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Title: Dyes, dye-sensitized solar cells, and methods of making and using the same

Abstract

Provided herein are dyes, dye-sensitized solar cells, and sequential series multijunction dye-sensitized solar cell devices. The dyes include an electron deficient acceptor moiety, a medium electron density π-bridge moiety, and an electron rich donor moiety comprising a biaryl, a substituted biaryl, or an R1, R2, R3 substituted phenyl where each of R1, R2, and R3 independently comprises H, aryl, multiaryl, alkyl substituted aryl, alkoxy substituted aryl, alkyl substituted multiaryl, alkoxy substituted multiaryl, OR4, N(R5)2, or a combination thereof; each R4 independently comprises H, alkyl, aryl, alkyl substituted aryl, alkoxy substituted aryl, or a combination thereof; and each R5 independently comprises aryl, multiaryl, alkyl substituted aryl, alkoxy substituted aryl, alkyl substituted multiaryl, alkoxy substituted multiaryl, or a combination thereof. The solar cells include a glass substrate, a dye-sensitized active layer, and a redox shuttle. The devices include at least two dye-sensitized solar cells connected in series.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Univ. of Mississippi, University, MS (United States)
Sponsoring Org.:
USDOE; National Science Foundation (NSF)
OSTI Identifier:
1925013
Patent Number(s):
11421110
Application Number:
16/779,569
Assignee:
University of Mississippi (University, MS)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C - CHEMISTRY C09 - DYES C09B - ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES {, e.g. PIGMENTS},
DOE Contract Number:  
1455167; 1539035; SC0019131
Resource Type:
Patent
Resource Relation:
Patent File Date: 01/31/2020
Country of Publication:
United States
Language:
English

Citation Formats

Delcamp, Jared Heath, Rodrigues, Roberta Ramalho, Peddapuram, Adithya, Cheema, Hammad Arshad, and Curiae, Christine. Dyes, dye-sensitized solar cells, and methods of making and using the same. United States: N. p., 2022. Web.
Delcamp, Jared Heath, Rodrigues, Roberta Ramalho, Peddapuram, Adithya, Cheema, Hammad Arshad, & Curiae, Christine. Dyes, dye-sensitized solar cells, and methods of making and using the same. United States.
Delcamp, Jared Heath, Rodrigues, Roberta Ramalho, Peddapuram, Adithya, Cheema, Hammad Arshad, and Curiae, Christine. Tue . "Dyes, dye-sensitized solar cells, and methods of making and using the same". United States. https://www.osti.gov/servlets/purl/1925013.
@article{osti_1925013,
title = {Dyes, dye-sensitized solar cells, and methods of making and using the same},
author = {Delcamp, Jared Heath and Rodrigues, Roberta Ramalho and Peddapuram, Adithya and Cheema, Hammad Arshad and Curiae, Christine},
abstractNote = {Provided herein are dyes, dye-sensitized solar cells, and sequential series multijunction dye-sensitized solar cell devices. The dyes include an electron deficient acceptor moiety, a medium electron density π-bridge moiety, and an electron rich donor moiety comprising a biaryl, a substituted biaryl, or an R1, R2, R3 substituted phenyl where each of R1, R2, and R3 independently comprises H, aryl, multiaryl, alkyl substituted aryl, alkoxy substituted aryl, alkyl substituted multiaryl, alkoxy substituted multiaryl, OR4, N(R5)2, or a combination thereof; each R4 independently comprises H, alkyl, aryl, alkyl substituted aryl, alkoxy substituted aryl, or a combination thereof; and each R5 independently comprises aryl, multiaryl, alkyl substituted aryl, alkoxy substituted aryl, alkyl substituted multiaryl, alkoxy substituted multiaryl, or a combination thereof. The solar cells include a glass substrate, a dye-sensitized active layer, and a redox shuttle. The devices include at least two dye-sensitized solar cells connected in series.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 23 00:00:00 EDT 2022},
month = {Tue Aug 23 00:00:00 EDT 2022}
}

Works referenced in this record:

A cobalt complex redox shuttle for dye-sensitized solar cells with high open-circuit potentials
journal, January 2012


Organic dyes incorporating the oxadiazole moiety for efficient dye-sensitized solar cells
patent-application, November 2016


Indolizine-based dyes for dye-sensitized solar cell
patent, February 2020


First-Principle Determination of Electronic Coupling and Prediction of Charge Recombination Rates in Dye-Sensitized Solar Cells
journal, December 2016


Organic dyes containing fused acenes as building blocks: Optical, electrochemical and photovoltaic properties
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Compounds for electrochemical and/or optoelectronic devices
patent-application, August 2014


Organic D-A-π-A Solar Cell Sensitizers with Improved Stability and Spectral Response
journal, December 2010


First-Principle Characterization of the Adsorption Configurations of Cyanoacrylic Dyes on TiO2 Film for Dye-Sensitized Solar Cells
journal, October 2016