Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes

Tsai, Hsinhan; Nie, Wanyi

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Title: Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes

Abstract

A radiation detector includes a p-i-n architecture including a p-type contact layer, an n-type contact layer, and an intrinsic layer between the p-type contact layer and the n-type contact layer. The intrinsic layer includes a thin film comprising a highly crystalline 2D layered perovskite material. The radiation detectors according to embodiments of the present disclosure generate high open circuit voltages, have good detecting photon density limits and high sensitivities, and can be self-powered.

Inventors:: Tsai, Hsinhan; Nie, Wanyi

Issue Date:: 2023-06-20

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1998510

Patent Number(s):: 11681059

Application Number:: 17/489,645

Assignee:: Triad National Security, LLC (Los Alamos, NM)

DOE Contract Number:: 89233218CNA000001

Resource Type:: Patent

Resource Relation:: Patent File Date: 09/29/2021

Country of Publication:: United States

Language:: English

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                    Tsai, Hsinhan, and Nie, Wanyi. Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes.  United States: N. p., 2023. 
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                    Tsai, Hsinhan, & Nie, Wanyi. Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes.  United States.

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                    Tsai, Hsinhan, and Nie, Wanyi. Tue .  
        "Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes".  United States.  https://www.osti.gov/servlets/purl/1998510.

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@article{osti_1998510,

  title        = {Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes},

  author       = {Tsai, Hsinhan and Nie, Wanyi},

  abstractNote = {A radiation detector includes a p-i-n architecture including a p-type contact layer, an n-type contact layer, and an intrinsic layer between the p-type contact layer and the n-type contact layer. The intrinsic layer includes a thin film comprising a highly crystalline 2D layered perovskite material. The radiation detectors according to embodiments of the present disclosure generate high open circuit voltages, have good detecting photon density limits and high sensitivities, and can be self-powered.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2023},

  month        = {6}

}

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Large angle solid state position sensitive x-ray detector system

Patent Kurtz, David S [State College, PA]; Ruud, Clay O [State College, PA]

A method and apparatus for x-ray measurement of certain properties of a solid material. In distinction to known methods and apparatus, this invention employs a specific fiber-optic bundle configuration, termed a reorganizer, itself known for other uses, for coherently transmitting visible light originating from the scintillation of diffracted x-radiation from the solid material gathered along a substantially one dimensional linear arc, to a two-dimensional photo-sensor array. The two-dimensional photodetector array, with its many closely packed light sensitive pixels, is employed to process the information contained in the diffracted radiation and present the information in the form of a conventional x-raymore » « less
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Title: Sensitive and robust thin film X-ray detector using 2D layered perovskite diodes

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X-ray imaging detectors for synchrotron and XFEL sources journal, April 2015

Perceived X-ray image quality for baggage screening conference, October 2015

High-Performance Planar-Type Photodetector on (100) Facet of MAPbI3 Single Crystal journal, November 2015

The emergence of perovskite solar cells journal, July 2014

Determination of X-ray flux using silicon pin diodes journal, February 2009

New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH 2 ) 3 )(CH 3 NH 3 ) n Pb n I 3 n +1 : Structure, Properties, and Photovoltaic Performance journal, November 2017

Direct Observation of Halide Migration and its Effect on the Photoluminescence of Methylammonium Lead Bromide Perovskite Single Crystals journal, September 2017

Role of the Metal–Semiconductor Interface in Halide Perovskite Devices for Radiation Photon Counting journal, September 2020

Two-dimensional Ruddlesden–Popper layered perovskite solar cells based on phase-pure thin films journal, November 2020

High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells journal, July 2016

Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells journal, May 2018

Solid-state, flat-panel, digital radiography detectors and their physical imaging characteristics journal, May 2008

Stable silicon photodiodes for absolute intensity measurements in the VUV and soft X-ray regions journal, May 1996

Contactless determination of current–voltage characteristics and minority‐carrier lifetimes in semiconductors from quasi‐steady‐state photoconductance data journal, October 1996

Optimizing Composition and Morphology for Large-Grain Perovskite Solar Cells via Chemical Control journal, August 2015

Halide perovskites: A dark horse for direct X‐ray imaging journal, November 2020

The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source journal, June 2012

Bandgap Dependence and Related Features of Radiation Ionization Energies in Semiconductors journal, March 1968

In Situ Grazing‐Incidence Wide‐Angle Scattering Reveals Mechanisms for Phase Distribution and Disorientation in 2D Halide Perovskite Films journal, July 2020

A sensitive and robust thin-film x-ray detector using 2D layered perovskite diodes journal, April 2020

High speed scintillation autoradiography journal, December 1975

Dimensional tailoring of hybrid perovskites for photovoltaics journal, November 2018

