Electrolyte for batteries with regenerative solid electrolyte interface

Xiao, Jie; Lu, Dongping; Shao, Yuyan; Bennett, Wendy D.; Graff, Gordon L.; Liu, Jun; Zhang, Ji-Guang

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Title: Electrolyte for batteries with regenerative solid electrolyte interface

Abstract

An energy storage device comprising: an anode; and a solute-containing electrolyte composition wherein the solute concentration in the electrolyte composition is sufficiently high to form a regenerative solid electrolyte interface layer on a surface of the anode only during charging of the energy storage device, wherein the regenerative layer comprises at least one solute or solvated solute from the electrolyte composition.

Inventors:: Xiao, Jie; Lu, Dongping; Shao, Yuyan; Bennett, Wendy D.; Graff, Gordon L.; Liu, Jun; Zhang, Ji-Guang

Issue Date:: 2017-08-01

Research Org.:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1373551

Patent Number(s):: 9722277

Application Number:: 14/530,562

Assignee:: Battelle Memorial Institute

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/0568 - characterised by the solutes
H01M10/0569 - characterised by the solvents
H01M2300/0028 - characterised by the solvent
H01M2300/004 - Three solvents
H01M4/38 - of elements or alloys
H01M4/587 - for inserting or intercalating light metals

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P70/50 - Manufacturing or production processes characterised by the final manufactured product

Show less

DOE Contract Number:: AC05-76RL01830

Resource Type:: Patent

Resource Relation:: Patent File Date: 2014 Oct 31

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Xiao, Jie, Lu, Dongping, Shao, Yuyan, Bennett, Wendy D., Graff, Gordon L., Liu, Jun, and Zhang, Ji-Guang. Electrolyte for batteries with regenerative solid electrolyte interface.  United States: N. p., 2017. 
        Web.

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                    Xiao, Jie, Lu, Dongping, Shao, Yuyan, Bennett, Wendy D., Graff, Gordon L., Liu, Jun, & Zhang, Ji-Guang. Electrolyte for batteries with regenerative solid electrolyte interface.  United States.

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                    Xiao, Jie, Lu, Dongping, Shao, Yuyan, Bennett, Wendy D., Graff, Gordon L., Liu, Jun, and Zhang, Ji-Guang. Tue .  
        "Electrolyte for batteries with regenerative solid electrolyte interface".  United States.  https://www.osti.gov/servlets/purl/1373551.

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@article{osti_1373551,

  title        = {Electrolyte for batteries with regenerative solid electrolyte interface},

  author       = {Xiao, Jie and Lu, Dongping and Shao, Yuyan and Bennett, Wendy D. and Graff, Gordon L. and Liu, Jun and Zhang, Ji-Guang},

  abstractNote = {An energy storage device comprising: an anode; and a solute-containing electrolyte composition wherein the solute concentration in the electrolyte composition is sufficiently high to form a regenerative solid electrolyte interface layer on a surface of the anode only during charging of the energy storage device, wherein the regenerative layer comprises at least one solute or solvated solute from the electrolyte composition.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2017},

  month        = {8}

}

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Works referenced in this record:

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Garth, Bruce Hollis
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Secondary Batteries Comprising Eutectic Mixture And Preparation Method Thereof
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Secondary Battery And Method For Manufacturing Same
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Process for producing non-flammable quasi-solid electrolyte and electrolyte-separator for lithium battery applications
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Dynamic Formation Protocol for Lithium-Ion Battery
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Cathode Active Material, Cathode Including The Cathode Active Material, And Sodium Secondary Battery Including The Cathode
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Performance Improvement of Li Ion Battery with Non-Flammable TMP Mixed Electrolyte by Optimization of Lithium Salt Concentration and SEI Preformation Technique on Graphite Anode
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Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy
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Similar Records

Title: Electrolyte for batteries with regenerative solid electrolyte interface

Abstract

Citation Formats

High energy density battery with dioxolane based electrolyte patent, January 1978

Dioxolane and dimethoxyethane electrolyte solvent system patent, April 2001

Secondary Batteries Comprising Eutectic Mixture And Preparation Method Thereof patent-application, January 2010

Redox Flow Battery patent-application, May 2012

Organic Non-Aqueous Cation-Based Redox Flow Batteries patent-application, August 2013

Secondary Battery And Method For Manufacturing Same patent-application, October 2013

Metal Sulfide Electrodes And Energy Storage Devices Thereof patent-application, October 2014

Process for producing non-flammable quasi-solid electrolyte and electrolyte-separator for lithium battery applications patent-application, January 2015

Dynamic Formation Protocol for Lithium-Ion Battery patent-application, March 2015

Cathode Active Material, Cathode Including The Cathode Active Material, And Sodium Secondary Battery Including The Cathode patent-application, April 2015

Performance Improvement of Li Ion Battery with Non-Flammable TMP Mixed Electrolyte by Optimization of Lithium Salt Concentration and SEI Preformation Technique on Graphite Anode journal, January 2014

Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy journal, January 2013

On the Electrode Potentials in Lithium-Sulfur Batteries and Their Solvent-Dependence journal, January 2014

Sacrificial Anion Reduction Mechanism for Electrochemical Stability Improvement in Highly Concentrated Li-Salt Electrolyte journal, June 2014

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal, September 2010

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate journal, September 2002

General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes journal, March 2014

Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries journal, March 2014

Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions journal, June 2013

High energy density battery with dioxolane based electrolyte
patent, January 1978

Dioxolane and dimethoxyethane electrolyte solvent system
patent, April 2001

Secondary Batteries Comprising Eutectic Mixture And Preparation Method Thereof
patent-application, January 2010

Redox Flow Battery
patent-application, May 2012

Organic Non-Aqueous Cation-Based Redox Flow Batteries
patent-application, August 2013

Secondary Battery And Method For Manufacturing Same
patent-application, October 2013

Metal Sulfide Electrodes And Energy Storage Devices Thereof
patent-application, October 2014

Process for producing non-flammable quasi-solid electrolyte and electrolyte-separator for lithium battery applications
patent-application, January 2015

Dynamic Formation Protocol for Lithium-Ion Battery
patent-application, March 2015

Cathode Active Material, Cathode Including The Cathode Active Material, And Sodium Secondary Battery Including The Cathode
patent-application, April 2015

Performance Improvement of Li Ion Battery with Non-Flammable TMP Mixed Electrolyte by Optimization of Lithium Salt Concentration and SEI Preformation Technique on Graphite Anode
journal, January 2014

Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy
journal, January 2013

On the Electrode Potentials in Lithium-Sulfur Batteries and Their Solvent-Dependence
journal, January 2014

Sacrificial Anion Reduction Mechanism for Electrochemical Stability Improvement in Highly Concentrated Li-Salt Electrolyte
journal, June 2014

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate
journal, September 2002

General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes
journal, March 2014

Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries
journal, March 2014

Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
journal, June 2013