Low power sensor for NOx detection
Abstract
Detection and capture of toxic nitrogen oxides (NOx) is important for emissions control of exhaust gases and general public health. The low power sensor provides direct electrically detection of trace (0.5-5 ppm) NO2 at relatively low temperatures (50° C.) via changes in the electrical properties of nitrogen-oxide-capture active materials. For example, the high impedance of MOF-74 enables applications requiring a near-zero power sensor or dosimeter, such as for smart industrial systems and the internet of things, with 0.8 mg MOF-74 active material drawing <15 pW for a macroscale sensor 35 mm2 area.
- Inventors:
- Issue Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1987105
- Patent Number(s):
- 11573217
- Application Number:
- 17/173,333
- Assignee:
- National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
- DOE Contract Number:
- NA0003525
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 02/11/2021
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Small, Leo J., Henkelis, Susan Elizabeth, Percival, Stephen J., Nenoff, Tina M., and Schindelholz, Mara Elizabeth. Low power sensor for NOx detection. United States: N. p., 2023.
Web.
Small, Leo J., Henkelis, Susan Elizabeth, Percival, Stephen J., Nenoff, Tina M., & Schindelholz, Mara Elizabeth. Low power sensor for NOx detection. United States.
Small, Leo J., Henkelis, Susan Elizabeth, Percival, Stephen J., Nenoff, Tina M., and Schindelholz, Mara Elizabeth. Tue .
"Low power sensor for NOx detection". United States. https://www.osti.gov/servlets/purl/1987105.
@article{osti_1987105,
title = {Low power sensor for NOx detection},
author = {Small, Leo J. and Henkelis, Susan Elizabeth and Percival, Stephen J. and Nenoff, Tina M. and Schindelholz, Mara Elizabeth},
abstractNote = {Detection and capture of toxic nitrogen oxides (NOx) is important for emissions control of exhaust gases and general public health. The low power sensor provides direct electrically detection of trace (0.5-5 ppm) NO2 at relatively low temperatures (50° C.) via changes in the electrical properties of nitrogen-oxide-capture active materials. For example, the high impedance of MOF-74 enables applications requiring a near-zero power sensor or dosimeter, such as for smart industrial systems and the internet of things, with 0.8 mg MOF-74 active material drawing <15 pW for a macroscale sensor 35 mm2 area.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 07 00:00:00 EST 2023},
month = {Tue Feb 07 00:00:00 EST 2023}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
NO x Adsorption and Optical Detection in Rare Earth Metal–Organic Frameworks
journal, October 2019
- Sava Gallis, Dorina F.; Vogel, Dayton J.; Vincent, Grace A.
- ACS Applied Materials & Interfaces, Vol. 11, Issue 46
Chemical gradients in automotive Cu-SSZ-13 catalysts for NOx removal revealed by operando X-ray spectrotomography
journal, December 2020
- Becher, Johannes; Sanchez, Dario Ferreira; Doronkin, Dmitry E.
- Nature Catalysis, Vol. 4, Issue 1
Structural and electronic properties of M-MOF-74 (M = Mg, Co or Mn)
journal, January 2018
- de Oliveira, Aline; de Lima, Guilherme Ferreira; De Abreu, Heitor Avelino
- Chemical Physics Letters, Vol. 691
Is iron unique in promoting electrical conductivity in MOFs?
journal, January 2017
- Sun, Lei; Hendon, Christopher H.; Park, Sarah S.
- Chemical Science, Vol. 8, Issue 6
Selective decontamination of the reactive air pollutant nitrous acid via node-linker cooperativity in a metal–organic framework
journal, January 2019
- McGrath, Devon T.; Ryan, Michaela D.; MacInnis, John J.
- Chemical Science, Vol. 10, Issue 21
Reversible MOF-Based Sensors for the Electrical Detection of Iodine Gas
journal, July 2019
- Small, Leo J.; Hill, Ryan C.; Krumhansl, James L.
