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Title: Hexacyanometallates as highly conducting solid electrolytes for batteries

Abstract

Described here is a solid-state lithium-ion battery, comprising a cathode, an anode, and a solid-state electrolyte disposed between the cathode and the anode, wherein the electrolyte comprises a hexacyanometallate represented by AxPy[R(CN)6-wLw]z, wherein: A is at least one alkali metal cation, P is at least one transition metal cation, at least one post-transition metal cation, and/or at least one alkaline earth metal cation, R is at least one transition metal cation, L is an anion, x, y, and z are related based on electrical neutrality, x>0, y>0, z>0, and 0≤w≤6.

Inventors:
; ;
Issue Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1568538
Patent Number(s):
10333171
Application Number:
15/258,732
Assignee:
The Board of Trustees of the Leland Stanford Junior University (Stanford, CA)
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 09/07/2016
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE

Citation Formats

Wang, Richard, Cui, Yi, and Pasta, Mauro. Hexacyanometallates as highly conducting solid electrolytes for batteries. United States: N. p., 2019. Web.
Wang, Richard, Cui, Yi, & Pasta, Mauro. Hexacyanometallates as highly conducting solid electrolytes for batteries. United States.
Wang, Richard, Cui, Yi, and Pasta, Mauro. Tue . "Hexacyanometallates as highly conducting solid electrolytes for batteries". United States. https://www.osti.gov/servlets/purl/1568538.
@article{osti_1568538,
title = {Hexacyanometallates as highly conducting solid electrolytes for batteries},
author = {Wang, Richard and Cui, Yi and Pasta, Mauro},
abstractNote = {Described here is a solid-state lithium-ion battery, comprising a cathode, an anode, and a solid-state electrolyte disposed between the cathode and the anode, wherein the electrolyte comprises a hexacyanometallate represented by AxPy[R(CN)6-wLw]z, wherein: A is at least one alkali metal cation, P is at least one transition metal cation, at least one post-transition metal cation, and/or at least one alkaline earth metal cation, R is at least one transition metal cation, L is an anion, x, y, and z are related based on electrical neutrality, x>0, y>0, z>0, and 0≤w≤6.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2019},
month = {6}
}

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