Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode
Abstract
A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1433852
- Patent Number(s):
- 9941058
- Application Number:
- 14/852,073
- Assignee:
- UT-BATTELLE, LLC (Oak Ridge, TN); DREXEL UNIVERSITY (Philadelphia, PA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Sep 11
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING
Citation Formats
Naskar, Amit K., Paranthaman, Mariappan Parans, Boota, Muhammad, and Gogotsi, Yury. Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode. United States: N. p., 2018.
Web.
Naskar, Amit K., Paranthaman, Mariappan Parans, Boota, Muhammad, & Gogotsi, Yury. Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode. United States.
Naskar, Amit K., Paranthaman, Mariappan Parans, Boota, Muhammad, and Gogotsi, Yury. Tue .
"Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode". United States. https://www.osti.gov/servlets/purl/1433852.
@article{osti_1433852,
title = {Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode},
author = {Naskar, Amit K. and Paranthaman, Mariappan Parans and Boota, Muhammad and Gogotsi, Yury},
abstractNote = {A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2018},
month = {4}
}
Works referenced in this record:
Composite carbon material of negative electrode in lithuim ion battery and its preparation method
patent-application, May 2009
- Yue, Min; Zhang, Wanhong
- US Patent Application 11/921205; 20090136849
Peanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
journal, January 2015
- Ding, Jia; Wang, Huanlei; Li, Zhi
- Energy & Environmental Science, Vol. 8, Issue 3, p. 941-955
Surface Functional Characteristics (C, O, S) of Waste Tire-Derived Carbon Black before and after Steam Activation
journal, January 2008
- Lin, Hsun-Yu; Chen, Wei-Chin; Yuan, Chung-Shin
- Journal of the Air & Waste Management Association, Vol. 58, Issue 1, p. 78-84
Polyaniline nanotubules—anion effect on conformation and oxidation state of polyaniline studied by Raman spectroscopy
journal, April 2004
- Tagowska, Magdalena; Pałys, Barbara; Jackowska, Krystyna
- Synthetic Metals, Vol. 142, Issue 1-3, p. 223-229
A metal-oxide nanofiber-decorated three-dimensional graphene hybrid nanostructured flexible electrode for high-capacity electrochemical capacitors
journal, January 2014
- Lee, Jun Seop; Lee, Choonghyeon; Jun, Jaemoon
- Journal of Materials Chemistry A, Vol. 2, Issue 30, p. 11922-11929
A review of electrode materials for electrochemical supercapacitors
journal, January 2012
- Wang, Guoping; Zhang, Lei; Zhang, Jiujun
- Chemical Society Reviews, Vol. 41, Issue 2, p. 797-828
Evolution of disposable bamboo chopsticks into uniform carbon fibers: a smart strategy to fabricate sustainable anodes for Li-ion batteries
journal, January 2014
- Jiang, Jian; Zhu, Jianhui; Ai, Wei
- Energy & Environmental Science, Vol. 7, Issue 8, p. 2670-2679
Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Reduced Graphene Oxide Sheets for Supercapacitors
journal, December 2013
- Wang, Li; Ye, Yinjian; Lu, Xingping
- Scientific Reports, Vol. 3, Article No. 3568
Effects of Pore Structure on Performance of An Activated-Carbon Supercapacitor Electrode Recycled from Scrap Waste Tires
journal, June 2014
- Zhi, Mingjia; Yang, Feng; Meng, Fanke
- ACS Sustainable Chemistry & Engineering, Vol. 2, Issue 7, p. 1592-1598
A Pilot Plant To Produce Biodiesel From High Free Fatty Acid Feedstocks
journal, January 2003
- Canakci, M.; Van Gerpen, J.
