Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition

Dai, Sheng; Sun, Xiaoguang

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Title: Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition

Abstract

An ionic liquid composition comprising a complex of a trihalo aluminum (III) species with at least one organic uncharged ligand comprising a ring structure having at least three ring carbon atoms and at least one ring heteroatom selected from nitrogen and sulfur, wherein the complex is a liquid at a temperature of 100° C. or less. Methods of electroplating aluminum onto a metallic substrate using the above-described ionic liquid composition are also described.

Inventors:: Dai, Sheng; Sun, Xiaoguang

Issue Date:: Tue Sep 22 00:00:00 EDT 2020

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1735289

Patent Number(s):: 10781525

Application Number:: 16/214,436

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25D - PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS

Show more

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2/22 - Metal halides
C07C45/56 - from heterocyclic compounds
C07C45/562 - {with nitrogen as the only hetero atom}
C07C45/567 - {with sulfur as the only hetero atom}

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25D - PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS
C25D3/44 - Aluminium
C25D3/665 - {from ionic liquids}
C25D5/003 - {Electroplating characterised by the use of gases, e.g. pressure influence

Show less

DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 12/10/2018

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Dai, Sheng, and Sun, Xiaoguang. Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition.  United States: N. p., 2020. 
        Web.

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                    Dai, Sheng, & Sun, Xiaoguang. Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition.  United States.

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                    Dai, Sheng, and Sun, Xiaoguang. Tue .  
        "Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition".  United States.  https://www.osti.gov/servlets/purl/1735289.

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@article{osti_1735289,

  title        = {Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition},

  author       = {Dai, Sheng and Sun, Xiaoguang},

  abstractNote = {An ionic liquid composition comprising a complex of a trihalo aluminum (III) species with at least one organic uncharged ligand comprising a ring structure having at least three ring carbon atoms and at least one ring heteroatom selected from nitrogen and sulfur, wherein the complex is a liquid at a temperature of 100° C. or less. Methods of electroplating aluminum onto a metallic substrate using the above-described ionic liquid composition are also described.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Sep 22 00:00:00 EDT 2020},

  month        = {Tue Sep 22 00:00:00 EDT 2020}

}

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Similar Records

Title: Aluminum trihalide-neutral ligand ionic liquids and their use in aluminum deposition

Abstract

Citation Formats

Electrodeposition of Aluminum from the Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Room Temperature Molten Salt + Benzene journal, January 1997

Apparatus for single anode brush electroplating patent, July 1993

Electroplating aluminum alloys from organic solvent baths and articles coated therewith patent, January 1988

Photoresponsive ionogel patent, April 2012

Electrolysis foil patent, October 1980

A taste of the future journal, June 2003

Semiconductor substrate processing apparatus and method patent-application, September 2001

Method and means for electrolytic precleaning of substrates and the electrodeposition of aluminum on said substrates patent, November 1978

Synthesis of ionic liquids patent-application, September 2006

Electric Al or Al Alloy Plating Bath Using Room Temperature Molten Salt Bath and Plating Method Using the Same patent-application, February 2012

Metal complexes patent-application, October 2013

Coating Method Using Ionic Liquid patent-application, July 2012

Plating apparatus and method of plating patent, March 2014

Aluminum electroplating solution patent, April 1983

Electrodeposition of Aluminum patent, August 1948

Imidazolium salts and their use of these ionic liquids as a solvent patent, March 2011

Ionic liquids patent-application, January 2013

Surface film structure of a metallic bipolar plate for fuel cells and a method for producing the same patent-application, May 2005

Aluminum electroplating method patent, August 1991

Method of electroplating of aluminum and plating baths therefor patent, January 1977

Electroplating solution and method for electroplating patent, June 2007

Electrolyte-liquid for the electrodeposition of aluminum patent, March 1979

Methods and systems for in-situ electroplating of electrodes patent-application, December 2009

Hydrophobic ionic liquids patent, October 1998

Electrochemical Reactivity in Room-Temperature Ionic Liquids journal, July 2008

Method of electroplating aluminum and its alloys patent, January 1978

Electrochemical deposition of conductive coatings on fuel cell bipolar plates patent-application, February 2010

Synthesis and characterization of complexes of aluminum halide with 2,2'-bipyridine, 1,10-phenanthroline and 2,2',2''-terpyridine in acetonitrile journal, February 1977

