Silicon oxide based high capacity anode materials for lithium ion batteries

Title: Silicon oxide based high capacity anode materials for lithium ion batteries

Abstract

Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.

Inventors:: Deng, Haixia; Han, Yongbong; Masarapu, Charan; Anguchamy, Yogesh Kumar; Lopez, Herman A.; Kumar, Sujeet

Issue Date:: 2017-03-21

Research Org.:: Envia Systems, Inc. Newark, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1347561

Patent Number(s):: 9,601,228

Application Number:: 13/108,708

Assignee:: Envia Systems, Inc.

DOE Contract Number:: AR0000034

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011 May 16

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Deng, Haixia, Han, Yongbong, Masarapu, Charan, Anguchamy, Yogesh Kumar, Lopez, Herman A., and Kumar, Sujeet. Silicon oxide based high capacity anode materials for lithium ion batteries.  United States: N. p., 2017. 
        Web.

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                    Deng, Haixia, Han, Yongbong, Masarapu, Charan, Anguchamy, Yogesh Kumar, Lopez, Herman A., & Kumar, Sujeet. Silicon oxide based high capacity anode materials for lithium ion batteries.  United States.

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                    Deng, Haixia, Han, Yongbong, Masarapu, Charan, Anguchamy, Yogesh Kumar, Lopez, Herman A., and Kumar, Sujeet. Tue .  
        "Silicon oxide based high capacity anode materials for lithium ion batteries".  United States.  https://www.osti.gov/servlets/purl/1347561.

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@article{osti_1347561,

  title        = {Silicon oxide based high capacity anode materials for lithium ion batteries},

  author       = {Deng, Haixia and Han, Yongbong and Masarapu, Charan and Anguchamy, Yogesh Kumar and Lopez, Herman A. and Kumar, Sujeet},

  abstractNote = {Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {3}

}

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Shi, Lihong; Li, Hong; Wang, Zhaoxiang
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Sun, Y.-K.; Cho, S.-W.; Lee, S.-W.
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Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
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Veluchamy, Angathevar; Doh, Chil-Hoon; Kim, Dong-Hun
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Significant Improvement of Electrochemical Performance of AlF₃-Coated Li[Ni_0.8Co_0.1Mn_0.1]O₂ Cathode Materials
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Yang, Xuelin; Wen, Zhaoyin; Xu, Xiaoxiong
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Electrochemical behaviors of silicon based anode material
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SiO_x-based anodes for secondary lithium batteries
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Yang, J.; Takeda, Y.; Imanishi, N.
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Nano-sized SiO_x/C composite anode for lithium ion batteries
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Title: Silicon oxide based high capacity anode materials for lithium ion batteries

Abstract

Citation Formats

Electrode including porous particles with embedded active material for use in a secondary electrochemical cell patent, April 1978

Secondary battery patent, July 1990

High energy electrochemical cell having composite solid-state anode patent, September 1992

Electrochemical secondary element patent, November 1992

Non-aqueous electrolyte secondary battery and its production method patent, March 1995

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell patent, July 1995

Method for intercalating alkali metal ions into carbon electrodes patent, August 1995

Composite anode for nonaqueous secondary battery and method for producing the same patent, July 1996

Process for prelithiation of carbon based anodes for lithium batteries patent, January 1997

Rechargeable lithium battery having improved reversible capacity patent, February 1998

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Process for prelithiation of carbon based anodes for lithium ion electrochemical cells patent, May 1998

Negative electrode material for use in lithium-ion secondary battery and process for producing the same patent, August 1998

Lithium ion electrochemical cell patent, September 1999

Lithium ion cell patent, February 2000

Non-aqueous electrolyte secondary battery patent, July 2000

Nonaqueous secondary battery containing silicic material patent, May 2001

Method of making activated carbon derived from pitches patent, June 2011

Secondary lithium-ion cell with an auxiliary electrode patent, January 2002

Anodes for rechargeable lithium batteries patent, March 2003

Lithium secondary battery having oxide particles embedded in particles of carbonaceous material as a negative electrode-active material patent, October 2003

