Electrode materials for sodium batteries

Johnson, Christopher S.; Kang, Sun-Ho; Kim, Donghan; Balasubramanian, Mahalingam

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Title: Electrode materials for sodium batteries

Abstract

The present invention provides an electrode material suitable for use as a cathode in a sodium electrochemical cell or battery, the electrode comprising a layered material of formula Na.sub.cLi.sub.dNi.sub.eMn.sub.fM.sub.zO.sub.b, wherein M comprises one or more metal cation, 0.24.ltoreq.c/b.ltoreq.0.5, 0 < d/b.ltoreq.0.23, 0.ltoreq.e/b.ltoreq.0.45, 0.ltoreq.f/b.ltoreq.0.45, 0.ltoreq.z/b.ltoreq.0.45, the combined average oxidation state of the metal components (i.e., Na.sub.cLi.sub.dNi.sub.eMn.sub.fM.sub.z) is in the range of about 3.9 to 5.2, and b is equal to (c+d+Ve+Xf+Yz)/2, wherein V is the average oxidation state of the Ni, X is the average oxidation state of the Mn, and Y is the average oxidation state of the M in the material. The combined positive charge of the metallic elements is balanced by the combined negative charge of the oxygen anions, the Na is predominately present in a sodium layer, and the Mn, Ni, and M are predominately present in a transition metal layer.

Inventors:: Johnson, Christopher S.; Kang, Sun-Ho; Kim, Donghan; Balasubramanian, Mahalingam

Issue Date:: Tue Sep 16 00:00:00 EDT 2014

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1532120

Patent Number(s):: 8835041

Application Number:: 13/006,512

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/39 - working at high temperature
H01M4/366 - {as layered products}
H01M4/483 - {for non-aqueous cells
H01M4/502 - {for non-aqueous cells
H01M4/523 - {for non-aqueous cells
H01M6/42 - Grouping of primary cells into batteries

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2011-01-14

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Johnson, Christopher S., Kang, Sun-Ho, Kim, Donghan, and Balasubramanian, Mahalingam. Electrode materials for sodium batteries.  United States: N. p., 2014. 
        Web.

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                    Johnson, Christopher S., Kang, Sun-Ho, Kim, Donghan, & Balasubramanian, Mahalingam. Electrode materials for sodium batteries.  United States.

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                    Johnson, Christopher S., Kang, Sun-Ho, Kim, Donghan, and Balasubramanian, Mahalingam. Tue .  
        "Electrode materials for sodium batteries".  United States.  https://www.osti.gov/servlets/purl/1532120.

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@article{osti_1532120,

  title        = {Electrode materials for sodium batteries},

  author       = {Johnson, Christopher S. and Kang, Sun-Ho and Kim, Donghan and Balasubramanian, Mahalingam},

  abstractNote = {The present invention provides an electrode material suitable for use as a cathode in a sodium electrochemical cell or battery, the electrode comprising a layered material of formula Na.sub.cLi.sub.dNi.sub.eMn.sub.fM.sub.zO.sub.b, wherein M comprises one or more metal cation, 0.24.ltoreq.c/b.ltoreq.0.5, 0 < d/b.ltoreq.0.23, 0.ltoreq.e/b.ltoreq.0.45, 0.ltoreq.f/b.ltoreq.0.45, 0.ltoreq.z/b.ltoreq.0.45, the combined average oxidation state of the metal components (i.e., Na.sub.cLi.sub.dNi.sub.eMn.sub.fM.sub.z) is in the range of about 3.9 to 5.2, and b is equal to (c+d+Ve+Xf+Yz)/2, wherein V is the average oxidation state of the Ni, X is the average oxidation state of the Mn, and Y is the average oxidation state of the M in the material. The combined positive charge of the metallic elements is balanced by the combined negative charge of the oxygen anions, the Na is predominately present in a sodium layer, and the Mn, Ni, and M are predominately present in a transition metal layer.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Sep 16 00:00:00 EDT 2014},

  month        = {Tue Sep 16 00:00:00 EDT 2014}

}

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Works referenced in this record:

Non-Aqueous Electrolyte Battery
patent-application, September 2010

Tsuruta, Sho; Saito, Motoharu; Yanagida, Katsunori
US Patent Application 12/732912; 20100248023
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100248023

Non-Aqueous Electrolyte Secondary Battery and Method of Manufacturing the Same
patent-application, September 2010

Saito, Motoharu; Koga, Hideyuki; Takeda, Katsutoshi
US Patent Application 12/161747; 20100248040
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100248040

Efficient sodium/sulfur battery
patent, January 1978

King, Randall N.; Mitoff, Stephan P.; Breiter, Manfred W.
US Patent Document 4,070,527
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4070527

Sodium ion secondary battery
patent, April 2010

Inoue, Takao; Saito, Motoharu; Fujimoto, Masahisa
US Patent Document 7,695,868
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7695868

Positive Electrode for a Lithium Battery
patent-application, June 2009

Park, Sang-Ho; Amine, Khalil
US Patent Application 12/331873; 20090155691
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090155691

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Layered oxide materials for batteries
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Kendrick, Emma; Gruar, Robert
US Patent Document 9,653,731
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9653731

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US Patent Document 10,008,738
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/10008738

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Similar Records

Title: Electrode materials for sodium batteries

Abstract

Citation Formats

Non-Aqueous Electrolyte Battery patent-application, September 2010

Non-Aqueous Electrolyte Secondary Battery and Method of Manufacturing the Same patent-application, September 2010

Efficient sodium/sulfur battery patent, January 1978

Sodium ion secondary battery patent, April 2010

Positive Electrode for a Lithium Battery patent-application, June 2009

Layered oxide materials for batteries patent, May 2017

Layered oxide materials for batteries patent, May 2017

Nanoconfined electrolytes and their use in batteries patent, June 2018

Non-Aqueous Electrolyte Battery
patent-application, September 2010

Non-Aqueous Electrolyte Secondary Battery and Method of Manufacturing the Same
patent-application, September 2010

Efficient sodium/sulfur battery
patent, January 1978

Sodium ion secondary battery
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Positive Electrode for a Lithium Battery
patent-application, June 2009

Layered oxide materials for batteries
patent, May 2017

Layered oxide materials for batteries
patent, May 2017

Nanoconfined electrolytes and their use in batteries
patent, June 2018