- Transactions of the ASAE, Vol. 46, Issue 4, p. 945-954
Human hair-derived carbon flakes for electrochemical supercapacitors
journal, January 2014
- Qian, Wenjing; Sun, Fengxia; Xu, Yanhui
- Energy & Environmental Science, Vol. 7, Issue 1, p. 379-386
Method For Obtaining A Carbon Black Powder By Pyrolyzing Scrap Rubber, The Carbon Black Thus Obtained And The Use Thereof
patent-application, December 2014
- Verberne, Arnoldus Henricus Adrianus; Jonkman, Jan Anne; Twigg, Christopher Michael
- US Patent Application 14/367121; 20140371385
Crosslinked polyaniline nanorods with improved electrochemical performance as electrode material for supercapacitors
journal, January 2014
- Wang, Xue; Deng, Jinxing; Duan, Xiaojuan
- Journal of Materials Chemistry A, Vol. 2, Issue 31, p. 12323-12329
Composite Manganese Oxide Percolating Networks As a Suspension Electrode for an Asymmetric Flow Capacitor
journal, May 2014
- Hatzell, Kelsey B.; Fan, Lei; Beidaghi, Majid
- ACS Applied Materials & Interfaces, Vol. 6, Issue 11, p. 8886-8893
Flexible all-solid-state high-power supercapacitor fabricated with nitrogen-doped carbon nanofiber electrode material derived from bacterial cellulose
journal, January 2013
- Chen, Li-Feng; Huang, Zhi-Hong; Liang, Hai-Wei
- Energy & Environmental Science, Vol. 6, Issue 11, p. 3331-3338
Process of producing gasoline, diesel and carbon black with waste rubbers and/or waste plastics
patent, April 1998
- Zhou, Dinli; Xing, Li
- US Patent Document 5,744,668
Pyrolysis of Tire Rubber: Porosity and Adsorption Characteristics of the Pyrolytic Chars
journal, June 1998
- Miguel, Guillermo San; Fowler, Geoffrey D.; Sollars, Christopher J.
- Industrial & Engineering Chemistry Research, Vol. 37, Issue 6, p. 2430-2435
Liquefaction of waste tires by pyrolysis for oil and chemicals—A review
journal, May 2013
- Quek, Augustine; Balasubramanian, Rajasekhar
- Journal of Analytical and Applied Pyrolysis, Vol. 101, p. 1-16
Mesoporous carbons and polymers
patent, October 2001
- Bell, William; Dietz, Steven
- US Patent Document 6,297,293
Apparatus for recovering marketable products from scrap rubber
patent, August 2008
- Denison, Gilbert W.
- US Patent Document 7,416,641
Li4Ti5O12/poly(methyl)thiophene asymmetric hybrid electrochemical device
journal, January 2004
- Du Pasquier, Aurelien; Laforgue, Alexis; Simon, Patrice
- Journal of Power Sources, Vol. 125, Issue 1, p. 95-102
Pyrolytic conversion of scrap tires to carbon products
patent, March 2009
- Karpetsky, Timothy P.; Mengel, R. William
- US Patent Document 7,497,929
Method For Upgrade-Processing Carbon Black Produced By Performing A Pyrolysis Process On Waste Tires
patent-application, October 2012
- Chung, Soo Hyun; Na, Jeong Geol
- US Patent Application 13/515681; 20120263641
Conducting polymer/carbon nanocoil composite electrodes for efficient supercapacitors
journal, January 2012
- Rakhi, R. B.; Chen, Wei; Alshareef, H. N.
- Journal of Materials Chemistry, Vol. 22, Issue 11, p. 5177-5183
Sulfonic acid group-containing carbonaceous material
patent, November 2013
- Yanagawa, Shinichirou; Kondo, Hidesato; Hara, Michikazu
- US Patent Document 8,575,281
Nitrogen-doped nanoporous carbon nanosheets derived from plant biomass: an efficient catalyst for oxygen reduction reaction
journal, January 2014
- Chen, Ping; Wang, Li-Kun; Wang, Gan
- Energy & Environmental Science, Vol. 7, Issue 12, p. 4095-4103
Carbon nano-particle and method of preparing the same and transparent conductive polymer composite containing the same
patent, July 2005
- Jang, Jyongsik; Oh, Joon-Hak; Kim, Dong Cheol
- US Patent Document 6,919,063
Mesoporous carbons and polymers
patent-application, May 2002
- Bell, William; Dietz, Steven
- US Patent Application 09/933521; 20020065333
From dead leaves to high energy density supercapacitors
journal, January 2013
- Biswal, Mandakini; Banerjee, Abhik; Deo, Meenal
- Energy & Environmental Science, Vol. 6, Issue 4, p. 1249-1259
Process for producing carbon anode compositions for lithium ion batteries
patent, August 2011
- Jang, Bor Z.; Zhamu, Aruna
- US Patent Document 7,993,780
Activity of solid acid catalysts for biodiesel production: A critical review
journal, January 2014
- Sani, Yahaya Muhammad; Daud, Wan Mohd Ashri Wan; Abdul Aziz, A. R.
