Lead-lead oxide-carbon nanocomposite for energy storage cells and method of preparation
Abstract
Lead/lead oxide/carbon (“Pb—O—C”) nanocomposite materials are useful as electrode active materials for electrodes in lithium and sodium batteries. A Pb—O—C nanocomposite as described herein comprises Pb and lead oxide nanoparticles homogeneously dispersed in a carbon nanoparticle matrix. In the nanocomposite, the other element or elements (e.g., transition metals, Al, Si, P, Sn, Sb, and Bi) can be alloyed with the Pb nanoparticles, incorporated as a mixed oxide with the lead oxide nanoparticles, or can be present as distinct elemental or oxide nanoparticles within the carbon nanoparticle matrix. In some embodiments, the additional element or elements are present as alloys and mixed oxides with the Pb materials and as distinct elemental and/or oxide nanoparticles. In a preferred embodiment the Pb nanoparticles surface is oxidized to lead oxide thus creating a shell on core nanostructure.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1987241
- Patent Number(s):
- 11611069
- Application Number:
- 16/853,988
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 04/21/2020
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Johnson, Christopher S., Lee, Eungje, Han, Jinhyup, and Park, Jehee. Lead-lead oxide-carbon nanocomposite for energy storage cells and method of preparation. United States: N. p., 2023.
Web.
Johnson, Christopher S., Lee, Eungje, Han, Jinhyup, & Park, Jehee. Lead-lead oxide-carbon nanocomposite for energy storage cells and method of preparation. United States.
Johnson, Christopher S., Lee, Eungje, Han, Jinhyup, and Park, Jehee. Tue .
"Lead-lead oxide-carbon nanocomposite for energy storage cells and method of preparation". United States. https://www.osti.gov/servlets/purl/1987241.
@article{osti_1987241,
title = {Lead-lead oxide-carbon nanocomposite for energy storage cells and method of preparation},
author = {Johnson, Christopher S. and Lee, Eungje and Han, Jinhyup and Park, Jehee},
abstractNote = {Lead/lead oxide/carbon (“Pb—O—C”) nanocomposite materials are useful as electrode active materials for electrodes in lithium and sodium batteries. A Pb—O—C nanocomposite as described herein comprises Pb and lead oxide nanoparticles homogeneously dispersed in a carbon nanoparticle matrix. In the nanocomposite, the other element or elements (e.g., transition metals, Al, Si, P, Sn, Sb, and Bi) can be alloyed with the Pb nanoparticles, incorporated as a mixed oxide with the lead oxide nanoparticles, or can be present as distinct elemental or oxide nanoparticles within the carbon nanoparticle matrix. In some embodiments, the additional element or elements are present as alloys and mixed oxides with the Pb materials and as distinct elemental and/or oxide nanoparticles. In a preferred embodiment the Pb nanoparticles surface is oxidized to lead oxide thus creating a shell on core nanostructure.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2023},
month = {3}
}
Works referenced in this record:
Mechanical Milling: a Top Down Approach for the Synthesis of Nanomaterials and Nanocomposites
journal, August 2012
- Prasad Yadav, Thakur; Manohar Yadav, Ram; Pratap Singh, Dinesh
- Nanoscience and Nanotechnology, Vol. 2, Issue 3
Application of Operando X-ray Diffraction and Raman Spectroscopies in Elucidating the Behavior of Cathode in Lithium-Ion Batteries
journal, July 2018
- Zhu, Wen; Liu, Dongqiang; Paolella, Andrea
- Frontiers in Energy Research, Vol. 6
Planetary Ball Mill Process in Aspect of Milling Energy
journal, April 2014
- Kho, Huynh Xuan; Bae, Sunwoo; Bae, Sangwon
- Journal of Korean Powder Metallurgy Institute, Vol. 21, Issue 2
Ordered‐Mesoporous‐Carbon‐Confined Pb/PbO Composites: Superior Electrocatalysts for CO
2
Reduction
journal, April 2020
- Huang, Xin; Song, Jinliang; Wu, Haoran
- ChemSusChem
A Low-Concentration Hydrothermal Synthesis of Biocompatible Ordered Mesoporous Carbon Nanospheres with Tunable and Uniform Size
journal, September 2010
- Fang, Yin; Gu, Dong; Zou, Ying
- Angewandte Chemie International Edition, Vol. 49, Issue 43
In Situ XRD Study of Silicon, Lead and Bismuth Negative Electrodes in Nonaqueous Sodium Cells
journal, December 2013
- Ellis, L. D.; Wilkes, B. N.; Hatchard, T. D.
- Journal of The Electrochemical Society, Vol. 161, Issue 3
Enabling High-Energy, High-Voltage Lithium-Ion Cells: Standardization of Coin-Cell Assembly, Electrochemical Testing, and Evaluation of Full Cells
journal, January 2016
- Long, Brandon R.; Rinaldo, Steven G.; Gallagher, Kevin G.
- Journal of The Electrochemical Society, Vol. 163, Issue 14
Negative active material for lithium secondary battery, method for preparing the same, negative electrode comprising the same, and lithium secondary battery comprising same
patent, April 2015
- Lee, Sung-Man; Lee, Jong-Hyuk
- US Patent Document 8,999,581
Botryoidal Pb/PbO@C nanocomposite derived from eggplant biomass as negative electrode additives for long-cyclability lead-acid batteries
journal, January 2021
- Gao, Yunfang; Guan, Li; Fu, Hanli
- Materials Chemistry and Physics, Vol. 257
Synthesis of Nanostructured PbO@C Composite Derived from Spent Lead-Acid Battery for Next-Generation Lead-Carbon Battery
journal, January 2018
- Hu, Yuchen; Yang, Jiakuan; Hu, Jingping
- Advanced Functional Materials, Vol. 28, Issue 9
Lead-based systems as suitable anode materials for Li-ion batteries
journal, February 2003
- Martos, M.
- Electrochimica Acta, Vol. 48, Issue 6
Alloy Negative Electrodes for Li-Ion Batteries
journal, October 2014
- Obrovac, M. N.; Chevrier, V. L.
- Chemical Reviews, Vol. 114, Issue 23
A facile route for PbO@C nanocomposites: An electrode candidate for lead-acid batteries with enhanced capacitance
journal, February 2013
- Wang, Huiqi; Yu, Jianguo; Zhao, Yongnan
- Journal of Power Sources, Vol. 224
Electrolytes for Lithium and Lithium-Ion Batteries
book, January 2014
- Jow, T. Richard; Xu, Kang; Borodin, Oleg
- Modern Aspects of Electrochemistry