Cobalt-stabilized lithium metal oxide electrodes for lithium batteries
Abstract
An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi2MO3.(1−x)LiM′O2].(1−y)Li1+dMn2−z−dM″zO4; wherein 0≤x≤1; 0.75≤y<1; 0
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1735324
- Patent Number(s):
- 10790508
- Application Number:
- 16/020,403
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/27/2018
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, and Lee, Eungje. Cobalt-stabilized lithium metal oxide electrodes for lithium batteries. United States: N. p., 2020.
Web.
Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, & Lee, Eungje. Cobalt-stabilized lithium metal oxide electrodes for lithium batteries. United States.
Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, and Lee, Eungje. Tue .
"Cobalt-stabilized lithium metal oxide electrodes for lithium batteries". United States. https://www.osti.gov/servlets/purl/1735324.
@article{osti_1735324,
title = {Cobalt-stabilized lithium metal oxide electrodes for lithium batteries},
author = {Thackeray, Michael M. and Croy, Jason R. and Long, Brandon R. and Park, Joong Sun and Lee, Eungje},
abstractNote = {An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi2MO3.(1−x)LiM′O2].(1−y)Li1+dMn2−z−dM″zO4; wherein 0≤x≤1; 0.75≤y<1; 0},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {9}
}
Works referenced in this record:
Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014
- Long, Brandon R.; Croy, Jason R.; Park, Joong Sun
- Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167
Structural complexity of layered-spinel composite electrodes for Li-ion batteries
journal, August 2010
- Cabana, Jordi; Johnson, Christopher S.; Yang, Xiao-Qing
- Journal of Materials Research, Vol. 25, Issue 8, p. 1601-1616
High-Performance ZrO2-Coated LiNiO2 Cathode Material
journal, January 2001
- Cho, Jaephil; Kim, Tae-Joon; Kim, Yong Jeong
- Electrochemical and Solid-State Letters, Vol. 4, Issue 10, p. A159-A161
Positive-electrode active material for non-aqueous electrolyte secondary cell and process for preparing the same
patent-application, July 2005
- Oesten, Ruediger; Suzuki, Ryuta; Nitta, Katsuhisa
- US Patent Application 10/510334; 20050153206
Methods for producing lithium metal oxide particles
patent, November 2002
- Kumar, Sujeet; Reitz, Hariklia Dris; Horne, Craig R.
- US Patent Document 6,482,374
Electrode Structures and Surfaces For Li Batteries
patent-application, March 2013
- Thackeray, Michael M.; Kim, Donghan; Croy, Jason
- US Patent Application 13/680959; 20130078518
Surface and Bulk Modified High Capacity Layered Oxide Cathodes with Low Irreversible Capacity Loss
patent-application, September 2009
- Manthiram, Arumugam
- US Patent Application 11/861248; 20090224212
Manganese oxide composite electrodes for lithium batteries
patent, September 2010
- Johnson, Christopher S.; Kang, Sun-Ho; Thackeray, Michael M.
- US Patent Document 7,790,308
Surface/chemically modified oxide cathodes for lithium-ion batteries
patent-application, June 2003
- Manthiram, Arumugam; Kanman, Arunachala Nadar Mada
- US Patent Application 10/010858; 20030108790
Controlled Nanoparticle Metal Phosphates (Metal = Al , Fe, Ce, and Sr) Coatings on LiCoO2 Cathode Materials
journal, January 2005
- Kim, Jisuk; Noh, Mijung; Cho, Jaephil
- Journal of The Electrochemical Society, Vol. 152, Issue 6, p. A1142-A1148
Positive active material for rechargeable lithium batteries and method of preparing same
patent, January 2006
- Kweon, Ho-Jin; Suh, Jun-Won; Jung, Won-Il
- US Patent Document 6,984,469
Electrode Structures and Surfaces for Li Batteries
patent-application, October 2012
- Thackery, Michael M.; Kang, Sun-Ho; Balasubramanian, Mahalingam
- US Patent Application 13/440431; 20120263998
Positive active material for rechargeable lithium battery and method of preparing same
patent, November 2006
- Kweon, Ho-Jin; Suh, Joon-Won
- US Patent Document 7,138,209
Positive electrode active material for lithium battery, method for producing the same, and lithium battery containing the same
patent, November 1999
- Amine, Khalil; Yasuda, Hideo; Fujita, Yuko
- US Patent Document 5,981,106
Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994
- Gummow, R. J.; de Kock, A.; Thackeray, M. M.