- Applied Catalysis A: General, Vol. 470, p. 140-161
Sulfonated Amorphous Carbon, Process for Producing the Same and Use Thereof
patent-application, July 2007
- Hara, Michikazu; Domen, Kazunari
- US Patent Application 10/572057; 20080227996
Polyaniline and Polypyrrole Pseudocapacitor Electrodes with Excellent Cycling Stability
journal, April 2014
- Liu, Tianyu; Finn, Lauren; Yu, Minghao
- Nano Letters, Vol. 14, Issue 5, p. 2522-2527
Activated Carbon Spheres as a Flowable Electrode in Electrochemical Flow Capacitors
journal, January 2014
- Boota, M.; Hatzell, K. B.; Beidaghi, M.
- Journal of the Electrochemical Society, Vol. 161, Issue 6, p. A1078-A1083
Biodiesel sulfur slurry
patent, October 2004
- Lackey, Kenneth R.; Alcorn, II, James R.
- US Patent Document 6,802,897
Biodiesel production: a review
journal, October 1999
- Ma, Fangrui; Hanna, Milford A.
- Bioresource Technology, Vol. 70, Issue 1, p. 1-15
Green chemistry: Biodiesel made with sugar catalyst
journal, November 2005
- Toda, Masakazu; Takagaki, Atsushi; Okamura, Mai
- Nature, Vol. 438, Issue 7065, p. 178-178
Growth of Polyaniline on Hollow Carbon Spheres for Enhancing Electrocapacitance
journal, November 2010
- Lei, Zhibin; Chen, Zhongwei; Zhao, X. S.
- The Journal of Physical Chemistry C, Vol. 114, Issue 46, p. 19867-19874
Nanofiber Formation in the Chemical Polymerization of Aniline: A Mechanistic Study
journal, November 2004
- Huang, Jiaxing; Kaner, Richard B.
- Angewandte Chemie, Vol. 116, Issue 43, p. 5941-5945
Production of a Char Reinforcing Agent from Pyrolyzed Scrap Rubber
patent, July 1974
- Wakefield, Lynn B.; Crane, Grant; Kay, Edward Leo
- US Patent Document 3,823,221
Graphene-containing flowable electrodes for capacitive energy storage
journal, October 2015
- Boota, M.; Hatzell, K. B.; Alhabeb, M.
- Carbon, Vol. 92, p. 142-149
Highly Stable Supercapacitors with Conducting Polymer Core-Shell Electrodes for Energy Storage Applications
journal, January 2015
- Xia, Chuan; Chen, Wei; Wang, Xianbin
- Advanced Energy Materials, Vol. 5, Issue 8, Article No. 1401805
Reduced-graphene oxide/molybdenum oxide/polyaniline ternary composite for high energy density supercapacitors: Synthesis and properties
journal, January 2012
- Xia, Xifeng; Hao, Qingli; Lei, Wu
- Journal of Materials Chemistry, Vol. 22, Issue 17, p. 8314-8320
Thermal plasma pyrolysis of used tires for carbon black recovery
journal, July 2005
- Tang, L.; Huang, H.
- Journal of Materials Science, Vol. 40, Issue 14, p. 3817-3819
Mesoporous and adsorptive properties of palm date seed activated carbon prepared via sequential hydrothermal carbonization and sodium hydroxide activation
journal, June 2015
- Islam, Md. Azharul; Tan, I. A. W.; Benhouria, A.
- Chemical Engineering Journal, Vol. 270, p. 187-195
Mesoporous carbons and polymers
patent, May 2004
- Bell, William; Dietz, Steven
- US Patent Document 6,737,445
Pyrolytic Carbon Black Composite And Method Of Making The Same
patent-application, September 2016
- Naskar, Amit K.; Paranthaman, Mariappan Parans;
- US Patent Application 15/056184; 20160254543
Interconnected Carbon Nanosheets Derived from Hemp for Ultrafast Supercapacitors with High Energy
journal, May 2013
- Wang, Huanlei; Xu, Zhanwei; Kohandehghan, Alireza
- ACS Nano, Vol. 7, Issue 6, p. 5131-5141
Carbon-based solid acid, catalyst comprising the solid acid, and reaction using the solid acid as catalyst
patent, September 2011
- Yanagawa, Shinichirou; Kondo, Hidesato; Hara, Michikazu
- US Patent Document 8,013,130
Solid acid catalyzed biodiesel production from waste cooking oil
journal, December 2008
- Jacobson, K.; Gopinath, R.; Meher, L.