Crystallization Kinetics in 2D Perovskite Solar Cells journal, October 2020

Flexible Inkjet-Printed Triple Cation Perovskite X-ray Detectors journal, March 2020

Method for Single Crystal Growth of Photovoltaic Perovskite Material and Devices patent-application, August 2016

Open-Circuit Voltages Exceeding 1.26 V in Planar Methylammonium Lead Iodide Perovskite Solar Cells journal, December 2018

Materials for Gamma-Ray Spectrometers: Inorganic Scintillators journal, July 2018

Capacitance measurements of p-n junctions: depletion layer and diffusion capacitance contributions journal, March 1993

GIXSGUI : a MATLAB toolbox for grazing-incidence X-ray scattering data visualization and reduction, and indexing of buried three-dimensional periodic nanostructured films journal, April 2015

X-ray detectors for digital radiography journal, January 1997

Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites journal, March 2017

Review of medical imaging with emphasis on X-ray detectors journal, July 2006

Light intensity dependence of open-circuit voltage of polymer:fullerene solar cells journal, March 2005

Light-induced lattice expansion leads to high-efficiency perovskite solar cells journal, April 2018

Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit journal, October 2017

Monolithic integration of hybrid perovskite single crystals with heterogenous substrate for highly sensitive X-ray imaging journal, April 2017

Rapid and Complete Conversion of CH3NH3PbI3 for Perovskite/C60 Planar‐Heterojunction Solar Cells by Two‐Step Deposition journal, February 2017

A review of X-ray explosives detection techniques for checked baggage journal, August 2012

Printable organometallic perovskite enables large-area, low-dose X-ray imaging journal, October 2017

Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors journal, April 2016

X-ray Detector Development at the Swiss Light Source journal, July 2014

Admittance spectroscopy of thin film solar cells journal, August 2005

2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications journal, June 2015

Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden-Popper Layered Perovskites journal, January 2018

High-efficiency and durable optoelectronic devices using layered 2D perovskites patent, September 2020

High-performance direct conversion X-ray detectors based on sintered hybrid lead triiodide perovskite wafers journal, June 2017

Automated X-Ray Object Recognition Using an Efficient Search Algorithm in Multiple Views conference, June 2013

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains journal, January 2015

Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals journal, March 2016

Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells journal, September 2017

Detection of X-ray photons by solution-processed lead halide perovskites journal, May 2015

Designing Ultraflexible Perovskite X‐Ray Detectors through Interface Engineering journal, November 2020

Determination of defect distributions from admittance measurements and application to Cu(In,Ga)Se 2 based heterojunctions journal, October 1996

Giant switchable photovoltaic effect in organometal trihalide perovskite devices journal, December 2014

Critical Role of Interface and Crystallinity on the Performance and Photostability of Perovskite Solar Cell on Nickel Oxide journal, December 2017

PIN Diode Detectors conference, January 2008

Transient current analysis of a GaN radiation detector by TCAD journal, October 2014

Thin-film solar cells: device measurements and analysis journal, March 2004

Direct-conversion flat-panel X-ray image sensors for digital radiography journal, April 2002

Solution‐Grown Organic and Perovskite X‐Ray Detectors: A New Paradigm for the Direct Detection of Ionizing Radiation journal, August 2020

CMOS Imaging Detectors as X-ray Detectors for Synchrotron Radiation Experiments conference, January 2004

X-ray imaging detectors for synchrotron and XFEL sources
journal, April 2015

Perceived X-ray image quality for baggage screening
conference, October 2015

High-Performance Planar-Type Photodetector on (100) Facet of MAPbI3 Single Crystal
journal, November 2015

The emergence of perovskite solar cells
journal, July 2014

Determination of X-ray flux using silicon pin diodes
journal, February 2009

New Type of 2D Perovskites with Alternating Cations in the Interlayer Space, (C(NH ₂ ) ₃ )(CH ₃ NH ₃ ) _n Pb _n I _{3 n +1} : Structure, Properties, and Photovoltaic Performance
journal, November 2017

Direct Observation of Halide Migration and its Effect on the Photoluminescence of Methylammonium Lead Bromide Perovskite Single Crystals
journal, September 2017

Role of the Metal–Semiconductor Interface in Halide Perovskite Devices for Radiation Photon Counting
journal, September 2020

Two-dimensional Ruddlesden–Popper layered perovskite solar cells based on phase-pure thin films
journal, November 2020

High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
journal, July 2016

Design principles for electronic charge transport in solution-processed vertically stacked 2D perovskite quantum wells
journal, May 2018