- Solid State Ionics, Vol. 69, Issue 1, p. 59-67
Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries
journal, July 1992
- Gummow, R. J.; Thackeray, M. M.
- Solid State Ionics, Vol. 53-56, p. 681-687
Surface Modification of High Capacity Layered Li [ Li0.2Mn0.54Ni0.13Co0.13 ] O2 Cathodes by AlPO4
journal, January 2008
- Wu, Y.; Vadivel Murugan, A.; Manthiram, A.
- Journal of The Electrochemical Society, Vol. 155, Issue 9, p. A635-A641
Microwave-Assisted Synthesis of High-Voltage Nanostructured LiMn1.5Ni0.5O4 Spinel: Tuning the Mn3+ Content and Electrochemical Performance
journal, July 2013
- Jafta, Charl J.; Mathe, Mkhulu K.; Manyala, Ncholu
- ACS Applied Materials & Interfaces, Vol. 5, Issue 15, p. 7592-7598
Effect of a ZrO2 Coating on the Structure and Electrochemistry of LixCoO2 When Cycled to 4.5 V
journal, January 2002
- Chen, Zhaohui; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 5, Issue 10, p. A213-A216
Coated lithium mixed oxide particles and a process for producing them
patent-application, November 2001
- Oesten, Ruediger; Li, Bangyin; Nakamura, Nobuaki
- US Patent Application 09/816663; 20010046628
Synthesis and Characterization of Carbon-Coated Lithium Transition Metal Phosphates LiMPO4 (M = Fe , Mn, Co, Ni) Prepared via a Nonaqueous Sol-Gel Route
journal, January 2006
- Yang, Jingsi; Xu, Jun John
- Journal of The Electrochemical Society, Vol. 153, Issue 4, p. A716-A723
Surface Protected Lithium-Metal-Oxide Electrodes
patent-application, July 2010
- Thackeray, Michael M.; Kang, Sun-Ho
- US Patent Application 12/694422; 20100190058
Electrochemical evaluation of mixed oxide electrode for Li-ion secondary batteries: Li1.1Mn1.9O4 and LiNi0.8Co0.15Al0.05O2
journal, August 2005
- Myung, Seung-Taek; Cho, Myung Hun; Hong, Hyeon Taik
- Journal of Power Sources, Vol. 146, Issue 1-2, p. 222-225
Layered Li(Li0.2Ni0.15+0.5zCo0.10Mn0.55−0.5z)O2−zFz cathode materials for Li-ion secondary batteries
journal, August 2005
- Kang, S.-H.; Amine, K.
- Journal of Power Sources, Vol. 146, Issue 1-2, p. 654-657
Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C
journal, April 2007
- Johnson, Christopher S.; Li, Naichao; Lefief, Christina
- Electrochemistry Communications, Vol. 9, Issue 4, p. 787-795
Electrochemical cell
patent, May 1994
- Thackeray, Michael M.; Gummow, Rosalind J.
- US Patent Document 5,316,877
Structural and Electrochemical Characterization of Composite Layered-Spinel Electrodes Containing Ni and Mn for Li-Ion Batteries
journal, January 2009
- Cabana, Jordi; Kang, Sun-Ho; Johnson, Christopher S.