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode patent, November 2003

Lithium metal oxide electrodes for lithium cells and batteries patent, January 2004

Lithium metal oxide electrodes for lithium cells and batteries patent, January 2004

Amorphous electrode compositions patent, March 2004

Lithium metal dispersion in secondary battery anodes patent, December 2001

Double current collector negative electrode design for alkali metal ion electrochemical cells patent, May 2004

Silicon oxide powder and making method patent, July 2004

Secondary battery patent, April 2005

Lithium-containing silicon oxide powder and making method patent, May 2005

Electrochemical cell electrodes comprising coal-based carbon foam patent, May 2005

Battery including carbon foam current collectors patent, December 2005

Conductive silicon composite, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent, May 2006

Electrode for use in lithium battery and rechargeable lithium battery patent, March 2007

Layered cathode materials for lithium ion rechargeable batteries patent, April 2007

Electrode for use in lithium battery and rechargeable lithium battery patent, June 2007

Nonaqueous electrolyte secondary battery patent, August 2007

Lithium metal dispersion in secondary battery anodes patent, October 2007

Negative electrode for rechargeable lithium battery and method for fabrication thereof patent, November 2007

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same patent, October 2008

Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries patent, October 2008

Negative active material for rechargeable lithium battery, method of preparing same, and rechargeable lithium battery comprising same patent, November 2008

Method of producing porous silicon particles by stain-etching and silicon nanoparticles from stain-etched silicon powder patent, April 2009

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same patent, April 2009

Lithium-ion battery patent, July 2009

Lithium secondary battery patent, August 2009

Lithium-ion battery patent, September 2009

Stabilized lithium metal powder for li-ion application, composition and process patent, September 2009

Electrode structure for lithium secondary battery and secondary battery having such electrode structure patent, November 2009

Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent, February 2010

Battery including an electrolyte solution comprising a halogenated carbonate derivative patent, July 2010

Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material patent, August 2010

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell patent, September 2010

Anode active material, method of preparing the same, and anode and lithium battery containing the material patent, November 2010

Alloy compositions for lithium ion batteries patent, December 2010

Alloy composition for lithium ion batteries patent, January 2011

Non-aqueous electrolyte secondary battery patent, April 2011

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries journal, January 1999

Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 journal, January 2010

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Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling journal, January 1998

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High-performance lithium battery anodes using silicon nanowires journal, December 2007

Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode journal, October 2006

Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries journal, September 2009

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Electrode including porous particles with embedded active material for use in a secondary electrochemical cell
patent, April 1978

Secondary battery
patent, July 1990

High energy electrochemical cell having composite solid-state anode
patent, September 1992

Electrochemical secondary element
patent, November 1992

Non-aqueous electrolyte secondary battery and its production method
patent, March 1995

Method for fabricating carbon/lithium-ion electrode for rechargeable lithium cell
patent, July 1995

Method for intercalating alkali metal ions into carbon electrodes
patent, August 1995

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patent, July 1996

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patent, January 1997

Rechargeable lithium battery having improved reversible capacity
patent, February 1998

Method of making a cell using a lithium-deactivated carbon anode
patent, April 1998

Process for prelithiation of carbon based anodes for lithium ion electrochemical cells
patent, May 1998

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patent, August 1998

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patent, September 1999

Lithium ion cell
patent, February 2000

Non-aqueous electrolyte secondary battery
patent, July 2000

Nonaqueous secondary battery containing silicic material
patent, May 2001

Method of making activated carbon derived from pitches
patent, June 2011

Secondary lithium-ion cell with an auxiliary electrode
patent, January 2002

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patent, March 2003

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patent, October 2003

Lithium secondary battery, anode for lithium secondary battery, and method for manufacturing the anode
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Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004

