Sodium iron(II)-hexacyanoferrate(II) battery electrode

Lu, Yuhao; Vail, Sean Andrew

Title: Sodium iron(II)-hexacyanoferrate(II) battery electrode

Abstract

A method is provided for synthesizing sodium iron(II)-hexacyanoferrate(II). A Fe(CN)6 material is mixed with the first solution and either an anti-oxidant or a reducing agent. The Fe(CN)6 material may be either ferrocyanide ([Fe(CN)6]4−) or ferricyanide ([Fe(CN)6]3−). As a result, sodium iron(II)-hexacyanoferrate(II) (Na1+XFe[Fe(CN)6]Z.MH2O is formed, where X is less than or equal to 1, and where M is in a range between 0 and 7. In one aspect, the first solution including includes A ions, such as alkali metal ions, alkaline earth metal ions, or combinations thereof, resulting in the formation of Na1+XAYFe[Fe(CN)6]Z.MH2O, where Y is less than or equal to 1. Also provided are a Na1+XFe[Fe(CN)6]Z.MH2O battery and Na1+XFe[Fe(CN)6]Z.MH2O battery electrode.

Inventors:: Lu, Yuhao; Vail, Sean Andrew

Issue Date:: 2016-12-27

Research Org.:: Sharp Laboratories of America, Inc., Camas, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1531964

Patent Number(s):: 9531003

Application Number:: 15/218,508

Assignee:: Sharp Laboratories of America, Inc. (Camas, WA)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B19/02 - Elemental selenium or tellurium

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T29/49108 - Electric battery cell making

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B17/02 - Preparation of sulfur

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/0416 - {involving impregnation with a solution, dispersion, paste or dry powder
H01M4/0404 - {by coating on electrode collectors}
H01M4/0452 - {from solutions}
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B33/021 - Preparation

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/58 - of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/1391 - of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/623 - {fluorinated polymers}
H01M10/052 - Li-accumulators

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01D - COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
C01D1/02 - Oxides

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/88 - by thermal analysis data, e.g. TGA, DTA, DSC

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/134 - Electrodes based on metals, Si or alloys

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M4/387 - {Tin or alloys based on tin}
H01M2004/027 - {Negative electrodes}
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M4/587 - for inserting or intercalating light metals
H01M4/5825 - {Oxygenated metallic slats or polyanionic structures, e.g. borates, phosphates, silicates, olivines}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B32/00 - Carbon

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/054 - Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
H01M4/56 - of lead
H01M4/628 - {Inhibitors, e.g. gassing inhibitors, corrosion inhibitors}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B25/003 - {Phosphorus}

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/77 - by unit-cell parameters, atom positions or structure diagrams

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/0495 - {Chemical alloying}
H01M4/049 - {Manufacturing of an active layer by chemical means}
H01M4/1397 - of electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01D - COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
C01D15/02 - Oxides

H - ELECTRICITY H02 - GENERATION H02J - CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER
H02J7/0042 - {characterised by the mechanical construction}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/5815 - {Sulfides}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J6/008 - {Pyrolysis reactions

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M4/1395 - of electrodes based on metals, Si or alloys
H01M4/04 - Processes of manufacture in general
H01M4/60 - of organic compounds
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M4/366 - {as layered products}
H01M4/133 - Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
H01M4/0497 - {Chemical precipitation}
H01M4/382 - {Lithium
H01M4/381 - {Alkaline or alkaline earth metals elements
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/136 - Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
H01M4/38 - of elements or alloys

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01C - AMMONIA
C01C3/12 - Simple or complex iron cyanides

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DOE Contract Number:: AR0000297

Resource Type:: Patent

Resource Relation:: Patent File Date: 2016-07-25

Country of Publication:: United States

Language:: English

Citation Formats


                    Lu, Yuhao, and Vail, Sean Andrew. Sodium iron(II)-hexacyanoferrate(II) battery electrode.  United States: N. p., 2016. 
        Web.

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                    Lu, Yuhao, & Vail, Sean Andrew. Sodium iron(II)-hexacyanoferrate(II) battery electrode.  United States.

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                    Lu, Yuhao, and Vail, Sean Andrew. Tue .  
        "Sodium iron(II)-hexacyanoferrate(II) battery electrode".  United States.  https://www.osti.gov/servlets/purl/1531964.

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@article{osti_1531964,

  title        = {Sodium iron(II)-hexacyanoferrate(II) battery electrode},

  author       = {Lu, Yuhao and Vail, Sean Andrew},

  abstractNote = {A method is provided for synthesizing sodium iron(II)-hexacyanoferrate(II). A Fe(CN)6 material is mixed with the first solution and either an anti-oxidant or a reducing agent. The Fe(CN)6 material may be either ferrocyanide ([Fe(CN)6]4−) or ferricyanide ([Fe(CN)6]3−). As a result, sodium iron(II)-hexacyanoferrate(II) (Na1+XFe[Fe(CN)6]Z.MH2O is formed, where X is less than or equal to 1, and where M is in a range between 0 and 7. In one aspect, the first solution including includes A ions, such as alkali metal ions, alkaline earth metal ions, or combinations thereof, resulting in the formation of Na1+XAYFe[Fe(CN)6]Z.MH2O, where Y is less than or equal to 1. Also provided are a Na1+XFe[Fe(CN)6]Z.MH2O battery and Na1+XFe[Fe(CN)6]Z.MH2O battery electrode.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2016},

  month        = {12}

}

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Works referenced in this record:

Two-part inkless applicator for fingerprints
patent, June 1977

Smith, III, Jay; Hedgcoth, Virgle L.
US Patent Document 4,029,012
URL: http://patft.uspto.gov/netacgi/nph-Parser?patentnumber=4029012

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Title: Sodium iron(II)-hexacyanoferrate(II) battery electrode

Abstract

Citation Formats

Two-part inkless applicator for fingerprints patent, June 1977

Two-part inkless applicator for fingerprints
patent, June 1977