- Journal of The Electrochemical Society, Vol. 156, Issue 9
High-energy and high-power Li-rich nickel manganese oxide electrode materials
journal, November 2010
- Kim, Donghan; Kang, Sun-Ho; Balasubramanian, Mahalingam
- Electrochemistry Communications, Vol. 12, Issue 11, p. 1618-1621
Mixed phase lithium metal oxide compositions with desirable battery performance
patent, June 2015
- Sharma, Sanjeev; Venkatachalam, Subramanian; Anguchamy, Yogesh Kumar
- US Patent Document 9,070,489
Thin Film Battery Comprising Stacked Battery Cells and Methods
patent-application, May 2009
- Kraznov, Victor; Nieh, Kai-Wei
- US Patent Application 11/946819; 20090136839
Positive active material for rechargeable lithium battery and method of preparing same
patent, April 2003
- Cho, Jae-Phil; Kim, Chan; Yoo, Sang-Im
- US Patent Document 6,555,269
The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes
journal, October 2004
- Johnson, C. S.; Kim, J-S.; Lefief, C.
- Electrochemistry Communications, Vol. 6, Issue 10, p. 1085-1091
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125
Characterization of LT ‐ LixCo1 − yNiy O 2 Electrodes for Rechargeable Lithium Cells
journal, January 1993
- Gummow, R. J.; Thackeray, M. M.
- Journal of The Electrochemical Society, Vol. 140, Issue 12, p. 3365-3368
Process of preparing a surface-treated positive active material for a lithium secondary battery
patent, November 2008
- Suh, Jun-Won; Kweon, Ho-Jin
- US Patent Document 7,445,871
Lithium transition metal oxide
patent, November 1992
- Thackeray, Michael M.; Gummow, Rosalind J.
- US Patent Document 5,160,712
Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy
journal, December 2011
- Croy, Jason R.; Balasubramanian, Mahalingam; Kim, Donghan
- Chemistry of Materials, Vol. 23, Issue 24, p. 5415-5424
Active material for battery and method of preparing same
patent, April 2005
- Cho, Jae-Phil; Jung, Won-II; Park, Yong-Chul
- US Patent Document 6,878,487
Coated electrode particles for composite electrodes and electrochemical cells
patent, August 2006
- Holman, Richard K.; Chiang, Yet-Ming; Gozdz, Antoni S.
- US Patent Document 7,087,348
Identification of LiNi0.5Mn1.5O4 spinel in layered manganese enriched electrode materials
journal, March 2011
- Belharouak, Ilias; Koenig, Gary M.; Ma, Jiwei
- Electrochemistry Communications, Vol. 13, Issue 3, p. 232-236
Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C
journal, March 1993
- Gummow, R. J.; Liles, D. C.; Thackeray, M. M.
- Materials Research Bulletin, Vol. 28, Issue 3, p. 235-246
What Are Batteries, Fuel Cells, and Supercapacitors?
journal, October 2004
- Winter, Martin; Brodd, Ralph J.
- Chemical Reviews, Vol. 104, Issue 10, p. 4245-4270
Manganese oxide composite electrodes for lithium batteries
patent, December 2011
- Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S.
- US Patent Document 8,080,340
Cathode active material and lithium battery using the same
patent, May 2011
- Park, Kyu-sung
- US Patent Document 7,935,270
Positive active material for a rechargeable lithium battery, method for preparing the same and battery containing the same
patent, July 2005
- Cho, Jae-Phil; Park, Byung Woo; Kim, Yong Jeong
- US Patent Document 6,916,580
Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004
- Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
- US Patent Document 6,677,082
Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell
journal, December 2000
- Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
- Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791
Electrochemical and Structural Properties of xLi2M‘O3 ·(1− x )LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)
journal, May 2004
- Kim, Jeom-Soo; Johnson, Christopher S.; Vaughey, John T.
- Chemistry of Materials, Vol. 16, Issue 10, p. 1996-2006
The Electrochemical Stability of Spinel Electrodes Coated with ZrO2, Al2O3, and SiO2 from Colloidal Suspensions
journal, January 2004
- Kim, J.-S.; Johnson, C. S.; Vaughey, J. T.
- Journal of The Electrochemical Society, Vol. 151, Issue 10, p. A1755-A1761
Optimization of Insertion Compounds Such as LiMn2O4 for Li-Ion Batteries
journal, November 2002
- Amatucci, G.; Tarascon, J.-M.
