Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing

Rios, Orlando; Carter, William G.; Kessler, Michael R.; Li, Yuzhan; Goswami, Monojoy

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Title: Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing

Abstract

Disclosed herein are embodiments of a composition that can be used to make liquid crystalline networks using thiol-ene-based polymerization. In particular embodiments, the liquid crystalline networks can be formed by using the composition embodiments in additive manufacturing methods. The composition comprises a monomer, chain extender compound, and a crosslinker compound and each of these components can be selected so as to influence the thermomechanical and shape memory properties of the liquid crystalline networks and/or objects formed therewith.

Inventors:: Rios, Orlando; Carter, William G.; Kessler, Michael R.; Li, Yuzhan; Goswami, Monojoy

Issue Date:: Tue Jul 25 00:00:00 EDT 2023

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 2222009

Patent Number(s):: 11708458

Application Number:: 17/076,693

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 10/21/2020

Country of Publication:: United States

Language:: English

Citation Formats


                    Rios, Orlando, Carter, William G., Kessler, Michael R., Li, Yuzhan, and Goswami, Monojoy. Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing.  United States: N. p., 2023. 
        Web.

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                    Rios, Orlando, Carter, William G., Kessler, Michael R., Li, Yuzhan, & Goswami, Monojoy. Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing.  United States.

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                    Rios, Orlando, Carter, William G., Kessler, Michael R., Li, Yuzhan, and Goswami, Monojoy. Tue .  
        "Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing".  United States.  https://www.osti.gov/servlets/purl/2222009.

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@article{osti_2222009,

  title        = {Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing},

  author       = {Rios, Orlando and Carter, William G. and Kessler, Michael R. and Li, Yuzhan and Goswami, Monojoy},

  abstractNote = {Disclosed herein are embodiments of a composition that can be used to make liquid crystalline networks using thiol-ene-based polymerization. In particular embodiments, the liquid crystalline networks can be formed by using the composition embodiments in additive manufacturing methods. The composition comprises a monomer, chain extender compound, and a crosslinker compound and each of these components can be selected so as to influence the thermomechanical and shape memory properties of the liquid crystalline networks and/or objects formed therewith.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Jul 25 00:00:00 EDT 2023},

  month        = {Tue Jul 25 00:00:00 EDT 2023}

}

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Works referenced in this record:

Stimuli-responsive liquid crystalline networks
patent, April 2019

Li, Yuzhan; Rios, Orlando; Kessler, Michael Richard
US Patent Document 10,253,261
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10253261

Liquid crystalline networks based on photo-initiated thiol–ene click chemistry
journal, January 2020

Li, Yuzhan; Zhang, Yuehong; Goswami, Monojoy
Soft Matter, Vol. 16, Issue 7
https://doi.org/10.1039/C9SM01818B

Liquid crystalline epoxy monomer and liquid crystalline epoxy resin containing mesogen twins
patent, September 1998

Shiota, Atsushi; Ober, Christopher K.
US Patent Document 5,811,504
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5811504

Photo-responsive thiol–ene networks for the design of switchable polymer patterns
journal, January 2017

Radl, S. V.; Schipfer, C.; Kaiser, S.
Polymer Chemistry, Vol. 8, Issue 9
https://doi.org/10.1039/C7PY00055C

Process for producing three-dimensionally crosslinked polyester having the liquid crystal structure
patent, December 1987

Uryu, Toshiyuki; Kato, Takashi
US Patent Document 4,710,547
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4710547

Production of crosslinked polymer layers having nonlinear optical properties and their use
patent, February 1995

Etzbach, Karl-Heinz; Kilburg, Heike; Lorkowski, Hans-Joachim
US Patent Document 5,393,644
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5393644

Microelectronic device having liquid crystalline epoxy resins
patent, September 2010

Matayabas, Jr., James C.; Koning, Paul A.
US Patent Document 7,794,623
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7794623

3D printable liquid crystalline elastomers with tunable shape memory behavior and bio-derived renditions
patent, September 2019

Li, Yuzhan; Rios, Orlando; Johs, Alexander
US Patent Document 10,407,535
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10407535

Functionalized Polymers Using Protected Thiols
patent-application, July 2009

David, Ralph L.; Kornfield, Julia A.
US Patent Application 12/251708; 20090176941
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090176941

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Similar Records

Title: Composition for thiol-ene-based polymerization and liquid crystalline network-containing objects formed therefrom using additive manufacturing

Abstract

Citation Formats

Stimuli-responsive liquid crystalline networks patent, April 2019

Liquid crystalline networks based on photo-initiated thiol–ene click chemistry journal, January 2020

Liquid crystalline epoxy monomer and liquid crystalline epoxy resin containing mesogen twins patent, September 1998

Photo-responsive thiol–ene networks for the design of switchable polymer patterns journal, January 2017

Process for producing three-dimensionally crosslinked polyester having the liquid crystal structure patent, December 1987

Production of crosslinked polymer layers having nonlinear optical properties and their use patent, February 1995

Microelectronic device having liquid crystalline epoxy resins patent, September 2010

3D printable liquid crystalline elastomers with tunable shape memory behavior and bio-derived renditions patent, September 2019

Functionalized Polymers Using Protected Thiols patent-application, July 2009

Stimuli-responsive liquid crystalline networks
patent, April 2019

Liquid crystalline networks based on photo-initiated thiol–ene click chemistry
journal, January 2020

Liquid crystalline epoxy monomer and liquid crystalline epoxy resin containing mesogen twins
patent, September 1998

Photo-responsive thiol–ene networks for the design of switchable polymer patterns
journal, January 2017

Process for producing three-dimensionally crosslinked polyester having the liquid crystal structure
patent, December 1987

Production of crosslinked polymer layers having nonlinear optical properties and their use
patent, February 1995

Microelectronic device having liquid crystalline epoxy resins
patent, September 2010

3D printable liquid crystalline elastomers with tunable shape memory behavior and bio-derived renditions
patent, September 2019

Functionalized Polymers Using Protected Thiols
patent-application, July 2009