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Title: Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Abstract

An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi2MO3.(1-x)LiM'O2].(1-y)Li1+dMn2-z-dM"-zO4; wherein 0.ltoreq.x.ltoreq.1; 0.75.ltoreq.y<1; 01+dMn2-z-dM"zO4 component comprises a spinel structure, each of the Li2MO3 and the LiM'O2 components comprise layered structures, and at least one of M, M', and M" comprises Co. Cells and batteries comprising the electrode material also are described.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1476897
Patent Number(s):
10069143
Application Number:
14/733,512
Assignee:
UCHICAGO ARGONNE, LLC (Chicago, IL)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Jun 08
Country of Publication:
United States
Language:
English

Citation Formats

Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, and Lee, Eungje. Cobalt-stabilized lithium metal oxide electrodes for lithium batteries. United States: N. p., 2018. Web.
Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, & Lee, Eungje. Cobalt-stabilized lithium metal oxide electrodes for lithium batteries. United States.
Thackeray, Michael M., Croy, Jason R., Long, Brandon R., Park, Joong Sun, and Lee, Eungje. Tue . "Cobalt-stabilized lithium metal oxide electrodes for lithium batteries". United States. https://www.osti.gov/servlets/purl/1476897.
@article{osti_1476897,
title = {Cobalt-stabilized lithium metal oxide electrodes for lithium batteries},
author = {Thackeray, Michael M. and Croy, Jason R. and Long, Brandon R. and Park, Joong Sun and Lee, Eungje},
abstractNote = {An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi2MO3.(1-x)LiM'O2].(1-y)Li1+dMn2-z-dM"-zO4; wherein 0.ltoreq.x.ltoreq.1; 0.75.ltoreq.y<1; 01+dMn2-z-dM"zO4 component comprises a spinel structure, each of the Li2MO3 and the LiM'O2 components comprise layered structures, and at least one of M, M', and M" comprises Co. Cells and batteries comprising the electrode material also are described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {9}
}

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Works referenced in this record:

Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014


Structural complexity of layered-spinel composite electrodes for Li-ion batteries
journal, August 2010


High-Performance ZrO2-Coated LiNiO2 Cathode Material
journal, January 2001


Controlled Nanoparticle Metal Phosphates (Metal = Al , Fe, Ce, and Sr) Coatings on LiCoO2 Cathode Materials
journal, January 2005


Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells
journal, April 1994


Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries
journal, July 1992


Surface Modification of High Capacity Layered Li [ Li0.2Mn0.54Ni0.13Co0.13 ] O2 Cathodes by AlPO4
journal, January 2008


Microwave-Assisted Synthesis of High-Voltage Nanostructured LiMn1.5Ni0.5O4 Spinel: Tuning the Mn3+ Content and Electrochemical Performance
journal, July 2013


Effect of a ZrO2 Coating on the Structure and Electrochemistry of LixCoO2 When Cycled to 4.5 V
journal, January 2002


Electrochemical evaluation of mixed oxide electrode for Li-ion secondary batteries: Li1.1Mn1.9O4 and LiNi0.8Co0.15Al0.05O2
journal, August 2005


Layered Li(Li0.2Ni0.15+0.5zCo0.10Mn0.55−0.5z)O2−zFz cathode materials for Li-ion secondary batteries
journal, August 2005


Anomalous capacity and cycling stability of xLi2MnO3·(1−x)LiMO2 electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C
journal, April 2007


AlF3-Coating to Improve High Voltage Cycling Performance of Li[Ni1∕3]Co1∕3]Mn1∕3]O2 Cathode Materials for Lithium Secondary Batteries
journal, January 2007


High-energy and high-power Li-rich nickel manganese oxide electrode materials
journal, November 2010


Structural and Electrochemical Characterization of Composite Layered-Spinel Electrodes Containing Ni and Mn for Li-Ion Batteries
journal, January 2009


The significance of the Li2MnO3 component in ‘composite’ xLi2MnO3·(1−x)LiMn0.5Ni0.5O2 electrodes
journal, October 2004


Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
journal, January 2007


Characterization of  LT  ‐ LixCo1 − yNiy O 2 Electrodes for Rechargeable Lithium Cells
journal, January 1993


Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy
journal, December 2011


Identification of LiNi0.5Mn1.5O4 spinel in layered manganese enriched electrode materials
journal, March 2011


Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C
journal, March 1993


What Are Batteries, Fuel Cells, and Supercapacitors?
journal, October 2004


Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell
journal, December 2000


Electrochemical and Structural Properties of xLi2M‘O3 ·(1− x )LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)
journal, May 2004


The Electrochemical Stability of Spinel Electrodes Coated with ZrO2, Al2O3, and SiO2 from Colloidal Suspensions
journal, January 2004


Optimization of Insertion Compounds Such as LiMn2O4 for Li-Ion Batteries
journal, November 2002


A New Three‐Volt Spinel Li1 + xMn1.5Ni0.5 O 4 for Secondary Lithium Batteries
journal, January 1996


Intergrown LiNi0.5Mn1.5O4·LiNi1/3Co1/3Mn1/3O2 composite nanorods as high-energy density cathode materials for lithium-ion batteries
journal, January 2013


Ordering in Lix(Ni0.5Mn0.5)O2 and its relation to charge capacity and electrochemical behavior in rechargeable lithium batteries
journal, October 2004


Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries
journal, March 2006


Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries
journal, March 2005

  • Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T.
  • Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267
  • https://doi.org/10.1039/b417616m

Li2MnO3-based composite cathodes for lithium batteries: A novel synthesis approach and new structures
journal, October 2011


In situ X-ray diffraction studies of mixed LiMn2O4–LiNi1/3Co1/3Mn1/3O2 composite cathode in Li-ion cells during charge–discharge cycling
journal, July 2009


The Effects of Acid Treatment on the Electrochemical Properties of 0.5 Li2MnO3 ∙ 0.5 LiNi0.44Co0.25Mn0.31O2 Electrodes in Lithium Cells
journal, January 2006


Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries
journal, November 2012


ChemInform Abstract: Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell.
journal, March 2001


Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C
journal, March 1992


Structural Considerations of Layered and Spinel Lithiated Oxides for Lithium Ion Batteries
journal, January 1995


A reinvestigation of the structures of lithium-cobalt-oxides with neutron-diffraction data
journal, November 1993


Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007