Solid-state, flat-panel, digital radiography detectors and their physical imaging characteristics
journal, May 2008

Stable silicon photodiodes for absolute intensity measurements in the VUV and soft X-ray regions
journal, May 1996

Contactless determination of current–voltage characteristics and minority‐carrier lifetimes in semiconductors from quasi‐steady‐state photoconductance data
journal, October 1996

Optimizing Composition and Morphology for Large-Grain Perovskite Solar Cells via Chemical Control
journal, August 2015

Halide perovskites: A dark horse for direct X‐ray imaging
journal, November 2020

The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source
journal, June 2012

Bandgap Dependence and Related Features of Radiation Ionization Energies in Semiconductors
journal, March 1968

In Situ Grazing‐Incidence Wide‐Angle Scattering Reveals Mechanisms for Phase Distribution and Disorientation in 2D Halide Perovskite Films
journal, July 2020

A sensitive and robust thin-film x-ray detector using 2D layered perovskite diodes
journal, April 2020

High speed scintillation autoradiography
journal, December 1975

Dimensional tailoring of hybrid perovskites for photovoltaics
journal, November 2018

Crystallization Kinetics in 2D Perovskite Solar Cells
journal, October 2020

Flexible Inkjet-Printed Triple Cation Perovskite X-ray Detectors
journal, March 2020

Method for Single Crystal Growth of Photovoltaic Perovskite Material and Devices
patent-application, August 2016

Open-Circuit Voltages Exceeding 1.26 V in Planar Methylammonium Lead Iodide Perovskite Solar Cells
journal, December 2018

Materials for Gamma-Ray Spectrometers: Inorganic Scintillators
journal, July 2018

Capacitance measurements of p-n junctions: depletion layer and diffusion capacitance contributions
journal, March 1993

GIXSGUI : a MATLAB toolbox for grazing-incidence X-ray scattering data visualization and reduction, and indexing of buried three-dimensional periodic nanostructured films
journal, April 2015

X-ray detectors for digital radiography
journal, January 1997

Extremely efficient internal exciton dissociation through edge states in layered 2D perovskites
journal, March 2017

Review of medical imaging with emphasis on X-ray detectors
journal, July 2006

Light intensity dependence of open-circuit voltage of polymer:fullerene solar cells
journal, March 2005

Light-induced lattice expansion leads to high-efficiency perovskite solar cells
journal, April 2018

Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit
journal, October 2017

Monolithic integration of hybrid perovskite single crystals with heterogenous substrate for highly sensitive X-ray imaging
journal, April 2017

Rapid and Complete Conversion of CH₃NH₃PbI₃ for Perovskite/C₆₀ Planar‐Heterojunction Solar Cells by Two‐Step Deposition
journal, February 2017

A review of X-ray explosives detection techniques for checked baggage
journal, August 2012

Printable organometallic perovskite enables large-area, low-dose X-ray imaging
journal, October 2017

Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
journal, April 2016

X-ray Detector Development at the Swiss Light Source
journal, July 2014

Admittance spectroscopy of thin film solar cells
journal, August 2005

2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
journal, June 2015

Stable Light-Emitting Diodes Using Phase-Pure Ruddlesden-Popper Layered Perovskites
journal, January 2018

High-efficiency and durable optoelectronic devices using layered 2D perovskites
patent, September 2020

High-performance direct conversion X-ray detectors based on sintered hybrid lead triiodide perovskite wafers
journal, June 2017

Automated X-Ray Object Recognition Using an Efficient Search Algorithm in Multiple Views
conference, June 2013

High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015

Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals
journal, March 2016

Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells
journal, September 2017

Detection of X-ray photons by solution-processed lead halide perovskites
journal, May 2015

Designing Ultraflexible Perovskite X‐Ray Detectors through Interface Engineering
journal, November 2020

Determination of defect distributions from admittance measurements and application to Cu(In,Ga)Se ₂ based heterojunctions
journal, October 1996

Giant switchable photovoltaic effect in organometal trihalide perovskite devices
journal, December 2014

Critical Role of Interface and Crystallinity on the Performance and Photostability of Perovskite Solar Cell on Nickel Oxide
journal, December 2017

PIN Diode Detectors
conference, January 2008

Transient current analysis of a GaN radiation detector by TCAD
journal, October 2014

Thin-film solar cells: device measurements and analysis
journal, March 2004

Direct-conversion flat-panel X-ray image sensors for digital radiography
journal, April 2002

Solution‐Grown Organic and Perovskite X‐Ray Detectors: A New Paradigm for the Direct Detection of Ionizing Radiation
journal, August 2020

CMOS Imaging Detectors as X-ray Detectors for Synchrotron Radiation Experiments
conference, January 2004