Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.; Park, Joong Sun; Lee, Eungje

Title: Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Abstract

An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi₂MO₃.(1-x)LiM'O₂].(1-y)Li_1+dMn_2-z-dM"_-zO₄; wherein 0.ltoreq.x.ltoreq.1; 0.75.ltoreq.y<1; 01+dMn_2-z-dM"_zO₄ component comprises a spinel structure, each of the Li₂MO₃ and the LiM'O₂ components comprise layered structures, and at least one of M, M', and M" comprises Co. Cells and batteries comprising the electrode material also are described.

Inventors:: Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.; Park, Joong Sun; Lee, Eungje

Issue Date:: 2018-09-04

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1476897

Patent Number(s):: 10069143

Application Number:: 14/733,512

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M2220/20 - Batteries in motive systems, e.g. vehicle, ship, plane
H01M2220/30 - Batteries in portable systems, e.g. mobile phone, laptop
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Jun 08

Country of Publication:: United States

Language:: English

Citation Formats


                    Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, and Lee, Eungje. Cobalt-stabilized lithium metal oxide electrodes for lithium batteries.  United States: N. p., 2018. 
        Web.

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                    Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, & Lee, Eungje. Cobalt-stabilized lithium metal oxide electrodes for lithium batteries.  United States.

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                    Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, and Lee, Eungje. Tue .  
        "Cobalt-stabilized lithium metal oxide electrodes for lithium batteries".  United States.  https://www.osti.gov/servlets/purl/1476897.

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@article{osti_1476897,

  title        = {Cobalt-stabilized lithium metal oxide electrodes for lithium batteries},

  author       = {Thackeray, Michael M. and Croy, Jason R. and Long, Brandon R. and Park, Joong Sun and Lee, Eungje},

  abstractNote = {An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi2MO3.(1-x)LiM'O2].(1-y)Li1+dMn2-z-dM"-zO4; wherein 0.ltoreq.x.ltoreq.1; 0.75.ltoreq.y<1; 01+dMn2-z-dM"zO4 component comprises a spinel structure, each of the Li2MO3 and the LiM'O2 components comprise layered structures, and at least one of M, M', and M" comprises Co. Cells and batteries comprising the electrode material also are described.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2018},

  month        = {9}

}

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Title: Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Abstract

Citation Formats

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journal, January 2005

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patent, September 2010

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patent, November 2002

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journal, July 1992

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journal, January 2002

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patent, November 1992

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journal, January 2006

Electrochemical evaluation of mixed oxide electrode for Li-ion secondary batteries: Li_1.1Mn_1.9O₄ and LiNi_0.8Co_0.15Al_0.05O₂
journal, August 2005

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patent-application, June 2003

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patent, January 2004

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journal, April 2007

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journal, January 2007

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patent-application, May 2009

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journal, November 2010

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patent, January 2008

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journal, July 2005

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journal, October 2004

Electrochemical cell
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Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007

Characterization of LT ‐ Li_xCo_1 − yNi_y O ₂ Electrodes for Rechargeable Lithium Cells
journal, January 1993

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patent, December 2011

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patent, April 2003

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patent-application, March 2013

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journal, December 2011

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journal, March 2011

Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C
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journal, October 2004

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patent-application, September 2006

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journal, December 2000

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journal, May 2004

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journal, January 2004

Optimization of Insertion Compounds Such as LiMn₂O₄ for Li-Ion Batteries
journal, November 2002

A New Three‐Volt Spinel Li_1 + xMn_1.5Ni_0.5 O ₄ for Secondary Lithium Batteries
journal, January 1996

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patent-application, February 2005

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patent-application, July 2005

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patent, April 2011

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journal, April 2008

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journal, October 2011

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journal, July 2009

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Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials
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