- Applied Catalysis B: Environmental, Vol. 85, Issue 1-2, p. 86-91
Carbons and Electrolytes for Advanced Supercapacitors
journal, February 2014
- Béguin, François; Presser, Volker; Balducci, Andrea
- Advanced Materials, Vol. 26, Issue 14, p. 2219-2251
Method for recovering carbon black from composites
patent, March 1998
- Holley, Carl A.
- US Patent Document 5,728,361
Activated carbon for use in electric double layer capacitors
patent-application, August 2002
- Hirahara, Satoshi; Takeda, Yoshitaka; Toki, Kazuyuki
- US Patent Application 10/040419; 20020114126
Sulfonated rubber compositions and processes therefor and therewith
patent, April 2003
- Patel, Bharat B.; Bishop, Marshall D.
- US Patent Document 6,547,710
Synthesis of biodiesel from waste vegetable oil with large amounts of free fatty acids using a carbon-based solid acid catalyst
journal, August 2010
- Shu, Qing; Gao, Jixian; Nawaz, Zeeshan
- Applied Energy, Vol. 87, Issue 8, p. 2589-2596
High-Density Sodium and Lithium Ion Battery Anodes from Banana Peels
journal, June 2014
- Lotfabad, Elmira Memarzadeh; Ding, Jia; Cui, Kai
- ACS Nano, Vol. 8, Issue 7, p. 7115-7129
Activated carbon and process for producing the same
patent, October 1999
- Suzuki, Mitsuo; Aikyo, Hiroyuki; Hirahara, Satoshi
- US Patent Document 5,965,479
Chloroform vapour sensor based on copper/polyaniline nanocomposite
journal, June 2002
- Sharma, Satish; Nirkhe, Chetan; Pethkar, Sushama
- Sensors and Actuators B: Chemical, Vol. 85, Issue 1-2, p. 131-136
Synthesis of biodiesel from cottonseed oil and methanol using a carbon-based solid acid catalyst
journal, July 2009
- Shu, Qing; Zhang, Qiang; Xu, Guanghui
- Fuel Processing Technology, Vol. 90, Issue 7-8, p. 1002-1008
Polymer-Nanocarbon Composites, Methods Of Making Composites, And Energy Storage Devices Including The Composite
patent-application, January 2015
- Roberts, Mark E.; Rao, Apparao M.; Podila, Ramakrishna
- US Patent Application 14/331264; 20150017528
Flexible graphene–polyaniline composite paper for high-performance supercapacitor
journal, January 2013
- Cong, Huai-Ping; Ren, Xiao-Chen; Wang, Ping
- Energy & Environmental Science, Vol. 6, Issue 4, p. 1185-1191
Tailored recovery of carbons from waste tires for enhanced performance as anodes in lithium-ion batteries
journal, January 2014
- Naskar, Amit K.; Bi, Zhonghe; Li, Yunchao
- RSC Advances, Vol. 4, Issue 72, p. 38213-38221
Process for producing granular activated carbon
patent, January 1977
- Watanabe, Yasuo; Miyajima, Toshiyuki
- US Patent Document 4,002,587
Pyrolyzed rubber products and processes
patent, May 2011
- Hamby, Kenneth W.; Kelly, James B.; Kuhn, Timothy J.
- US Patent Document 7,947,248
Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents
journal, March 2005
- Chen, Jingyi; Saeki, Fusayo; Wiley, Benjamin J.
- Nano Letters, Vol. 5, Issue 3, p. 473-477
Towards High-Energy-Density Pseudocapacitive Flowable Electrodes by the Incorporation of Hydroquinone
journal, January 2015
- Boota, M.; Hatzell, K. B.; Kumbur, E. C.
- ChemSusChem, Vol. 8, Issue 5, p. 835-843
Effect of Oxidation of Carbon Material on Suspension Electrodes for Flow Electrode Capacitive Deionization
journal, February 2015
- Hatzell, Kelsey B.; Hatzell, Marta C.; Cook, Kevin M.
- Environmental Science & Technology, Vol. 49, Issue 5, p. 3040-3047
Method for recovering carbon black from a waste rubber such as tires and the like and apparatus therefor
patent, October 1999
- Takegawa, Toshiyuki; Arima, Kenichi
- US Patent Document 5,961,946
Waste Tire Derived Carbon-Polymer Composite Paper as Pseudocapacitive Electrode with Long Cycle Life
journal, September 2015
- Boota, M.; Paranthaman, M. Parans; Naskar, Amit K.