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patent, January 2004

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patent, March 2004

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patent, December 2001

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patent, May 2004

Silicon oxide powder and making method
patent, July 2004

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patent, April 2005

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patent, May 2005

Electrochemical cell electrodes comprising coal-based carbon foam
patent, May 2005

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patent, December 2005

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patent, May 2006

Electrode for use in lithium battery and rechargeable lithium battery
patent, March 2007

Layered cathode materials for lithium ion rechargeable batteries
patent, April 2007

Electrode for use in lithium battery and rechargeable lithium battery
patent, June 2007

Nonaqueous electrolyte secondary battery
patent, August 2007

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patent, October 2007

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patent, November 2007

Negative active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery comprising the same
patent, October 2008

Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries
patent, October 2008

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patent, April 2009

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Lithium-ion battery
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Lithium secondary battery
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Lithium-ion battery
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Stabilized lithium metal powder for li-ion application, composition and process
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Electrode structure for lithium secondary battery and secondary battery having such electrode structure
patent, November 2009

Si-C-O composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, February 2010

Battery including an electrolyte solution comprising a halogenated carbonate derivative
patent, July 2010

Silicon-silicon oxide-lithium composite, making method, and non-aqueous electrolyte secondary cell negative electrode material
patent, August 2010

Silicon composite particles, preparation thereof, and negative electrode material for non-aqueous electrolyte secondary cell
patent, September 2010

Anode active material, method of preparing the same, and anode and lithium battery containing the material
patent, November 2010

Alloy compositions for lithium ion batteries
patent, December 2010

Alloy composition for lithium ion batteries
patent, January 2011

Non-aqueous electrolyte secondary battery
patent, April 2011

High Capacity, Temperature-Stable Lithium Aluminum Manganese Oxide Cathodes for Rechargeable Batteries
journal, January 1999

Cyclic deterioration and its improvement for Li-rich layered cathode material Li[Ni_0.17Li_0.2Co_0.07Mn_0.56]O₂
journal, January 2010

A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatment
journal, August 2008

Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes
journal, June 2009

Lithium Insertion in Carbon-Silicon Composite Materials Produced by Mechanical Milling
journal, January 1998

Electrochemical Behavior of Nonflammable Organo-Fluorine Compounds for Lithium Ion Batteries
journal, January 2009

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Effect of fluoroethylene carbonate additive on interfacial properties of silicon thin-film electrode
journal, October 2006

Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries
journal, September 2009

SiO_x–graphite as negative for high energy Li-ion batteries
journal, July 2011

Li-Ion Battery Performance with FSI-Based Ionic Liquid Electrolyte and Fluorinated Solvent-Based Electrolyte
journal, January 2011

A Nanostructured SiAl_0.2O Anode Material for Lithium Batteries
journal, October 2010

Enhancing the rate capability of high capacity xLi₂MnO₃ · (1−x)LiMO₂ (M=Mn, Ni, Co) electrodes by Li–Ni–PO₄ treatment
journal, April 2009

Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries
journal, August 2005

Synthesis of spherical Li[Ni_(1/3−z)Co_(1/3−z)Mn_(1/3−z)Mg_z]O₂ as positive electrode material for lithium-ion battery
journal, February 2006

Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries
journal, July 2005

High capacity Li[Li_0.2Ni_0.2Mn_0.6]O₂ cathode materials via a carbonate co-precipitation method
journal, November 2006

Improvement of cycling stability of Si anode by mechanochemcial reduction and carbon coating
journal, April 2009

Electrical transport in doped multiwalled carbon nanotubes
journal, April 2001

Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
journal, September 1999

Electrochemical Properties and Chemical Structures of Metal-Doped SiO Anodes for Li-Ion Rechargeable Batteries
journal, January 2007

Nonflammable Hydrofluoroether for Lithium-Ion Batteries: Enhanced Rate Capability, Cyclability, and Low-Temperature Performance
journal, January 2009

Enhanced thermal properties of the solid electrolyte interphase formed on graphite in an electrolyte with fluoroethylene carbonate
journal, July 2009