chil-Hoon; Kim, Dong-Hun
Journal of Power Sources, Vol. 188, Issue 2, p. 574-577
DOI: 10.1016/j.jpowsour.2008.11.137

Significant Improvement of Electrochemical Performance of AlF₃-Coated Li[Ni_0.8Co_0.1Mn_0.1]O₂ Cathode Materials
journal, January 2007

Woo, S.-U.; Yoon, C. S.; Amine, K.
Journal of The Electrochemical Society, Vol. 154, Issue 11, p. A1005-A1009
DOI: 10.1149/1.2776160

Nanosized silicon-based composite derived by in situ mechanochemical reduction for lithium ion batteries
journal, February 2007

Yang, Xuelin; Wen, Zhaoyin; Xu, Xiaoxiong
Journal of Power Sources, Vol. 164, Issue 2, p. 880-884
DOI: 10.1016/j.jpowsour.2006.11.010

Electrochemical behaviors of silicon based anode material
journal, August 2005

Yoshio, Masaki; Tsumura, Takaaki; Dimov, Nikolay
Journal of Power Sources, Vol. 146, Issue 1-2, p. 10-14
DOI: 10.1016/j.jpowsour.2005.03.143

SiO_x-based anodes for secondary lithium batteries
journal, December 2002

Yang, J.; Takeda, Y.; Imanishi, N.
Solid State Ionics, Vol. 152-153, p. 125-129
DOI: 10.1016/S0167-2738(02)00362-4

Nano-sized SiO_x/C composite anode for lithium ion batteries
journal, May 2011

Wang, Jing; Zhao, Hailei; He, Jianchao
Journal of Power Sources, Vol. 196, Issue 10, p. 4811-4815
DOI: 10.1016/j.jpowsour.2011.01.053

Similar records in DOepatents and OSTI.GOV collections:

High capacity anode materials for lithium ion batteries

Patent Lopez, Herman A. ; Anguchamy, Yogesh Kumar ; Deng, Haixia ; Han, Yongbon ; Masarapu, Charan ; Venkatachalam, Subramanian ; Kumar, Suject

High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.
Full Text Available November 2015
High capacity anode materials for lithium ion batteries

Patent Lopez, Herman A. ; Anguchamy, Yogesh Kumar ; Deng, Haixia ; Han, Yongbong ; Masarapu, Charan ; Venkatachalam, Subramanian ; Kumar, Sujeet

High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.
Full Text Available June 2018
Silicon-based active materials for lithium ion batteries and synthesis with solution processing

Patent Han, Yongbong ; Masarapu, Charan ; Deng, Haixia ; Anguchamy, Yogesh Kumar ; Venkatachalam, Subramanian ; Lopez, Herman A.

Silicon based anode active materials are described for use in lithium ion batteries. The silicon based materials are generally composites of nanoscale elemental silicon with stabilizing components that can comprise, for example, silicon oxide-carbon matrix material, inert metal coatings or combinations thereof. High surface area morphology can further contribute to the material stability when cycled in a lithium based battery. In general, the material synthesis involves a significant solution based processing step that can be designed to yield desired material properties as well as providing convenient and scalable processing.
Full Text Available July 2018
Anode materials for lithium-ion batteries

Patent Sunkara, Mahendra Kumar ; Meduri, Praveen ; Sumanasekera, Gamini

An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.
Full Text Available December 2014
Anode materials for lithium ion batteries

Patent Abouimrane, Ali ; Amine, Khalil

A composite material has general Formula (1-x)J-(x)Q wherein: J is a metal carbon alloy of formula Sn.sub.zSi.sub.z'Met.sub.wMet'.sub.w'C.sub.t; Q is a metal oxide of formula A.sub..gamma.M.sub..alpha.M'.sub..alpha.'O.sub..beta.; A is Li, Na, or K; M, M', Met, and Met' are individually Ge, Mo, Al, Ga, As, Sb, Te, Ti, Ta, Zr, Ca, Mg, Sr, Ba, Li, Na, K, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Nb, Rt, Ru or Cd; 0
Full Text Available June 2015