- Journal of The Electrochemical Society, Vol. 149, Issue 12, p. K31-K46
A New Three‐Volt Spinel Li1 + xMn1.5Ni0.5 O 4 for Secondary Lithium Batteries
journal, January 1996
- Amine, K.; Tukamoto, H.; Yasuda, H.
- Journal of The Electrochemical Society, Vol. 143, Issue 5, p. 1607-1613
Non-aqueous electrolyte secondary battery
patent-application, September 2006
- Shirakata, Hironori; Kitao, Hideki; Akita, Hiroyuki
- US Patent Application 11/378638; 20060216605
Electrode Structures and Surfaces for Li Batteries
patent-application, May 2014
- Thackeray, Michael M.; Kang, Sun-Ho; Balasubramanian, Mahalingam
- US Patent Application 14/154948; 20140127398
Influence of Lattice Parameter Differences on the Electrochemical Performance of the 5 V Spinel LiMn1.5 − yNi0.5 − zMy + zO4 (M = Li , Mg, Fe, Co, and Zn)
journal, January 2005
- Arunkumar, T. A.; Manthiram, A.
- Electrochemical and Solid-State Letters, Vol. 8, Issue 8, p. A403-A405
Lithium manganese oxide compound
patent, October 1992
- Thackeray, Michael M.; Rossouw, Margaretha H.
- US Patent Document 5,153,081
Lithium metal oxide electrodes for lithium cells and batteries
patent, January 2004
- Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
- US Patent Document 6,680,143
Improvement of structural and electrochemical properties of AlF3-coated Li[Ni1/3Co1/3Mn1/3]O2 cathode materials on high voltage region
journal, April 2008
- Park, B.-C.; Kim, H.-B.; Myung, S.-T.
- Journal of Power Sources, Vol. 178, Issue 2, p. 826-831
Intergrown LiNi0.5Mn1.5O4·LiNi1/3Co1/3Mn1/3O2 composite nanorods as high-energy density cathode materials for lithium-ion batteries
journal, January 2013
- Yang, Jingang; Zhang, Xiaolong; Han, Xiaopeng
- Journal of Materials Chemistry A, Vol. 1, Issue 44, p. 13742-13745
Positive electrode active material, positive electrode and non-aqueous electrolyte secondary battery using thereof
patent-application, May 2003
- Noguchi, Takehiro; Numata, Tatsuji
- US Patent Application 10/270946; 20030086863
Lithium metal oxide electrodes for lithium cells and batteries
patent, December 2008
- Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil
- US Patent Document 7,468,223
Ordering in Lix(Ni0.5Mn0.5)O2 and its relation to charge capacity and electrochemical behavior in rechargeable lithium batteries
journal, October 2004
- Van der Ven, A.; Ceder, G.
- Electrochemistry Communications, Vol. 6, Issue 10, p. 1045-1050
Surface protected lithium-metal-oxide electrodes
patent, August 2014
- Thackeray, Michael M.; Kang, Sun-Ho
- US Patent Document 8,808,912
Lithium secondary battery with high power
patent-application, December 2005
- Park, Hey Woong; Yu, Ji-Sang; Kim, Sung-Woo
- US Patent Application 11/091072; 20050271943
Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries
journal, March 2006
- Choi, W.; Manthiram, A.
- Electrochemical and Solid-State Letters, Vol. 9, Issue 5, p. A245-A248
Stabilization of xLi2MnO3 ⋅ ( 1 − x ) LiMO2 Electrode Surfaces ( M = Mn , Ni , Co ) with Mildly Acidic, Fluorinated Solutions
journal, January 2008
- Kang, S.-H.; Thackeray, M. M.
- Journal of The Electrochemical Society, Vol. 155, Issue 4, p. A269-A275
Positive-electrode active material for non-aqueous electrolyte secondary cell and process for preparing the same
patent, June 2008
- Oesten, Ruediger; Suzuki, Ryuta; Nitta, Katsuhisa
- US Patent Document 7,384,664
Cathode active material and lithium battery using the same
patent, April 2011
- Park, Kyu-sung
- US Patent Document 7,927,506
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005
- Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
- Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
Li2MnO3-based composite cathodes for lithium batteries: A novel synthesis approach and new structures
journal, October 2011
- Croy, J. R.; Kang, S.-H.; Balasubramanian, M.