Electroplating solutions for the electrodeposition of aluminum and method of making same patent, May 1979

Electroplating method and apparatus patent, November 2000

Electrodeposition of Metals from a Fused Bath of Aluminum Halohydride Organic Complex and Composition thereof patent, August 1966

Ionic liquids patent-application, July 2012

Aluminum electroplating solution and method for forming aluminum plating film patent-application, October 2011

Reversible superhydrophilic-superhydrophobic coating for fuel cell bipolar plates and method of making the same patent-application, July 2011

Electrodeposition of aluminum patent, December 1976

Electroplating bath and method for the electrodeposition of bright aluminum coatings patent, June 1977

Highly Stretchable and Transparent Ionogels as Nonvolatile Conductors for Dielectric Elastomer Transducers journal, May 2014

Low temperature ionic liquids patent, March 1998

Plating bath for electrodeposition of aluminum and process for the same patent, May 1988

Electrodeposition in Ionic Liquids journal, January 2014

Protection of magnesium alloys by aluminum plating from ionic liquids patent, July 2014

Electrodeposition of Aluminum from the Aluminum Chloride-1-Methyl-3-ethylimidazolium Chloride Room Temperature Molten Salt + Benzene
journal, January 1997

Apparatus for single anode brush electroplating
patent, July 1993

Electroplating aluminum alloys from organic solvent baths and articles coated therewith
patent, January 1988

Photoresponsive ionogel
patent, April 2012

Electrolysis foil
patent, October 1980

A taste of the future
journal, June 2003

Semiconductor substrate processing apparatus and method
patent-application, September 2001

Method and means for electrolytic precleaning of substrates and the electrodeposition of aluminum on said substrates
patent, November 1978

Synthesis of ionic liquids
patent-application, September 2006

Electric Al or Al Alloy Plating Bath Using Room Temperature Molten Salt Bath and Plating Method Using the Same
patent-application, February 2012

Metal complexes
patent-application, October 2013

Coating Method Using Ionic Liquid
patent-application, July 2012

Plating apparatus and method of plating
patent, March 2014

Aluminum electroplating solution
patent, April 1983

Electrodeposition of Aluminum
patent, August 1948

Imidazolium salts and their use of these ionic liquids as a solvent
patent, March 2011

Ionic liquids
patent-application, January 2013

Surface film structure of a metallic bipolar plate for fuel cells and a method for producing the same
patent-application, May 2005

Aluminum electroplating method
patent, August 1991

Method of electroplating of aluminum and plating baths therefor
patent, January 1977

Electroplating solution and method for electroplating
patent, June 2007

Electrolyte-liquid for the electrodeposition of aluminum
patent, March 1979

Methods and systems for in-situ electroplating of electrodes
patent-application, December 2009

Hydrophobic ionic liquids
patent, October 1998

Electrochemical Reactivity in Room-Temperature Ionic Liquids
journal, July 2008

Method of electroplating aluminum and its alloys
patent, January 1978

Electrochemical deposition of conductive coatings on fuel cell bipolar plates
patent-application, February 2010

Synthesis and characterization of complexes of aluminum halide with 2,2'-bipyridine, 1,10-phenanthroline and 2,2',2''-terpyridine in acetonitrile
journal, February 1977

Electroplating solutions for the electrodeposition of aluminum and method of making same
patent, May 1979

Electroplating method and apparatus
patent, November 2000

Electrodeposition of Metals from a Fused Bath of Aluminum Halohydride Organic Complex and Composition thereof
patent, August 1966

Ionic liquids
patent-application, July 2012

Aluminum electroplating solution and method for forming aluminum plating film
patent-application, October 2011

Reversible superhydrophilic-superhydrophobic coating for fuel cell bipolar plates and method of making the same
patent-application, July 2011

Electrodeposition of aluminum
patent, December 1976

Electroplating bath and method for the electrodeposition of bright aluminum coatings
patent, June 1977

Highly Stretchable and Transparent Ionogels as Nonvolatile Conductors for Dielectric Elastomer Transducers
journal, May 2014

Low temperature ionic liquids
patent, March 1998

Plating bath for electrodeposition of aluminum and process for the same
patent, May 1988

Electrodeposition in Ionic Liquids
journal, January 2014

Protection of magnesium alloys by aluminum plating from ionic liquids
patent, July 2014