Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries

Title: Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries

Abstract

A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li.sub.1+xNi.sub..alpha.Co.sub..beta.Mn.sub..gamma.M'.sub..delta.O.sub.yF- .sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the .alpha. between 0 and 1, the .beta. between 0 and 1, the .gamma. between 0 and 2, the .delta. between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.

Inventors:

Kang, Sun-Ho ^[1]; Amine, Khalil ^[2]

Naperville, IL
Downers Grove, IL

Issue Date:: 2008-10-14

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 985399

Patent Number(s):: 7435402

Application Number:: 10/903,514

Assignee:: U Chicago Argonne LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/1315 - containing halogen atoms, e.g. LiCoOxFy

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2006/40 - Electric properties
C01P2004/84 - one phase coated with the other
C01P2004/61 - Micrometer sized, i.e. from 1-100 micrometer
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/32 - Spheres
C01P2004/03 - obtained by SEM

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G45/1228 - {of the type [MnO2]n- , e.g. LiMnO2, Li[MxMn1-x]O2}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/54 - one element only

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/366 - {as layered products}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G53/50 - {of the type [MnO2]n- , e.g. Li

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/582 - {Halogenides}
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G51/50 - {of the type [MnO2]n- , e.g. Li

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2004/51 - Particles with a specific particle size distribution
C01P2002/76 - by a space-group or by other symmetry indications

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M10/052 - Li-accumulators

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: W-31-109-ENG-38

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Kang, Sun-Ho, and Amine, Khalil. Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries.  United States: N. p., 2008. 
        Web.

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                    Kang, Sun-Ho, & Amine, Khalil. Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries.  United States.

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                    Kang, Sun-Ho, and Amine, Khalil. Tue .  
        "Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries".  United States.  https://www.osti.gov/servlets/purl/985399.

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@article{osti_985399,

  title        = {Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries},

  author       = {Kang, Sun-Ho and Amine, Khalil},

  abstractNote = {A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li.sub.1+xNi.sub..alpha.Co.sub..beta.Mn.sub..gamma.M'.sub..delta.O.sub.yF- .sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the .alpha. between 0 and 1, the .beta. between 0 and 1, the .gamma. between 0 and 2, the .delta. between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2008},

  month        = {10}

}

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Works referenced in this record:

Layered Lithium Insertion Material of LiNi _1/2 Mn _1/2 O ₂ : A Possible Alternative to LiCoO ₂ for Advanced Lithium-Ion Batteries
journal, August 2001

Ohzuku, Tsutomu; Makimura, Yoshinari
Chemistry Letters, Vol. 30, Issue 8
https://doi.org/10.1246/cl.2001.744

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
journal, January 2001

Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R.
Electrochemical and Solid-State Letters, Vol. 4, Issue 11
https://doi.org/10.1149/1.1407994

Understanding the Anomalous Capacity of Li / Li [ Ni_xLi _{( 1 / 3 − 2x / 3 )} Mn_{( 2 / 3 − x / 3 )} ] O₂ Cells Using In Situ X-Ray Diffraction and Electrochemical Studies
journal, January 2002

Lu, Zhonghua; Dahn, J. R.
Journal of The Electrochemical Society, Vol. 149, Issue 7, p. A815-A822
https://doi.org/10.1149/1.1480014

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Title: Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries

Abstract

Citation Formats

Layered Lithium Insertion Material of LiNi 1/2 Mn 1/2 O 2 : A Possible Alternative to LiCoO 2 for Advanced Lithium-Ion Batteries journal, August 2001

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries journal, January 2001

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Layered Lithium Insertion Material of LiNi _1/2 Mn _1/2 O ₂ : A Possible Alternative to LiCoO ₂ for Advanced Lithium-Ion Batteries
journal, August 2001

Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries
journal, January 2001

Understanding the Anomalous Capacity of Li / Li [ Ni_xLi _{( 1 / 3 − 2x / 3 )} Mn_{( 2 / 3 − x / 3 )} ] O₂ Cells Using In Situ X-Ray Diffraction and Electrochemical Studies
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