Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode

Naskar, Amit K.; Paranthaman, Mariappan Parans; Boota, Muhammad; Gogotsi, Yury

Title: Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode

Abstract

A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.

Inventors:: Naskar, Amit K.; Paranthaman, Mariappan Parans; Boota, Muhammad; Gogotsi, Yury

Issue Date:: 2019-10-29

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1600232

Patent Number(s):: 10460881

Application Number:: 15/923,691

Assignee:: UT-Battelle, LLC (Oak Ridge, TN); Drexel University (Philadelphia, PA)

Patent Classifications (CPCs):: Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS

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Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/13 - Ultracapacitors, supercapacitors, double-layer capacitors

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01G - CAPACITORS
H01G11/44 - Raw materials therefor, e.g. resins or coal
H01G11/86 - specially adapted for electrodes
H01G11/38 - Carbon pastes or blends
H01G11/34 - characterised by carbonisation or activation of carbon

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DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 03/16/2018

Country of Publication:: United States

Language:: English

Subject:: 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Naskar, Amit K., Paranthaman, Mariappan Parans, Boota, Muhammad, and Gogotsi, Yury. Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode.  United States: N. p., 2019. 
        Web.

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                    Naskar, Amit K., Paranthaman, Mariappan Parans, Boota, Muhammad, & Gogotsi, Yury. Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode.  United States.

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                    Naskar, Amit K., Paranthaman, Mariappan Parans, Boota, Muhammad, and Gogotsi, Yury. Tue .  
        "Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode".  United States.  https://www.osti.gov/servlets/purl/1600232.

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@article{osti_1600232,

  title        = {Flexible and conductive waste tire-derived carbon/polymer composite paper as pseudocapacitive electrode},

  author       = {Naskar, Amit K. and Paranthaman, Mariappan Parans and Boota, Muhammad and Gogotsi, Yury},

  abstractNote = {A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce a tire-derived carbon composite comprising carbon black embedded in rubber-derived carbon matrix comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated tire-derived carbon composite; and, mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. An electrode and a supercapacitor are also disclosed.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2019},

  month        = {10}

}

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