- Electrochemistry Communications, Vol. 13, Issue 10, p. 1063-1066
Manganese oxide composite electrodes for lithium batteries
patent, December 2007
- Thackeray, Michael M.; Johnson, Christopher S.; Li, Naichao
- US Patent Document 7,303,840
In situ X-ray diffraction studies of mixed LiMn2O4–LiNi1/3Co1/3Mn1/3O2 composite cathode in Li-ion cells during charge–discharge cycling
journal, July 2009
- Nam, Kyung-Wan; Yoon, Won-Sub; Shin, Hyunjung
- Journal of Power Sources, Vol. 192, Issue 2, p. 652-659
Manganese oxide composite electrodes for lithium batteries
patent, December 2009
- Johnson, Christopher S.; Kang, Sun-Ho; Thackeray, Michael M.
- US Patent Document 7,635,536
The Effects of Acid Treatment on the Electrochemical Properties of 0.5 Li2MnO3 ∙ 0.5 LiNi0.44Co0.25Mn0.31O2 Electrodes in Lithium Cells
journal, January 2006
- Kang, S.-H.; Johnson, C. S.; Vaughey, J. T.
- Journal of The Electrochemical Society, Vol. 153, Issue 6, p. A1186-A1192
Lithium metal oxide electrodes for lithium batteries
patent, January 2008
- Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S.
- US Patent Document 7,314,682
Lithium Metal Oxide Electrodes for Lithium Batteries
patent-application, June 2015
- Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.
- US Patent Application 14/554666; 20150180031
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries
journal, November 2012
- Kim, Donghan; Sandi, Giselle; Croy, Jason R.
- Journal of The Electrochemical Society, Vol. 160, Issue 1, p. A31-A38
Lithium metal oxide electrodes for lithium batteries
patent-application, February 2005
- Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S.
- US Patent Application 10/825931; 20050026040
Assembled Battery and Battery System
patent-application, August 2010
- Sugiyama, Shigeyuki; Aoki, Mamoru
- US Patent Application 12/676493; 20100207577
Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C
journal, March 1992
- Gummow, R. J.; Thackeray, M. M.; David, W. I. F.
- Materials Research Bulletin, Vol. 27, Issue 3, p. 327-337
Lithium–manganese oxide electrodes with layered–spinel composite structures xLi2MnO3·(1−x)Li1+yMn2−yO4 (0<x<1, 0⩽y⩽0.33) for lithium batteries
journal, May 2005
- Johnson, C. S.; Li, N.; Vaughey, J. T.
- Electrochemistry Communications, Vol. 7, Issue 5, p. 528-536
Understanding the effect of synthesis temperature on the structural and electrochemical characteristics of layered-spinel composite cathodes for lithium-ion batteries
journal, October 2013
- Lee, Eun-Sung; Huq, Ashfia; Manthiram, Arumugam
- Journal of Power Sources, Vol. 240, p. 193-203
Structural Considerations of Layered and Spinel Lithiated Oxides for Lithium Ion Batteries
journal, January 1995
- Thackeray, M. M.
- Journal of The Electrochemical Society, Vol. 142, Issue 8
Positive plate active material and nonaqyeous electrolyte secondary cell using same
patent-application, April 2004
- Hosoya, Yosuke; Yamamoto, Yoshikatsu; Sato, Takashi
- US Patent Application 10/468900; 20040076882
A reinvestigation of the structures of lithium-cobalt-oxides with neutron-diffraction data
journal, November 1993
- Gummow, R. J.; Liles, D. C.; Thackeray, M. M.
- Materials Research Bulletin, Vol. 28, Issue 11, p. 1177-1184
Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007
- Park, S.; Kang, S.; Johnson, C.
- Electrochemistry Communications, Vol. 9, Issue 2, p. 262-268
Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials
patent-application, April 2010
- Venkatachalam, Subramanian; Lopez, Herman; Kumar, Sujeet
- US Patent Application 12/246814; 20100086853