- ChemSusChem, Vol. 8, Issue 21, p. 3576-3581
Flexible and Conductive Waste Tire-Derived Carbon/Polymer Composite Paper As Pseudocapacitive Electrode
patent-application, December 2016
- Naskar, Amit K.; Paranthaman, Mariappan Parans; Boota, Muhammad
- US Patent Application 14/852073; 20160351346
Preparation of Graphitic Oxide
journal, March 1958
- Hummers, William S.; Offeman, Richard E.
- Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339
Pyrolytic carbon black composite and method of making the same
patent, September 2016
- Naskar, Amit K.; Paranthaman, Mariappan Parans; Bi, Zhonghe
- US Patent Document 9,441,113
Charge storage mechanism in nanoporous carbons and its consequence for electrical double layer capacitors
journal, June 2010
- Simon, P.; Gogotsi, Y.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 368, Issue 1923, p. 3457-3467
Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films
journal, March 2010
- Wu, Qiong; Xu, Yuxi; Yao, Zhiyi
- ACS Nano, Vol. 4, Issue 4, p. 1963-1970
Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage
journal, August 2010
- Xu, Jingjing; Wang, Kai; Zu, Sheng-Zhen
- ACS Nano, Vol. 4, Issue 9, p. 5019-5026
Pyrolytic Carbon Black Composite And Method Of Making The Same
patent-application, January 2015
- Naskar, Amit K.; Paranthaman, Mariappan Parans; Bi, Zhonghe
- US Patent Application 13/945239; 20150021525
Biochar based solid acid catalyst for biodiesel production
journal, July 2010
- Dehkhoda, Amir Mehdi; West, Alex H.; Ellis, Naoko
- Applied Catalysis A: General, Vol. 382, Issue 2, p. 197-204
Polyaniline/multi-walled carbon nanotube composites with core–shell structures as supercapacitor electrode materials
journal, April 2010
- Zhou, Yi; Qin, Zong-Yi; Li, Li
- Electrochimica Acta, Vol. 55, Issue 12, p. 3904-3908
A comparative study of solid carbon acid catalysts for the esterification of free fatty acids for biodiesel production. Evidence for the leaching of colloidal carbon
journal, November 2013
- Deshmane, Chinmay A.; Wright, Marcus W.; Lachgar, Abdessadek
- Bioresource Technology, Vol. 147, p. 597-604
Hydrothermal Carbonization of Abundant Renewable Natural Organic Chemicals for High-Performance Supercapacitor Electrodes
journal, May 2011
- Wei, Lu; Sevilla, Marta; Fuertes, Antonio B.
- Advanced Energy Materials, Vol. 1, Issue 3, p. 356-361
Highly porous carbon spheres for electrochemical capacitors and capacitive flowable suspension electrodes
journal, October 2014
- Zhang, Chuanfang; Hatzell, Kelsey B.; Boota, Muhammad
- Carbon, Vol. 77, p. 155-164
New sulfonic acid ion-exchange resins for the preesterification of different oils and fats with high content of free fatty acids
journal, June 2009
- Russbueldt, Bernhard M. E.; Hoelderich, Wolfgang F.
- Applied Catalysis A: General, Vol. 362, Issue 1-2, p. 47-57
Process for the preparation of a granular activated carbon, and granular activated carbons produced thereby
patent, May 1975
- DeJong, Geert J.
- US Patent Document 3,886,088
Biodiesel production from waste oil feedstocks by solid acid catalysis
journal, November 2008
- Peng, Bao-Xiang; Shu, Qing; Wang, Jin-Fu
- Process Safety and Environmental Protection, Vol. 86, Issue 6, p. 441-447
Flowable Conducting Particle Networks in Redox-Active Electrolytes for Grid Energy Storage
journal, January 2015
- Hatzell, K. B.; Boota, M.; Kumbur, E. C.
- Journal of the Electrochemical Society, Vol. 162, Issue 5, p. A5007-A5012
On the Configuration of Supercapacitors for Maximizing Electrochemical Performance
journal, April 2012
- Zhang, Jintao; Zhao, X. S.
- ChemSusChem, Vol. 5, Issue 5, p. 818-841