- ACS Applied Materials & Interfaces, Vol. 11, Issue 31
Interaction of Acid Gases SO 2 and NO 2 with Coordinatively Unsaturated Metal Organic Frameworks: M-MOF-74 (M = Zn, Mg, Ni, Co)
journal, May 2017
- Tan, Kui; Zuluaga, Sebastian; Wang, Hao
- Chemistry of Materials, Vol. 29, Issue 10
Functional metal–organic frameworks as effective sensors of gases and volatile compounds
journal, January 2020
- Li, Hai-Yang; Zhao, Shu-Na; Zang, Shuang-Quan
- Chemical Society Reviews, Vol. 49, Issue 17
Reversible adsorption of nitrogen dioxide within a robust porous metal–organic framework
journal, June 2018
- Han, Xue; Godfrey, Harry G. W.; Briggs, Lydia
- Nature Materials, Vol. 17, Issue 8
Solvothermal growth of Mg-MOF-74 films on carboxylic functionalized silicon substrate using acrylic acid
journal, February 2021
- Lee, Chang Taek; Shin, Moo Whan
- Surfaces and Interfaces, Vol. 22
Interactions of NO 2 with Zr-Based MOF: Effects of the Size of Organic Linkers on NO 2 Adsorption at Ambient Conditions
journal, December 2012
- Ebrahim, Amani M.; Levasseur, Benoit; Bandosz, Teresa J.
- Langmuir, Vol. 29, Issue 1
A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release
journal, January 2019
- Henkelis, Susan E.; Vornholt, Simon M.; Cordes, David B.
- CrystEngComm, Vol. 21, Issue 12
Capture of nitrogen dioxide and conversion to nitric acid in a porous metal–organic framework
journal, November 2019
- Li, Jiangnan; Han, Xue; Zhang, Xinran
- Nature Chemistry, Vol. 11, Issue 12
Excellent activity and selectivity of Cu-SSZ-13 in the selective catalytic reduction of NOx with NH3
journal, October 2010
- Kwak, Ja Hun; Tonkyn, Russell G.; Kim, Do Heui
- Journal of Catalysis, Vol. 275, Issue 2
Direct Electrical Detection of Iodine Gas by a Novel Metal–Organic-Framework-Based Sensor
journal, December 2017
- Small, Leo J.; Nenoff, Tina M.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 51
Picowatt gas sensing and resistance switching in tunneling nano-gap electrodes
conference, October 2016
- Banerjee, A.; Farhoudi, N.; Ghosh, C.
- 2016 IEEE SENSORS
Structural, elastic, thermal, and electronic responses of small-molecule-loaded metal–organic framework materials
journal, January 2015
- Canepa, Pieremanuele; Tan, Kui; Du, Yingjie
- Journal of Materials Chemistry A, Vol. 3, Issue 3
Manganese-rich MnSAPO-34 molecular sieves as an efficient catalyst for the selective catalytic reduction of NO x with NH3: one-pot synthesis, catalytic performance, and characterization
journal, January 2017
- Yu, Chenglong; Chen, Feng; Dong, Lifu
- Environmental Science and Pollution Research, Vol. 24, Issue 8
Competitive Coadsorption of CO 2 with H 2 O, NH 3 , SO 2 , NO, NO 2 , N 2 , O 2 , and CH 4 in M-MOF-74 (M = Mg, Co, Ni): The Role of Hydrogen Bonding
journal, March 2015
- Tan, Kui; Zuluaga, Sebastian; Gong, Qihan
- Chemistry of Materials, Vol. 27, Issue 6
MOF thin films: existing and future applications
journal, January 2011
- Shekhah, O.; Liu, J.; Fischer, R. A.
- Chemical Society Reviews, Vol. 40, Issue 2
Metal–Organic Framework Materials as Chemical Sensors
journal, September 2011
- Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K.
- Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125
Gradual Release of Strongly Bound Nitric Oxide from Fe 2 (NO) 2 (dobdc)
journal, March 2015
- Bloch, Eric D.; Queen, Wendy L.; Chavan, Sachin
- Journal of the American Chemical Society, Vol. 137, Issue 10
Exceptional Behavior over the Whole Adsorption−Storage−Delivery Cycle for NO in Porous Metal Organic Frameworks
journal, August 2008
- McKinlay, Alistair C.; Xiao, Bo; Wragg, David S.
- Journal of the American Chemical Society, Vol. 130, Issue 31
Metal–organic framework growth at functional interfaces: thin films and composites for diverse applications
journal, January 2012
- Bradshaw, Darren; Garai, Ashesh; Huo, Jia
- Chem. Soc. Rev., Vol. 41, Issue 6
Field Effect Transistor Gas Sensor Having a Housing and Porous Catalytic Material Contained Therein
patent-application, June 2010
- Fix, Richard; Widenmeyer, Markus; Martin, Alexander
- US Patent Application 12/733141; 20100139365
A Calixarene-Based Metal-Organic Framework for Highly Selective NO 2 Detection
journal, August 2018
- Schulz, Marcel; Gehl, Adrian; Schlenkrich, Jakob
- Angewandte Chemie International Edition, Vol. 57, Issue 39